Templating approaches based on the self-assembly of block-copolymers represent a powerful tool for the preparation of ordered carbon-containing nanomaterials. Combining such strategies with the use of well-defined amphiphilic precursors with sp2-carbon-ric ...
(Chemical Equation Presented) Less carbon: Following a biogenetic proposal, the unusual 6-5-6 carbon skeleton of C19 taiwaniaquinoids was obtained by an intramolecular benzilic acid rearrangement from a C20 precur-sor. A protecting-group-free total synthes ...
The connection of twelve peripheral and divergent dodecyloxy chains to a central tridentate aromatic binding unit provides the dodecacatenar ligand L11, for which room- temperature mesomorphism is detected. An enthalpically unbalanced large melting entropy ...
Various methods for the synthesis of bimetallic complexes, in which two different metal fragments which are connected by two or three halogeno bridges, are reported. The reactions are usually fast and give rise to structurally defined products in quantitat ...
The crystal structure of a strontium-imidazolium polymeric material obtained from the reaction of zwitterionic 1,3-bis(carboxymethyl)-imidazolium with SrCO3 (2:1) in water is reported. The compound crystallized in the orthorhombic space group Pcc2 with a = ...
