Publications related to Phosphorus

Global emergent responses of stream microbial metabolism to glacier shrinkage

Tom Ian Battin, Hannes Markus Peter, Massimo Bourquin, Nicola Deluigi, Tyler Joe Kohler, Michail Styllas

Most cryospheric ecosystems are energy limited. How their energetics will respond to climate change remains largely unknown. This is particularly true for glacier-fed streams, which interface with the cryosphere and initiate some of Earth's largest river s ...

Nature Portfolio2024

Electronic Structure of Few-Layer Black Phosphorus from & mu;-ARPES

Nicola Marzari, Marco Gibertini, Samuel Poncé, Christophe Berthod

Black phosphorus (BP) stands out among two-dimensional(2D) semiconductorsbecause of its high mobility and thickness dependent direct band gap.However, the quasiparticle band structure of ultrathin BP has remainedinaccessible to experiment thus far. Here we ...

AMER CHEMICAL SOC2023

Functional and structural characterization of polyphosphate-accumulating organisms in aerobic granular biofilms

Arnaud Michel Gelb

The "Aerobic Granular Sludge" (AGS) technology for wastewater treatment is based on dense microbial biofilm in the form of granular aggregates that have an excellent settling property allowing high biomass concentrations in bioreactors. This promising biol ...

EPFL2023

Biomimetic Photodegradation of Glyphosate in Carborane-Functionalized Nanoconfined Spaces

Kyriakos Stylianou, Arunraj Chidambaram

The removal of organophosphorus (OP) herbicides fromwater hasbeen studied using adsorptive removal, chemical oxidation, electrooxidation,enzymatic degradation, and photodegradation. The OP herbicide glyphosate(GP) is one of the most used herbicides worldwi ...

AMER CHEMICAL SOC2023

Thermal Sintering and Phosphorus Poisoning of a Layered Diesel Oxidation Catalyst

Oliver Kröcher, Davide Ferri

The tightening emission regulations have led to the development of commercial DOCs with zoned or layered formulations allowing to cover a wide range of functionalities (i.e. CO, HC and NO oxidation as well as HC or NOx trap). Aging phenomena in such comple ...

SPRINGER/PLENUM PUBLISHERS2023

Synthesizing the impacts of baseflow contribution on concentration-discharge (C-Q) relationships across Australia using a Bayesian hierarchical model

Camille Roland Marie Minaudo

Understanding concentration-discharge (C - Q) relationships can inform catchment solute and particulate export processes. Previous studies have shown that the extent to which baseflow contributes to streamflow can affect C-Q relationships in some catchment ...

COPERNICUS GESELLSCHAFT MBH2022

The influence of climate on water chemistry states and dynamics in rivers across Australia

Camille Roland Marie Minaudo

For effective water quality management and policy development, spatial variability in the mean concentrations and dynamics of riverine water quality needs to be understood. Using water chemistry (calcium, electrical conductivity, nitrate-nitrite, soluble r ...

WILEY2021

Developing the Catalytic Applications of 1,3,2-Diazaphospholenes

John Henry Reed

The development of new catalytic methods for organic synthesis is a critical endeavour in order to obviate the economic and ecological drawbacks of stoichiometric organic synthesis. While catalysis can offer significant advantages in terms of atom-economy, ...

EPFL2021

Iron phosphate mediated magnetite synthesis: a bioinspired approach

Giulia Mirabello

The biomineralization of intracellular magnetite in magnetotactic bacteria (MTB) is an area of active investigation. Previous work has provided evidence that magnetite biomineralization begins with the formation of an amorphous phosphate-rich ferric hydrox ...

ROYAL SOC CHEMISTRY2021

Valorization of calcium phosphite waste as phosphorus fertilizer: Effects on green manure productivity and soil properties

Alexandre Buttler, Luca Bragazza, Thomas Guillaume, Mathieu Raymond Santonja, Mario Fontana

The potential to use calcium phosphite (Ca-Phi) as phosphorus (P) fertilizer may represent an effective recycling of P-containing by-products. A greenhouse experiment was conducted to investigate the effect of Ca-Phi (38 kg P ha(-1)) on soil properties and ...

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD2021

Delineating Conformation Control in the Photophysical Behaviour of a Molecular Donor-Acceptor-Donor Triad

Shubhajit Das

Mechanochromic luminescent materials, exhibiting a change in luminescence behavior under external stimuli have emerged as one of the promising candidates for upcoming efficient OLEDs. Recently mechanochromic luminescence was reported in a donor-acceptor-do ...

WILEY-V C H VERLAG GMBH2021

Towards an improved understanding of biogeochemical processes across surface-groundwater interactions in intermittent rivers and ephemeral streams

Luis Gómez Gener, Oleksandra Shumilova

Surface-groundwater interactions in intermittent rivers and ephemeral streams (IRES), waterways which do not flow year-round, are spatially and temporally dynamic because of alternations between flowing, non-flowing and dry hydrological states. Interaction ...

2021

Adapting the dynamic LakeMab model to simulate seasonal variations of phosphorus concentration in reservoirs: a case study of Lake Bultiere (France)

Camille Roland Marie Minaudo, Qian Zhang

Controlling phosphorus is fundamental to limit the risk of eutrophication of continental aquatic ecosystems. Integrated modelling of its concentration in the aquatic continuum requires specific tools for water bodies. However, although simple static empiri ...

2020

Ruthenium on phosphorous-modified alumina as an effective and stable catalyst for catalytic transfer hydrogenation of furfural

Oliver Kröcher, Davide Ferri, Gaël Peng, Thibault Xavier Florian Fovanna

Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorous was introduced on a Ru/Al2O3 based catalyst upon impregnation with ammonium hypophosphite followed b ...

2020

Influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene

Shubhajit Das

We report the influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene TerP?PTer (1; Ter = 2,6-Mes(2)C(6)H(3); Mes = 2,4,6-Me3C6H2), a phosphorus-analogue of an alkene. The diphosphene 1 itself is completely inert towards water. Howev ...

ROYAL SOC CHEMISTRY2020

Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays

Andrea Cannizzo, Giulia Fulvia Mancini, Camila Bacellar Cases Da Silveira, Martin Beck, Victoria Kabanova, Samuel Menzi

OLED technology beyond small or expensive devices requires light-emitters, luminophores, based on earth-abundant elements. Understanding and experimental verification of charge transfer in luminophores are needed for this development. An organometallic mul ...

Nature Publishing Group2020

Recent progress in black phosphorus nanostructures as environmental photocatalysts

Sami Rtimi, Yucheng Wu

Hazardous chemicals excruciatingly contaminated water, air, and soil for the past few decades. Eco-friendly techniques to clean and or destroy these harmful chemicals is an urgent requirement at this moment. In this direction, a large number of methodologi ...

ELSEVIER SCIENCE SA2020

Cellulose phosphorylation comparison and analysis of phosphorate position on cellulose fibers

David Lyndon Emsley, Jayasubba Reddy Yarava, Michel Bardet, Julien Bras

Chemical modifications of cellulose fibers as pretreatment for cellulose nanofibrils (CNF) production have been investigated to improve the production process and the quality of obtained cellulosic nanomaterial. In this study, phosphorylation of cellulose ...

ELSEVIER SCI LTD2020

The role of Organophosphate Esters Flame Retardants and plasticizers (OPEs) in Phosphorus Cycle in the atmosphere of the Mediterranean Sea

Athanasios Nenes, Kalliopi Violaki, Christos Panagiotopoulos

The atmosphere is considered as an important external nutrient source for the marine environment, especially in remote ocean waters or the oligotrophic Mediterranean Sea. Phosphorus (P) is a critical nutrient affecting primary productivity in large areas o ...

2020

Tribocorrosion of a CoCrMo alloy in sulfuric acid - Glycerol mixtures

Stefano Mischler, Shoufan Cao

This work reports on the tribocorrosion properties of a CoCrMo alloy sliding under imposed passive potential against alumina in sulfuric acid-glycerol mixtures exhibiting different viscosities and thus, in principle, lubrication properties. As expected, we ...

ELSEVIER SCIENCE SA2020