Publications related to Period 2 element

Theory-guided development of homogeneous catalysts for the reduction of CO2 to formate, formaldehyde, and methanol derivatives

Matthew Wodrich, Anne-Clémence Corminboeuf, Shubhajit Das, Hanna Hinrika Cramer

The stepwise catalytic reduction of carbon dioxide (CO2) to formic acid, formaldehyde, and methanol opens non-fossil pathways to important platform chemicals. The present article aims at identifying molecular control parameters to steer the selectivity to ...

2023

Band alignment at the CaF2/Si(111) interface through advanced electronic structure calculations

Alfredo Pasquarello, Igor Reshetnyak, Thomas Bischoff

We determine the band alignment at the CaF2/Si(111) interface through various advanced electronic structure methods. This interface is experimentally well studied and serves as an ideal test case to examine the accuracy of theoretical schemes. We use both ...

2020

Beryllium melting and erosion on the upper dump plates in JET during three ITER-like wall campaigns

Olivier Sauter, Ambrogio Fasoli, Basil Duval, Stefano Coda, Yves Martin, Jonathan Graves, Duccio Testa, Patrick Blanchard, Pierre-Thomas Paul Brun, Henri Weisen, Alessandro Pau, Federico Nespoli, Cristian Sommariva, David Pfefferlé, Richard Pitts, Jonathan Marc Philippe Faustin, Yann Camenen, Hamish William Patten, Jan Horacek, Samuel Lanthaler, Javier García Hernández, Marco Wischmeier, Nicola Vianello, Mikhail Maslov, Yao Zhou, Davide Galassi, Antonio José Pereira de Figueiredo, Liang Yao, Dalziel Joseph Wilson, Bernhard Sieglin, Otto Asunta

Data on erosion and melting of beryllium upper limiter tiles, so-called dump plates (DP), are presented for all three campaigns in the JET tokamak with the ITER-like wall. High-resolution images of the upper wall of JET show clear signs of flash melting on ...

IOP Publishing Ltd2019

The effect of beryllium oxide on retention in JET ITER-like wall tiles

Olivier Sauter, Ambrogio Fasoli, Basil Duval, Stefano Coda, Jonathan Graves, Yves Martin, Duccio Testa, Patrick Blanchard, Bruno Emanuel Ferreira De Sousa Correia, Alessandro Pau, Henri Weisen, Cristian Sommariva, David Pfefferlé, Richard Pitts, Jonathan Marc Philippe Faustin, Yann Camenen, Hamish William Patten, Jan Horacek, Samuel Lanthaler, Javier García Hernández, Marco Wischmeier, Nicola Vianello, Mikhail Maslov, Federico Nespoli, Yao Zhou, Davide Galassi, Antonio José Pereira de Figueiredo, Liang Yao, Dalziel Joseph Wilson, Bernhard Sieglin, Otto Asunta

Preliminary results investigating the microstructure, bonding and effect of beryllium oxide formation on retention in the JET ITER-like wall beryllium tiles, are presented. The tiles have been investigated by several techniques: Scanning Electron Microscop ...

Elsevier2019

Identification of BeO and BeOxDy in melted zones of the JET Be limiter tiles: Raman study using comparison with laboratory samples

Olivier Sauter, Ambrogio Fasoli, Basil Duval, Stefano Coda, Martinus Gijs, Jonathan Graves, Yves Martin, Duccio Testa, Patrick Blanchard, Bruno Emanuel Ferreira De Sousa Correia, Alessandro Pau, Pierre-Thomas Paul Brun, Cristian Sommariva, Henri Weisen, Richard Pitts, Sun Hee Kim, Yann Camenen, Jan Horacek, Javier García Hernández, Marco Wischmeier, Mikhail Maslov, Nicola Vianello, Miguel Fernández Ruiz, Federico Nespoli, Antonio José Pereira de Figueiredo, Liang Yao, Yao Zhou, David Pfefferlé, Dalziel Joseph Wilson, Robin Humphry-Baker, Davide Galassi, José Pedro Rebelo Ferreira Marques, Ana Francisca Leal Silva Soares, Jonathan Marc Philippe Faustin, Daniel Scott Alessi, Arnout Lodewijk M Beckers, Julio Rodriguez, Hamish William Patten, Jonnathan Cesar Hidalgo Acosta, , , , , , , , , ,

Thermal Interface Material Enablement of Off-Board Two-Phase Cooling

John Richard Thome, Raffaele Luca Amalfi

Two-phase, refrigerant-based cooling offers significant promise for increasing heat densities and energy efficiencies of electronic components. One barrier to wide spread adoption of two-phase cooling solutions is preserving product features deemed essenti ...

IEEE2018

Axisymmetric oscillations at L-H transitions in JET: M-mode

Nicola Vianello, Antonio José Pereira de Figueiredo, Bernhard Sieglin

L to H transition studies at JET have revealed an n = 0, m = 1 magnetic oscillation starting immediately at the L to H transition (called M-mode for brevity). While the magnetic oscillation is present a weak ELM-less H-mode regime is obtained, with a clear ...

IOP Publishing Ltd2017

Plasma cleaning of beryllium coated mirrors

Cleaning systems of metallic first mirrors are needed in more than 20 optical diagnostic systems from ITER to avoid reflectivity losses. Currently, plasma sputtering is considered as one of the most promising techniques to remove deposits coming from the m ...

Iop Publishing Ltd2016

Excitation of Sodium Atoms Attached to Helium Nanodroplets: The 3p

Marcel Drabbels, Evgeniy Loginov, Alberto Hernando de Castro

The dynamics of Na atoms on the surface of helium nanodroplets following excitation via the 3p

American Chemical Society2015

Hydrogen plasma treatment for improved conductivity in amorphous aluminum doped zinc tin oxide thin films

Christophe Ballif, Aïcha Hessler-Wyser, Quentin Thomas Jeangros, Sylvain Nicolay, Laura Ding, Monica Morales Masis, Fabien Paul Jacques Dauzou

Improving the conductivity of earth-abundant transparent conductive oxides (TCOs) remains an important challenge that will facilitate the replacement of indium-based TCOs. Here, we show that a hydrogen (H-2)-plasma post-deposition treatment improves the co ...

Amer Inst Physics2014

Low Temperature Hermetic Wafer Bonding and Microfabrication of Wall-Coated Alkali Vapor Cells for Chip-Scale Atomic Clocks

Rahel Strässle

The increasing demand for highly precise, yet compact and low power timing devices pushes the research in the field of chip scale atomic clocks (CSACs). At the heart of a CSAC, there is a vapor cell containing a few micrograms of alkali metal, such as rubi ...

EPFL2013

Design and construction of a portable whole-cell living bacterial biosensor for the detection of arsenic in water

Nina Buffi

Contamination of drinking water with arsenic is a recurring problem in both industrialized and developing countries. Supplies for large populations can have concentrations much higher than the permissible levels, set by the World Health Organization (WHO) ...

EPFL2013

Integrated packaging solutions and hotplates for a miniature atomic clock and other microsystems

Fabrizio Vecchio

This thesis aimed at developing innovative packaging solutions for a miniature atomic clock and other microsystems in the cm-scale, i.e. somewhat larger than what is practical for full "chip-scale" device-package integration using clean-room technologies f ...

EPFL2013

How are small endohedral silicon clusters stabilized?

Anne-Clémence Corminboeuf, Fabrice Avaltroni

Clusters in the (Be, B, C)@Si-n((0,1,2+)) (n = 6-10) series, isoelectronic to Si-n(2-), present multiple symmetric structures, including rings, cages and open structures, which the doping atom stabilizes using contrasting bonding mechanisms. The most strik ...

Royal Society of Chemistry2012

Broadband excitation and indirect detection of nitrogen-14 in rotating solids using Delays Alternating with Nutation (DANTE)

Geoffrey Bodenhausen, Simone Ulzega, Marc Anthony Caporini

A train of short rotor-synchronized pulses in the manner of Delays Alternating with Nutations for Tailored Excitation (DANTE) applied to nitrogen-14 nuclei (I = 1) in samples spinning at the magic angle at high frequencies (typically nu(rot) = 62.5 kHz so ...

Academic Press Inc - Elsevier Science2011

Submicro- and Nano-Structured Porous Materials for Production of High-Intensity Exotic Radioactive Ion Beams

Sandrina Fernandes

ISOLDE, the CERN Isotope Separator On-line DEvice is a unique source of low energy beams of radioactive isotopes - atomic nuclei that have too many or too few neutrons to be stable. The facility is like a small 'chemical factory', giving the possibility of ...

EPFL2010

Surfactant-free synthesis of mesoporous and hollow silica nanoparticles with an inorganic template

Barbora Bártová

A surfactant-free synthesis of mesoporous and hollow silica nanoparticles is reported in which boron acts as the templating agent. Using such a simple and mild procedure as a treatment with water, the boron-rich phase is selectively removed, affording meso ...

Royal Society of Chemistry2009

Increased tolerance of sunflower mutant seedlings to Cd and Zn in hydroponic culture

Jean-Paul Schwitzguebel, Erika Nehnevajova

Cadmium and zinc show similarities in their chemistry, geochemistry and environmental properties. Whereas Cd is a phytotoxic non-essential element, Zn is an essential trace element for plant growth and development. Zinc plays a fundamental role in several ...

2009