Publications related to Supercooling

Local vs. cooperative: Unraveling glass transition mechanisms with SEER

Which phenomenon slows down the dynamics in supercooled liquids and turns them into glasses is a long-standing question of condensed matter. Most popular theories posit that as the temperature decreases, many events must occur in a coordinated fashion on a ...

National Academy of Sciences2024

Testing Theories of the Glass Transition with the Same Liquid but Many Kinetic Rules

Matthieu Wyart, Carolina Brito Carvalho dos Santos

We study the glass transition by exploring a broad class of kinetic rules that can significantly modify the normal dynamics of supercooled liquids while maintaining thermal equilibrium. Beyond the usual dynamics of liquids, this class includes dynamics in ...

Amer Physical Soc2024

The molecular scale mechanism of deposition ice nucleation on silver iodide

Athanasios Nenes, Mária Lbadaoui-Darvas, André Welti

Heterogeneous ice nucleation is a ubiquitous process in the natural and built environment. Deposition ice nucleation, i.e. heterogeneous ice nucleation that - according to the traditional view - occurs in a subsaturated water vapor environment and in the a ...

Royal Soc Chemistry2024

Quasi-operando Transmission Electron Microscopy Diagnostics for Electrocatalytic Processes in Liquids

Vasiliki Tileli

It is of great interest to the energy community to understand how the mechano-physico-chemical phenomena that eventually lead to device degradation are related to the startup, operation, and shutdown phases. For electrocatalytic systems operating in liquid ...

Swiss Chemical Soc2024

Identification and thermal healing of focused ion beam-induced defects in GaN using off-axis electron holography

Nicolas Grandjean, Jean-François Carlin, Raphaël Butté, Yi Wang

Thermal healing of focused ion beam-implanted defects in GaN is investigated by off-axis electron holography in TEM. The data reveal that healing starts at temperatures as low as about 250 degrees C. The healing processes result in an irreversible transiti ...

Iop Publishing Ltd2024

Snowfall microphysics: a dual-frequency and Doppler spectral radar perspective

Anne-Claire Marie Billault--Roux

Snowfall is an essential component of the hydrological cycle, as it is involved in most precipitation on Earth, either directly as snow falling to the ground or indirectly as rain melted from snow. At the same time, the ice phase of clouds and precipitatio ...

EPFL2023

Electron imaging of gas diffusion electrodes for proton exchange membrane fuel cells

Michele Bozzetti

The current energy crisis demands the development of new sustainable energy sources and devices with low environmental impact, including in the field of electrochemical cells. Mass transport limitations can reduce the overall performance of the device by l ...

EPFL2023

Nanoliter Liquid Packaging in a Bioresorbable Microsystem by Additive Manufacturing and its Application as a Controlled Drug Delivery Device

Jürgen Brugger, Arnaud Bertsch, Cristina Martin Olmos, Jongeon Park

Precise packaging of nanoliter amounts of liquid in a microsystem is important for many biomedical applications. However, existing liquid encapsulation technologies have limitations in terms of liquid waste, evaporation, trapped bubbles, and liquid degrada ...

2023

Phase and microstructure selection in peritectic alloys under high G-V ratio

Wilfried Kurz, Stéphane Dobler

A new model for the case of a superposition of a phase transformation and a microstructure transition from columnar plane front to equiaxed dendritic growth for peritectic alloys is presented. This model is applied to Fe-Ni alloys where a phase transition ...

WALTER DE GRUYTER GMBH2022

Peritectic equilibrium in Fe-Co alloys

Wilfried Kurz

Recent results of directional solidification experiments with Fe-Co alloys were not consistent with the presently accepted peritectic phase diagram. Therefore, the Fe-rich part of this phase diagram was re-examined. High-temperature gradient plane front so ...

WALTER DE GRUYTER GMBH2022

Electron diffraction of deeply supercooled water in no man’s land

Marcel Drabbels, Ulrich Lorenz, Constantin Richard Krüger, Gabriele Bongiovanni, Nathan Junior Mowry

A generally accepted understanding of the anomalous properties of water will only emerge if it becomes possible to systematically characterize water in the deeply supercooled regime, from where the anomalies appear to emanate. This has largely remained elu ...

Nature Research2023

Highly Active Ice‐Nucleating Particles at the Summer North Pole

Julia Schmale

The amount of ice versus supercooled water in clouds is important for their radiative properties and role in climate feedbacks. Hence, knowledge of the concentration of ice-nucleating particles (INPs) is needed. Generally, the concentrations of INPs are fo ...

2022

Freezing-induced stiffness and strength anisotropy in freezing clayey soil: Theory, numerical modeling, and experimental validation

Gioacchino Viggiani, Edward Carlo Giorgio Andò

This paper presents a combined experimental-modeling effort to interpret the coupled thermo-hydro-mechanical behaviors of the freezing soil, where an unconfined, fully saturated clay is frozen due to a temperature gradient. By leveraging the rich experimen ...

WILEY2022

Tomographic Volumetric Additive Manufacturing of Silicon Oxycarbide Ceramics

Jürgen Brugger, Christophe Moser, Paul Delrot, Jorge Andres Madrid Wolff, Max Kollep, Georgia Konstantinou, Damien Claude-Marie Loterie, Antoine Vincent Boniface, Lorenz Hagelüken

Ceramics are highly technical materials with properties of interest for multiple industries. Precisely because of their high chemical, thermal, and mechanical resistance, ceramics are difficult to mold into complex shapes. A possibility to make convoluted ...

2022

Secondary ice production in summer clouds over the Antarctic coast: an underappreciated process in atmospheric models

Athanasios Nenes, Alexis Berne, Georgia Sotiropoulou, Etienne Gabriel Henri Vignon

The correct representation of Antarctic clouds in atmospheric models is crucial for accurate projections of the future Antarctic climate. This is particularly true for summer clouds which play a critical role in the surface melting of the ice shelves in th ...

European Geosciences Union2021

Anomalous interfacial dynamics of single proton charges in binary aqueous solutions

Aleksandra Radenovic, Evgenii Glushkov, Jean Camille Benjamin Comtet, Ahmet Avsar, Miao Zhang

Our understanding of the dynamics of charge transfer between solid surfaces and liquid electrolytes has been hampered by the difficulties in obtaining interface, charge, and solvent-specific information at both high spatial and temporal resolution. Here, w ...

AMER ASSOC ADVANCEMENT SCIENCE2021

Thermal origin of quasilocalized excitations in glasses

Matthieu Wyart, Thomas Willem Jan de Geus, Elisabeth Agoritsas, Wencheng Ji, Marko Popovic

Key aspects of glasses are controlled by the presence of excitations in which a group of particles can rearrange. Surprisingly, recent observations indicate that their density is dramatically reduced and their size decreases as the temperature of the super ...

2020

3D Ordering at the Liquid-Solid Polar Interface of Nanowires

Anna Fontcuberta i Morral, Michele Ceriotti, Cécile Hébert, Duncan Thomas Lindsay Alexander, Gözde Tütüncüoglu, Martin George Friedl, Luca Francaviglia, Mahdi Zamani, Nicolas Tappy, Giulio Imbalzano, Sara Marti Sanchez, Lea Ghisalberti

The nature of the liquid-solid interface determines the characteristics of a variety of physical phenomena, including catalysis, electrochemistry, lubrication, and crystal growth. Most of the established models for crystal growth are based on macroscopic t ...

Wiley2020

Classical nucleation theory predicts the shape of the nucleus in homogeneous solidification

Michele Ceriotti, Bingqing Cheng, Gareth Aneurin Tribello

Macroscopic models of nucleation provide powerful tools for understanding activated phase transition processes. These models do not provide atomistic insights and can thus sometimes lack material-specific descriptions. Here, we provide a comprehensive fram ...

AMER INST PHYSICS2020

Influence of Minor Cr Additions on Crystal Growth in Rapidly Solidified Al-20Zn Alloys

Michel Rappaz

It has been discovered quite recently that Icosahedral Short-Range Order (ISRO) of atoms in the liquid phase of metallic alloys surrounding some trace elements added to the melt can influence both the nucleation and growth of the primary phase. In this wor ...

2020