Publications related to Polysulfone

Supramolecular Modifications of Semicrystalline Polymers

Supramolecular interactions play an important role in defining the structure and the resulting mechanical properties of materials. For instance, interchain hydrogen-bonding in PAs gives them superior strength and stiffness in engineering materials, while t ...

EPFL2023

Sustainable polyesters via direct functionalization of lignocellulosic sugars

François Maréchal, Harm-Anton Klok, Véronique Michaud, Jeremy Luterbacher, Yves Leterrier, Maxime Alexandre Clément Hedou, Adrien Julien Demongeot, Graham Reid Dick, Christèle Rayroud, Thibault Rambert

The development of sustainable plastics from abundant renewable feedstocks has been limited by the complexity and efficiency of their production, as well as their lack of competitive material properties. Here we demonstrate the direct transformation of the ...

2022

Poly(lactide)/cellulose nanocrystal nanocomposites by high-shear mixing

Véronique Michaud, Nicolas Candau, Oguzhan Oguz, Adrien Julien Demongeot, Mehmet Kerem Citak, Fatma Nalan Cetin

There is currently considerable interest in developing stiff, strong, tough, and heat resistant poly(lactide) (PLA) based materials with improved melt elasticity in response to the increasing demand for sustainable plastics. However, simultaneous optimizat ...

WILEY2021

Mechanistic Study of Diaryl Ether Bond Cleavage during Palladium-Catalyzed Lignin Hydrogenolysis

Jeremy Luterbacher, Yuan Li

Hydrogenolysis has emerged as one of the most effective means of converting polymeric lignin into monoaromatic fragments of value. Reported yields may be higher than for other methods and can exceed the theoretical yields estimated from measures of the con ...

2020

A Sustainable Approach to Produce Stiff, Super-Tough, and Heat-Resistant Poly(lactic acid)-Based Green Materials

Nicolas Candau, Oguzhan Oguz, Mehmet Kerem Citak, Fatma Nalan Cetin

Circumventing inherent embrittlement, poor heat resistance, and melt elasticity of poly(lactic acid) (PLA) without compromising its remarkable stiffness and strength has become a particular challenge in polymer science due to increasing demand for green ma ...

AMER CHEMICAL SOC2019

Nanoscale Selective Passivation of Electrodes Contacting a 2D Semiconductor

Aleksandra Radenovic, Martina Lihter, Michael Graf

2D semiconducting materials have become the central component of various nanoelectronic devices and sensors. For sensors operating in liquid, it is crucial to efficiently block the electron transfer that occurs between the electrodes contacting the 2D mate ...

2019

Semiaromatic Polyamides and Copolyamides Comprising Kinked Repeating Units

Julien Philippe Cretenoud

The replacement of metals with polymer-based materials is considered to be key to reducing weight, cost, and cycle times in different technological applications, including the automotive and aerospace industries. Semiaromatic polyamides are particularly at ...

EPFL2018

Thermal mending in E-glass reinforced poly(epsilon-caprolactone)/epoxy blends

Véronique Michaud, Amaël Maximilien Cohades

Blends of difunctional epoxy monomer with a 4,4'-diaminodiphenylsulfone hardener and poly(epsilon-caprolactone) (PCL) were used as a self-healing matrix in woven glass fibre-reinforced polymer composites (FRPs). FRPs with these blends (containing 0, 25 and ...

Elsevier2017

Damage recovery after impact in E-glass reinforced poly(epsilon-caprolactone)/epoxy blends

Véronique Michaud, Amaël Maximilien Cohades

Damage recovery after low-velocity impact has been assessed in woven E-glass fibre-reinforced polymer composites with an epoxy matrix and a blend of epoxy and 25 vol% of poly(e-caprolactone) (PCL). Impact was carried out at three energy levels (8.5, 17, 34 ...

Elsevier2017

Enhanced permeation arising from dual transport pathways in hybrid polymer-MOF membranes

Wendy Lee Queen, Daniel Teav Sun

The rise of anthropogenic global warming has sparked new interest in developing strategies to mitigate carbon dioxide emissions. Conventional carbon capture processes are not economically viable at scale due to their enormous energy cost. Membrane-based se ...

Royal Society of Chemistry2016

Influence of processing routes on morphology and low strain stiffness of polymer/nanofibrillated cellulose composites

Yves Leterrier, Pierre-Etienne Bourban, John Christopher Plummer, Sylvain Cyril Claude Galland, Lars Berglund

The morphology of polymer/nanofibrillated cellulose (NFC) composite sheets produced using different techniques and its influence on low strain stiffness were assessed by optical and transmission electron microscopy. Solvent processing led to relatively hom ...

Maney Publishing2015

Reversible supramolecular modification of surfaces

Negar Moridi

Enzymes are biocatalysts widely used in a large number of industrial biotech processes as they offer clear advantages over their chemical counterparts. Indeed, enzymes often show high substrate selectivity along with elevated turnover rates. Enzymatic cata ...

EPFL2015

Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) feedstock development and optimization for thermoplastic forming of thin planar and tubular oxygen separation membranes

Stefan Diethelm

This paper presents the processing steps for producing thin planar and tubular oxygen separation membranes by thermoplastic forming of Ba0.5Sr0.5Co0.8Fe0.2O3-delta (BSCF) with polystyrene (PS) and stearic acid (SA) as binder. The influence of powder conten ...

Elsevier Science Bv2013

Design, Synthesis and Characterization of New Nanoparticle Stabilizers and Their Application in Catalysis

Ilaria Biondi

In recent years, a strong emphasis in research towards creating sustainable and environmental friendly chemical processes has propelled the development of novel types of catalytic systems that combine advantages from homogeneous and heterogeneous processes ...

EPFL2011

Time-intensity transformation and internal stress in UV-curable hyperbranched acrylates

Yves Leterrier, Daniel Schmäh, Lars Schmidt

The photocuring of three different highly functional acrylates—Di-pentaerythritol penta/hexaacrylate (DPHA) and two hyperbranched molecules (HBP), one with a stiff polyester and one with a more flexible polyether structure—was investigated by means of phot ...

Springer-Verlag2007

Polysulfones as new organic catalysts : mechanism and development of new strategies for polyol selective semi-protection

Dean Markovic

Even unsubstituted butadiene adds to sulfur dioxide in the hetero-Diels-Alder mode more rapidly than in the chelotropic mode. The sultine can be observed in equilibrium with the diene and the sulfur dioxide only at low temperature and in the presence of CF ...

EPFL2005

Plastics

Thierry Meyer, Philip Nising

A review in 4 sections comprising synthetic methods and prodn. processes of plastics (section I), apparatuses for prodn., processing, and making of plastics (section II), manufg. processes for the most important plastics (section III), and processing of th ...

Wiley-VCH2005

Continuous delivery of human and mouse erythropoietin in mice by genetically engineered polymer encapsulated myoblasts

Patrick Aebischer, Nicole Déglon, Bernard Schneider

The transplantation of polymer encapsulated myoblasts genetically engineered to secrete erythropoietin (Epo) may obviate the need for repeated parenteral administration of recombinant Epo as a treatment for chronic renal failure, cancer or AIDS-associated ...

1998