A method for producing a carbonate-containing species-rich, nitrogen-containing species-free solution from a urea-rich solution is proposed. The method comprising the steps of: providing a first reservoir comprising a first mixture including urea and a cat ...
We study the self-propulsion of a charged colloidal particle that releases ionic species using theory and experiments. We relax the assumptions of thin Debye length and weak nonequilibrium effects assumed in classical phoretic models. This leads to a numbe ...
To reduce the fossil-fuel consumption and the impacts of conventional ammonia production on climate change, green ammonia production processes using green hydrogen need to be investigated. For commercial production scale, potential alternatives can be base ...
Synthesis gas, composed of H-2 and CO, is an important fuel which serves as feedstock for industrially relevant processes, such as methanol or ammonia synthesis. The efficiency of these reactions depends on the H-2 : CO ratio, which can be controlled by a ...
The development of new processes for the selective and sustainable transformation of abundant small molecules constitutes one of the major research areas in inorganic and organometallic chemistry. These molecules as CO2, CO, N2 and H2 are abundant reservoi ...
The main aim of this dissertation is to study the catalytic aspects of very small transition metal clusters supported on h-BN/Rh(111). The catalytic reactions of interest were ammonia synthesis and CO oxidation on mass selected and soft landed iron and pla ...
Using density-functional calculations, we investigate the possibility of ammonia synthesis at supported Fe nanoclusters along catalytic routes closely resembling those in biological nitrogen fixation. To achieve similar catalytic conditions as at the activ ...
The rotational spectrum of cyanic acid, HOCN, has been detected in the centimeter-wave band in a molecular beam by Fourier transform microwave spectroscopy and in the millimeter-wave band by conventional spectroscopy in a low-pressure laboratory discharge. ...