Publications related to Polyester

Biobased Composites from Eugenol- and Coumarin-Derived Methacrylic Latex and Hemp Nanocellulose: Cross-Linking via [2+2] Photocycloaddition and Barrier Properties

A novel-biobased latex was synthesized by redox-initiated emulsion copolymerization of ethoxy dihydroeugenyl methacrylate with 5 wt % of a photosensitive methacrylate containing a coumarin group. A stable copolymer latex having 16 wt % solids content and a ...

Amer Chemical Soc2024

Advances in High-Speed, Multiparametric Atomic Force Microscopy

Santiago Harald Andany

After decades of technological advancements, high-speed atomic force microscopy (HS-AFM) has emerged as a powerful technique for visualizing dynamic processes. At the nanoscale, the AFM provides valuable insights into the sample by sensing minute interacti ...

EPFL2024

New Polymers from Biomass-Derived Hydroxycinnamic Acid Derivatives

Ghezae Tekleab

Polymers play a central role in shaping our world across various fields, but their heavy reliance on petrochemicals poses climate change, environmental and health risks. To address and alleviate these issues, transitioning to sustainable polymers, sourced ...

EPFL2024

A novel interfacial polymerization assisted phase inversion process for the facile fabrication of ion-selective nanofiltration membranes

Zongyao Zhou, Tao Liu, Shijie Hu

Interfacial polymerization (IP) and non-solvent induced phase inversion (NIPS) are the two most commonly used mainstream technologies to fabricate separation membranes. Taking their advantages, we developed a simple, facile and scalable method to integrate ...

Elsevier Science Sa2023

Recyclable flame retardant phosphonated epoxy based thermosets enabled via a reactive approach

Véronique Michaud, Valentin Rougier

The development of reusable fire-safe polymers with a prolonged lifetime heralds the switch for a transition towards circular economy. In this framework, we report a novel phosphonated thermoset which is composed of networked phosphonate esters containing ...

ELSEVIER SCIENCE SA2023

On-Demand Cross-Linkable Bottlebrush Polymers for Voltage- Driven Artificial Muscles

Frank Nüesch, Francis Owusu, Yeerlan Adeli

Dielectric elastomer actuators (DEAs) generate motion resembling natural muscles in reliability, adaptability, elongation, and frequency of operation. They are highly attractive in implantable soft robots or artificial organs. However, many applications of ...

AMER CHEMICAL SOC2023

Bottlebrush Dielectric Elastomers with Improved Properties for Actuation

Yeerlan Adeli

Dielectric elastomer actuators (DEA) are elastic capacitors composed of a pair of compliant electrodes and a soft dielectric elastomer film sandwiched in between. This kind of stretchable capacitors can be actuated when charged, can generate electricity fr ...

EPFL2023

Acetal-Stabilized Carbohydrates as Novel Platform Molecules for Renewable Polymer Production

Lorenz Perry Manker

To address the rising demand for plastics, it is essential to create new types of polymers that are both highly recyclable and emit minimal amounts of greenhouse gases. These plastics should be derived from readily available, renewable feedstocks. Such eff ...

EPFL2023

A hybrid Selective Laser Sintering based process for the additive manufacturing of architectured composites

Erwan Philippe Guenier

Additive Manufacturing also commonly referred as 3D printing has been given a lot of interest lately. Market is growing exponentially and the aim for obtaining more complex and ready-to use parts is emerging. All the 3D printing processes consist in buildi ...

EPFL2023

Enriching the Computational Toolbox for Organocatalysis

Simone Gallarati

Organocatalysis has evolved significantly over the last decades, becoming a pillar of synthetic chemistry, but traditional theoretical approaches based on quantum mechanical computations to investigate reaction mechanisms and provide rationalizations of ca ...

EPFL2023

A multi scale consolidation model for press moulding of hybrid textiles into complex geometries

Vincent Werlen

Side-by-side hybrid textiles are an intermediate step for the production of fibre-reinforced thermoplastic composites. Press moulding these materials combining reinforcing fibre textiles and thermoplastic matrix textiles or flexible layers is a promising m ...

EPFL2023

Electrospun zein incorporating phycocyanin and Spirulina extract: Fabrication, characterization, and potential application

Niloufar Sharif

Electrospinning was used to develop zein fibers containing phycocyanin and aqueous-ethanolic extract of Spirulina (AEES) for elucidating the potent packaging properties of phycocyanin and AEES on walnut samples. Morphological results revealed that using th ...

Elsevier2023

Sustainable polyesters via direct functionalization of lignocellulosic sugars

François Maréchal, Harm-Anton Klok, Véronique Michaud, Jeremy Luterbacher, Yves Leterrier, Maxime Alexandre Clément Hedou, Adrien Julien Demongeot, Graham Reid Dick, Christèle Rayroud, Thibault Rambert

The development of sustainable plastics from abundant renewable feedstocks has been limited by the complexity and efficiency of their production, as well as their lack of competitive material properties. Here we demonstrate the direct transformation of the ...

2022

Extraction and controlled functionalization of lignin for materials applications

Stefania Bertella

Lignin is a renewable aromatic polymer that due to its abundance and unique chemical structure is a promising candidate to replace aromatic materials that are currently sourced from fossil oil. The same structure of lignin poses however drawbacks for its v ...

EPFL2022

A Kilometre-range Distributed Relative Humidity Fibre Sensor

Tiago Filipe Pimentel Das Neves

Fibre optics sensors have been identified as very good candidates for environmental monitoring inside the silicon detectors operated at CERN's Large Hadron Collider. The objective of this dissertation is the development of a Relative Humidity (RH) distribu ...

EPFL2022

Recycling of Bottle Grade PET: Influence of HDPE Contamination on the Microstructure and Mechanical Performance of 3D Printed Parts

Véronique Michaud, Yves Leterrier, Adrien Julien Demongeot, Joanne Hélène Vaucher-Joset

As part of a project that aims to provide people with disabilities with simple assistive devices in Colombia, the possibility of creating a PET filament that can be printed by Fused Deposition Modelling (FDM) from beverage bottle waste was investigated, wi ...

MDPI2022

Semiaromatic polyamides with enhanced charge carrier mobility

John Christopher Plummer, Holger Frauenrath, Nicolas Candau

The control of local order in polymer semiconductors using non-covalent interactions may be used to engineer materials with interesting combinations of mechanical and optoelectronic properties. To investigate the possibility of preparing n-type polymer sem ...

ROYAL SOC CHEMISTRY2021

Polysulfone Dispersed Liquid Crystals As Promising Materials For Flexible Substrates Of Organic Light Emitting Diodes

Maria-Alexandra Paun

The paper deals with the preparation and investigation of a series of polymer dispersed liquid crystals (PDLCs) based on polysulfone matrix and an azomethine liquid crystal. The PDLC systems were prepared by thermal induced phase separation method. Their m ...

UNIV POLITEHNICA BUCHAREST, SCI BULL2021

Development and Characterization of Rice Husk and Recycled Polypropylene Composite Filaments for 3D Printing

Véronique Michaud

Nowadays the use of natural fiber composites has gained significant interest due to their low density, high availability, and low cost. The present study explores the development of sustainable 3D printing filaments based on rice husk (RH), an agricultural ...

2021

Advanced methods for Brillouin based distributed optical fiber sensors

Simon Adrien Zaslawski

After more than thirty years of continuous research and development, the performances of conventional Brillouin based distributed optical fiber sensors (DOFS) are now peaking, as they are facing fundamental barriers that restrict the power of the light inj ...

EPFL2021