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Related publications (28)

Operando Observation of (Bi)carbonate Precipitation during Electrochemical CO2 Reduction in Strongly Acidic Electrolytes

Corsin Battaglia, Alessandro Senocrate, Nukorn Plainpan

Precipitation of (bi)carbonate salts during the electrochemical CO2 reduction (CO2RR) has been identified as a major cause of degradation and one of the main challenges to be overcome before implementing this technology on the industrial scale. Recently, t ...

Amer Chemical Soc2024

Water weakening and the compressive brittle strength of carbonates: Influence of fracture toughness and static friction

Marie Estelle Solange Violay, Barnaby Padraig Fryer, Corentin Jean-Marie Rémi Noël

Water is ubiquitous within the pore space of rocks and has been shown to affect their physical and mechanical behaviour. Indeed, water can act on the rock strength via mechanical (i.e., reducing the effective stresses) or chemical effects (e.g., mineral di ...

2024

Contradict mechanism of long-term magnesium and sodium sulfate attacks of nano silica-modified cement mortars - Experimental and thermodynamic modeling

Qiao Wang

The mechanisms of external sulfate attack on cement mortars containing nano silica have been studied under full immersion conditions after 3 years. The sulfate degradation processes were compared between sodium sulfate and magnesium sulfate solutions with ...

Elsevier Sci Ltd2024

First paleoproteome study of fossil fish otoliths and the pristine preservation of the biomineral crystal host

Anders Meibom, Jaroslaw Hubert Stolarski, Jinming Guo

Otoliths are calcium carbonate components of the stato-acoustical organ responsible for hearing and maintenance of the body balance in teleost fish. During their formation, control over, e.g., morphology and carbonate polymorph is influenced by complex ins ...

Nature Portfolio2023

Influence of Low- to Medium-Kaolinite Clay on the Durability of Limestone Calcined Clay Cement (LC3) Concrete

Karen Scrivener, Matea Flegar

The kaolinite content is principally responsible for the durability performance of Limestone Calcined Clay Cement (LC3), which calls into question its global applicability. The clay supply has a significant impact on the LC3 system's reduced carbon footpri ...

MDPI2023

Atomistic modeling of C-S-H: bulk and surface

Ziga Casar

By replacing part of Portland cement with so-called supplementary cementitious materials (SCMs) it is possible to reduce the CO2 footprint of the cement industry. These SCMs are commonly limestone, calcined clay, slag and fly ash. While doing so the early ...

EPFL2023

Durability Challenges of Low-Grade Calcined Clay Opposed to High-Volume Fly Ash in General Purpose Concrete

Karen Scrivener, Matea Flegar

With the decrease in availability of common supplementary cementitious materials (SCMs) such as fly ash in Europe, the search for appropriate SCMs should be dealt with locally. A com-bination of abundant low-grade calcined clay and limestone powder has pro ...

AMER SOC TESTING MATERIALS2023

Influence of pore-scale heterogeneity on the precipitation patterns in Microbially Induced Calcite Precipitation (MICP)

Ariadni Elmaloglou

The principle of tailoring material properties to improve the mechanical behaviour of soils through compaction or cement grouting dates to the 60s. The increasing trends of urbanization worldwide require new solutions for the development of resilient and s ...

EPFL2023

Going Below 50% Clinker Factor in Limestone Calcined Clay Cements (LC3): A Comparison with Pozzolanic Cements from the South American Market

Karen Scrivener, Franco Alberto Zunino Sommariva

Limestone calcined clays are a promising technology as they offer similar performance to OPC from 7 days onwards, while enabling a reduction of the clinker content of 50%. In some regions of the world like South America, pozzolanic cements (i.e., blended c ...

SPRINGER INTERNATIONAL PUBLISHING AG2023

Unsupervised Electrofacies Clustering Based on Parameterization of Petrophysical Properties: A Dynamic Programming Approach

François Fleuret, Karthigan Sinnathamby

Electrofacies using well logs play a vital role in reservoir characterization. Often, they are sorted into clusters according to the self-similarity of input logs and do not capture the known underlying physical process. In this paper, we propose an unsupe ...

SOC PETROPHYSICISTS & WELL LOG ANALYSTS-SPWLA2023

Fine-scale dynamics of calcite precipitation in a large hardwater lake

Pascal Perolo

In hardwater lakes, calcite precipitation is an important yet poorly understood process in the lacustrine carbon cycle, in which catchment-derived alkalinity (Alk) is both transformed and translocated. While the physico-chemical conditions supporting the s ...

2022

Hydration and durability of fast hardening binders incorporating supplementary cementitious materials

Sarra El Housseini

The use of supplementary cementitious materials (SCMs) is widely considered the most promis-ing approach to reduce CO2 emissions relative to cement production. SCMs are not commonly present in binders used for special applications. On the other hand, due t ...

EPFL2022

Clay calcination technology: state-of-the-art review by the RILEM TC 282-CCL

Mohsen Ben Haha, Karen Scrivener, Shashank Bishnoi, François Henri Avet, Adrian Alujas Diaz, Franco Alberto Zunino Sommariva, Anuj Parashar, Alastair Thomas Matthew Marsh

The use of calcined clays as supplementary cementitious materials provides the opportunity to significantly reduce the cement industry's carbon burden; however, use at a global scale requires a deep understanding of the extraction and processing of the cla ...

SPRINGER2022

Oxidation of pyrite (FeS2) and troilite (FeS) impurities in kaolinitic clays after calcination

Karen Scrivener, Franco Alberto Zunino Sommariva

Valorisation of locally available clays for producing blended cements is crucial for a widespread adoption of sustainable binders incorporating these materials. In some places, clays can be intermixed with small amounts of iron sulfides, which could eventu ...

SPRINGER2022

Hydration and mixture design of calcined clay blended cements: review by the RILEM TC 282-CCL

Mohsen Ben Haha, Karen Scrivener, François Henri Avet, Franco Alberto Zunino Sommariva, Anuj Parashar, Sreejith Krishnan, Yuvaraj Dhandapani

The RILEM technical committee 282-CCL: Calcined Clays as Supplementary Cementitious Materials, investigates all the aspects related to calcined clays, from clay exploration and characterization to calcination process, hydration reactions and concrete prope ...

SPRINGER2022

ECO2 framework assessment of limestone powder concrete slabs and columns

Hisham Tarek Mohamed Hafez

Producing limestone powder requires comparably far less energy than the production of ordinary Portland cement (OPC), making it a promising sustainable solution for partial replacement of OPC in concrete. Lower production energy could be translated into lo ...

ELSEVIER2022

The effect of pore microstructure on strength and chloride ingress in blended cement based on low kaolin clay

Karen Scrivener, Diana Londoño Zuluaga

The objective of this study is to analyse the mechanical and durability properties of a high-performance mortars based on low grade kaolin clay and the effect of electrical conductivity and pore microstructure on the chloride penetration resistance. A tota ...

ELSEVIER2022

Investigation of the effect of mineral dissolution on the geomechanical behaviour of geomaterials

Taeheon Kim

Geotechnical engineering scenarios engaged in internal erosion or mineral dissolution were found worldwide, from CO2 sequestration projects to internal erosion of earth dams. Materials subjected to loss of solid phase from their internal fabric vary from s ...

EPFL2022

Strength-promoting mechanism of alkanolamines on limestone-calcined clay cement and the role of sulfate

Karen Scrivener, François Henri Avet, Wilasinee Hanpongpun, Xuerun Li, Hong Huang

This paper reports the strength-promoting mechanism of alkanolamines on limestone-calcined clay cement (LC3). The hydration kinetics, phase formation and microstructure of LC3 with triethanolamine (TEA) or triisopropanolamine (TIPA) were investigated. TEA ...

Pergamon-Elsevier Science Ltd2021

Understanding of the factors slowing down metakaolin reaction in limestone calcined clay cement (LC3) at late ages

Paul Bowen, Mohsen Ben Haha, Karen Scrivener, François Henri Avet, Yosra Briki

Factors which could explain the slowing down of the metakaolin reaction in LC3 blends are investigated. Portlandite availability and the presence of aluminium ions in the pore solution are shown not to be limiting factors. ...

Pergamon-Elsevier Science Ltd2021

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