Publications related to Geophagia

Effect of the mineralogical composition on the elastoplastic hydromechanical response of Opalinus Clay shale

Lyesse Laloui, Alessio Ferrari, Eleonora Crisci

Opalinus Clay is the shale currently under investigation as the host formation for geological radioactive waste disposal in Switzerland. Its hydromechanical response has been widely studied, and the experimental results show a range of values whose dispers ...

2021

Water retention behaviour of compacted and reconstituted scaly clays

Alessio Ferrari

The paper presents the results of an experimental research devoted to investigate the response to suction variations of a scaly clay in compacted and reconstituted conditions. Different experimental techniques (axis translation, vapour equilibrium, dew poi ...

E D P SCIENCES2020

Increasing the kaolinite content of raw clays using particle classification techniques for use as supplementary cementitious materials

Karen Scrivener, Franco Alberto Zunino Sommariva

The adoption of blended cements to reduce the carbon footprint has increased significantly over the last decades. Clays containing kaolinite are a promising choice due to their widespread availability. Kaolinite content is the major factor controlling the ...

ELSEVIER SCI LTD2020

Impacting factors and properties of limestone calcined clay cements (LC3)

Karen Scrivener, Franco Alberto Zunino Sommariva, François Henri Avet, Julien Ston, Aurélie Rosine Favier, Hamed Maraghechi, Wilasinee Hanpongpun

This paper details the main factors influencing the performance of limestone calcined clay cements (LC3). The kaolinite content plays a major role in the rheological properties as well as strength development. Even in the presence of secondary phases, kaol ...

ICE PUBLISHING2019

Hydro-mechanical response of Opalinus Clay shale: dependency on composition and burial depth

Eleonora Crisci

Shales are sedimentary formation currently studied for their involvement in many geo-energy related applications, such as radioactive waste disposal, CO2 sequestration, oil and gas extraction. In Switzerland the Opalinus Clay shale has been selected has ho ...

EPFL2019

Investigation of C-A-S-H composition, morphology and density in Limestone Calcined Clay Cement (LC3)

Karen Scrivener, Emmanuelle Boehm Courjault, François Henri Avet

In this study, the C-A-S-H composition, morphology and density are characterized for Limestone Calcined Clay Cement (LC3-50) blends containing clays with various kaolinite contents. Significant incorporation of aluminium is observed for LC3-50 blends compa ...

Pergamon-Elsevier Science Ltd2019

Hydro-mechanical behaviour of shallow Opalinus Clay shale

Lyesse Laloui, Alessio Ferrari, Eleonora Crisci

In Switzerland, Opalinus Clay shale has been selected as the host formation for radioactive waste disposal. The minimum required depth of the repository is related to the long-lasting isolation required for the disposal (1 million years). During this perio ...

2019

Impact of Mineralogical Composition on Geotechnical Properties of Opalinus Clay

Lyesse Laloui, Alessio Ferrari, Eleonora Crisci

Opalinus Clay is the selected host geomaterial for the construction of underground geological disposals for radioactive waste in Switzerland. The formation has been studied in several sites, i.e. the Mont Terri laboratory, and several boreholes in the nort ...

2019

Performance of Limestone Calcined Clay Cement (LC3) with various kaolinite contents with respect to chloride transport

Karen Scrivener, François Henri Avet, Hamed Maraghechi, Mohammadhadi Kazemi Kamyab

The durability of mortar and paste mixtures with respect to chloride ion ingress was investigated for binary blends of Portland Cement Calcined Clay, and ternary systems of Limestone Calcined Clay Cement (LC3). Five clays from various sources with differen ...

SPRINGER2018

Chloride Transport Behavior of LC3 Binders

Karen Scrivener, François Henri Avet, Hamed Maraghechi

Corrosion of metal reinforcement is the most important durability concern of concrete infrastructures. In this research, chloride transport in mortars prepared using ternary blends of OPC-calcined clay-limestone (LC3) as the cementitious materials is asses ...

SPRINGER2018

Chemical Influence of Pore Pressure on Brine Flow in Clay-Rich Material

Roman Makhnenko, Etienne André Cassini, Danila Mylnikov

Hydromechanical properties of shales are complex due to the involved ma-terial structure, with the solid matrix being mainly formed by swelling clays and porosity dominated by nanometer scale tortuous voids with large aspect ratios. Intrinsic permeability ...

Springer International Publishing2017

Highly filled polymer nanocomposite films derived from novel nanostructured latexes

Riccardo Ruggerone

The overall aim of this thesis has been to assess the potential of latex-based technologies for the preparation of polymer/clay nanocomposites. The key feature of latex-based technologies is that they offer the possibility of improved control of the final ...

EPFL2010

Release kinetics of volatiles from smectite clay minerals

Pascal Clausen

The focus of this thesis was on the mechanisms of release of volatile molecules from smectite clay minerals. The weight loss was monitored by thermogravimetry, differential calorimetry, and mass spectrometry under isothermal conditions and under ramp tempe ...

EPFL2009

Adsorption of low-molecular-weight molecules on the surface of a sodium smectite clay: an ab initio study

John Christopher Plummer, Wanda Andreoni, Pascal Clausen, Alessandro Curioni

We present a study of the adsorption of single molecules of volatiles, such as water, ethanol, ethyl acetate, pyridine, toluene, and n-octane, on the dry surface of a smectite clay using a series of calculations based on density functional theory. Our clay ...

2009

Equilibrium desorption isotherms of water, ethanol, ethyl acetate and toluene on a sodium smectite clay

John Christopher Plummer, Pascal Clausen

Desorption isotherms for water, ethanol, ethyl acetate and toluene from a sodium smectite clay have been determined by both dynamic vapor sorption (DVS) measurements and Knudsen thermogravimetry (KTGA), at the exception of toluene that was measured only by ...

Springer Netherlands2009