Publications related to Polyvinylidene fluoride

Tailor-made Piezoelectric Elastomer Materials

Recent advancements in miniature devices with higher computational capabilities and ultralow power consumption have accelerated the development of wearable sensors, actuators, and energy harvesters everywhere. The ultimate aim of such a technological revol ...

EPFL2023

Additively Manufactured Degradable Piezoelectric Microsystems for Sensing and Actuating

Danick Briand, Luis Guillermo Villanueva Torrijo, Nicolas Francis Fumeaux, Morgan Mc Kay Monroe

The global overabundance of electronic waste and ever-increasing concerns regarding the energy-and material-intensive manufacturing processes associated with traditional electronics are driving the development of solution-processed, degradable electronics. ...

Wiley2023

Low-temperature processing of screen-printed piezoelectric KNbO3 with integration onto biodegradable paper substrates

Danick Briand, Luis Guillermo Villanueva Torrijo, Morgan Mc Kay Monroe

The development of fully solution-processed, biodegradable piezoelectrics is a critical step in the development of green electronics towards the worldwide reduction of harmful electronic waste. However, recent printing processes for piezoelectrics are hind ...

2023

3D printing of elastomeric mechanical sensors designed for human motion monitoring

Ryan Mitchell van Dommelen

In this thesis several advances are made to the emerging field of 3D printed mechanical sensors. Techniques and processes were developed to enable the integration of highly conductive, and capacitive and piezoresistive sensing features embedded within 3D p ...

EPFL2022

Stretchable High Response Piezoelectric Elastomers Based on Polable Polynorbornene Fillers in a Polydimethylsiloxane Matrix

Frank Nüesch, Francis Owusu

To advance the field of piezoelectrics, it is desirable to find materials that combine high piezoelectricity with high elasticity. Applications such as self-sensors, stretchable electronics, soft robots, and energy harvesting would benefit tremendously. Ho ...

WILEY-V C H VERLAG GMBH2022

A life cycle analysis of novel lightweight composite processes: Reducing the environmental footprint of automotive structures

Véronique Michaud, Baris Çaglar, Colin Gomez, Vincent Werlen, Christian Rytka

In this study, three novel thermoplastic impregnation processes were analyzed towards automotive applications. The first process is thermoplastic compression resin transfer molding in which a glass fiber mat is impregnated in through thickness by a thermop ...

ELSEVIER SCI LTD2022

De Novo Crystal Structure Determination from Machine Learned Chemical Shifts

David Lyndon Emsley, Albert Hofstetter, Manuel Cordova, Martins Balodis

Determination of the three-dimensional atomic-level structure of powdered solids is one of the key goals in current chemistry. Solid-state NMR chemical shifts can be used to solve this problem, but they are limited by the high computational cost associated ...

2022

Chemo- and regio-divergent access to fluorinated 1-alkyl and 1-acyl triazenes from alkynyl triazenes

Kay Severin, Nicolai Cramer, Carl Thomas Bormann, Jin Fay Tan

The 1,1,2,2-tetrafluoroethylene unit is prevalent in bioactive molecules and functional materials. Despite being in principle a straightforward strategy to access this motif, the direct tetrafluorination of alkynes involves very hazardous or inconvenient r ...

2022

Surface modified microfibrillated cellulose‐poly(vinylidene fluoride) composites: β‐phase formation, viscoelastic and dielectric performance

Véronique Michaud, Yves Leterrier, Dragan Damjanovic, Mohammed Arif Poothanari

The effect of silylation of microfibrillated cellulose (MFC) surfaces on β‐phase formation in poly(vinylidene difluoride) (PVDF) and the resulting viscoelastic and dielectric performance of MFC‐PVDF composites is investigated. Two different organosilanes, ...

2021

Interface-Dominated Time-Dependent Behavior of Poled Poly(Vinylidene Fluoride–Trifluoroethylene)/Barium Titanate Composites

Véronique Michaud, Yves Leterrier, Dragan Damjanovic, Sara Dalle Vacche

Composites in which particles of ferroelectric ceramic phase are randomly dispersed in a polymeric matrix are of interest because of flexibility, conformability, and ease of processing. However, their piezoelectric properties are rather low, unless very hi ...

2020

Composite material

Véronique Michaud, Amaël Maximilien Cohades

In a composite material (6), comprising a fibrous reinforcement (3), and a polymer matrix (14), wherein the polymer matrix (14) comprises two interpenetrating phases, namely a thermoset phase and a continuous thermoplastic phase, wherein the thermoset phas ...

2020

Lead-Oxygen Bond Length Distributions of the Relaxor Ferroelectric 0.67PbMg(1/3)Nb(2/3)O(3)-0.33PbTiO(3) from Pb-207 Nuclear Magnetic Resonance

David Lyndon Emsley, Brennan James Walder, Claudia Esther Avalos

We investigate changes in the local environment of Pb-207 sites in the relaxor ferroelectric 0.67PbMg(1/3)Nb(2/3)O(3)-0.33PbTiO(3) using variable temperature magic angle spinning nuclear magnetic resonance. We observe a Gaussian distribution of Pb-207 chem ...

AMER CHEMICAL SOC2019

Dielectric Actuation Techniques at the Nanoscale: Piezoelectricity and Flexoelectricity

Kaitlin Marie Howell

Micro- and nanoelectromechanical systems (MEMS/NEMS) have long shown their potential to disrupt the established technologies. Over the past 15 years, MEMS have become fundamental components in filters, accelerometers, gyroscopes and gas sensors. MEMS are n ...

EPFL2019

Design of High Permittivity Polysiloxane Elastomers for Dielectric Elastomer Transducers

Philip Horst Caspari

Dielectric elastomer transducers consist of a dielectric elastomer between two compliant electrodes. When the elastic capacitor is electrically charged, the dielectric elastomer elongates until a balance of elastic and electrostatic force is reached. Elect ...

EPFL2019

Improved mechanical dispersion or use of coupling agents? Advantages and disadvantages for the properties of fluoropolymer/ceramic composites

Sara Dalle Vacche, Véronique Michaud, Yves Leterrier, Dragan Damjanovic

The aim of this work is to investigate the influence of interfacial chemistry on the properties of fluoropolymer composites, independent of effects derived from changes in morphology, in particular particle dispersion state. A comparative study of solvent ...

2018

Local Structural Heterogeneity and Electromechanical Responses of Ferroelectrics: Learning from Relaxor Ferroelectrics

Dragan Damjanovic

Long-range ordering of dipoles is a key microscopic signature of ferroelectrics. These ordered dipoles form ferroelectric domains, which can be reoriented by electric fields. Relaxor ferroelectrics are a type of ferroelectric where the longrange ordering o ...

2018

Strain generation and energy-conversion mechanisms in lead-based and lead-free piezoceramics

Dragan Damjanovic

Piezoelectric ceramics generate strain through the intrinsic piezoelectric effect, the motion of ferroelectric domain walls, or through field-induced phase transitions. The enhanced piezoelectric properties observed in morphotropic solid solutions arise fr ...

2018

High diffusion barrier and piezoelectric nanocomposites based on polyvinylidene fluoride-trifluoroethylene copolymer and hydrophobized clay

Yves Leterrier, Dragan Damjanovic, Sara Dalle Vacche, Antonia Neels, Olha Sereda, Alex Dommann

Nanocomposites based on polyvinylidene fluoride– trifluoroethylene copolymer and up to 4 vol % of hydrophobized clay nanoparticles are investigated. The structure, piezoelectric properties, and oxygen permeability of solvent cast films are analyzed before ...

Wiley-Blackwell2017

Photoproduction of Hydrogen by Decamethylruthenocene Combined with Electrochemical Recycling

Hubert Girault, Pekka Eero Peljo, Manuel Alejandro Méndez Agudelo, Grégoire Clément Gschwend, Laurent Alexis Clément Vannay, Micheal Diarmaid Scanlon, Lucie Josette Renée Rivier

The photoinduced hydrogen evolution reaction (HER) by decamethylruthenocene, Cp2RuII (Cp=C5Me5), is reported. The use of a metallocene to photoproduce hydrogen is presented as an alternative strategy to reduce protons without involving an additional phot ...

Wiley-Blackwell2017

Thermal mending in E-glass reinforced poly(epsilon-caprolactone)/epoxy blends

Véronique Michaud, Amaël Maximilien Cohades

Blends of difunctional epoxy monomer with a 4,4'-diaminodiphenylsulfone hardener and poly(epsilon-caprolactone) (PCL) were used as a self-healing matrix in woven glass fibre-reinforced polymer composites (FRPs). FRPs with these blends (containing 0, 25 and ...

Elsevier2017