Publications related to Permanganate

Probing structural and dynamic properties of MAPbCl3 hybrid perovskite using Mn2+ EPR

Hybrid methylammonium (MA) lead halide perovskites have emerged as materials exhibiting excellent photovoltaic performance related to their rich structural and dynamic properties. Here, we use multifrequency (X-, Q-, and W-band) electron paramagnetic reson ...

Royal Soc Chemistry2024

Microstructure - Electrochemical Surface Reactivity Relationship of Electrochemically Grown Manganese Oxides Films

Roberto Cestaro

This Thesis provides a comprehensive and correlative investigation of the microstructure, chemical state, and electrochemical reactivity of manganese oxide (MnOx) films, aiming to gain a deeper understanding of the deposition and dissolution mechanism of M ...

EPFL2024

Photo-induced environmental remediation, biomedical imaging, and microbial inactivation by Mn-doped semiconductors: critical issues

Juan Kiwi, Sami Rtimi

The Mn-doping/decoration of S-containing semiconductor quantum dots (QDs) determine their photochemical properties and are important in the field of artificial photosynthesis. The Mn-mediated charge-transfer kinetics and energetics in composites of the typ ...

ELSEVIER SCI LTD2021

Permanganate Reduction by Hydrogen Peroxide: Formation of Reactive Manganese Species and Superoxide and Enhanced Micropollutant Abatement

Urs von Gunten, Ke Xu

Permanganate (MnO4-, Mn(VII)) is widely applied at the initial stage of water treatment to, e.g., abate taste and odor compounds, Mn(II) and Fe(II). However, its selectivity limits its application for micropollutant abatement. Hydrogen peroxide (H2O2), whi ...

AMER CHEMICAL SOC2021

Stabilization of high-spin Mn ions in tetra-pyrrolic configuration on copper

Magalí Alejandra Lingenfelder

By means of Mn-Cu transmetalation, we incorporated Mn atoms in an array of TCNQ (7,7,8,8-tetracyanoquinodimethane) grown on Cu(100), forming a long range ordered and commensurate metal-organic coordination network (MOCN). Preliminary Sn alloying of the Cu( ...

ELSEVIER2021

UV and IR Spectroscopy of Transition Metal–Crown Ether Complexes in the Gas Phase: Mn2+(benzo-15-crown-5)(H2O)0–2

Thomas Rizzo, Yoshiya Inokuchi

Ultraviolet photodissociation (UVPD) and IR–UV double-resonance spectroscopy are performed for bare and microhydrated complexes of Mn2+(benzo-15-crown-5), Mn2+(B15C5)(H2O)n (n = 0–2), under cold (∼10 K) gas-phase conditions. Density functional theory (DFT) ...

2019

Targeted design of alpha-MnO2 based catalysts for oxygen reduction

Michael Markus Busch

The paper focuses on theoretical and experimental aspects of an oxide surface optimization for oxygen reduction reaction (ORR). Various doped alpha-MnO2 based electrocatalysts were prepared by microwave-assisted hydrothermal synthesis and electrochemically ...

Pergamon-Elsevier Science Ltd2016

Synthesis of Homogeneous Manganese-Doped Titanium Oxide Nanotubes from Titanate Precursors

László Forró, Arnaud Magrez, Kurt Schenk, Endre Horvath, Bálint Náfrádi, Rita Smajda, Péter Szirmai, Zlatko Mickovic

We report a novel synthesis route of homogeneously manganese-doped TiO2 nanotubes in a broad concentration range. The scroll-type trititanate (H2Ti3O7) nanotubes prepared by hydrothermal synthesis were used as precursors. Mn2+ ions were introduced by an io ...

Amer Chemical Soc2013

Stereoselectivity and electrostatics in charge-transfer Mn- and Cs-TCNQ(4) networks on Ag(100)

Klaus Kern, Andrea Floris, Sebastian Stepanow, Tzu-Chun Tseng, Nasiba Abdurakhmanova

Controlling supramolecular self-assembly is a fundamental step towards molecular nanofabrication, which involves a formidable reverse engineering problem. It is known that a variety of structures are efficiently obtained by assembling appropriate organic m ...

Nature Publishing Group2012

Formation of assimilable organic carbon during oxidation of natural waters with ozone, chlorine dioxide, chlorine, permanganate, and ferrate

Urs von Gunten

Five oxidants, ozone, chlorine dioxide, chlorine, permanganate, and ferrate were studied with regard to the formation of assimilable organic carbon (AOC) and oxalate in absence and presence of cyanobacteria in lake water matrices. Ozone and ferrate formed ...

2011

Monolithic micro-direct methanol fuel cell in PDMS with microfluidic channel-integrated Nafion strip

Martinus Gijs, Meng Shen

We demonstrate a monolithic polymer electrolyte membrane fuel cell by integrating a narrow (200 mu m) Nafion strip in a molded polydimethylsiloxane (PDMS) structure. We propose two designs, based on two 200 mu m-wide and two 80 mu m-wide parallel microflui ...

2009

Ionization and fragmentation of water clusters by fast highly charged ions

Ivano Tavernelli, Pablo Lopez Tarifa

We study the dissociative ionization of water clusters by impact of 12 MeV/u Ni25+ ions. Cold target recoil ion momentum spectroscopy (COLTRIMS) is used to obtain information about stability, energetics and charge mobility of the ionized water clusters. An ...

IOP Publishing2009