Publications related to Solvent

Development of Sustainable Carbohydrate-Based Solvents by Acetal Functionalisation of Biomass

Organic solvents are ubiquitous in industrial and domestic applications from the production of pharmaceuticals to household consumer products. The negative impact of most traditional solvents, especially aprotic types, on the environment, health, and safet ...

EPFL2024

Separation of CO2 and TFE by using diethanolamine and diisopropylamine

Elia Mercedes Ruiz Pachon, Muhammad Salman

The near-azeotrope mixture of TFE and CO2 is an important concern urging the scientific community to develop new ways for TFE/CO2 separations. In this work, for the first time, Diisopropylamine (DIPA) and Diethanolamine (DEA) are used as solvents for separ ...

Taylor & Francis Inc2024

Continuous Supercritical Water Impregnation Method for the Preparation of Metal Oxide on Activated Carbon Composite Materials

Christian Ludwig

Metal oxide (MexOy) nanomaterials are used as catalysts and/or sorbents in processes taking place in supercritical water (scH2O), which is the “green” solvent needed to obtain energy-relevant products. Their properties are significantly influenced by the s ...

2024

New Polymers from Biomass-Derived Hydroxycinnamic Acid Derivatives

Ghezae Tekleab

Polymers play a central role in shaping our world across various fields, but their heavy reliance on petrochemicals poses climate change, environmental and health risks. To address and alleviate these issues, transitioning to sustainable polymers, sourced ...

EPFL2024

Optically responsive dry cholesteric liquid crystal marbles

Dry liquid crystal marbles are structures that consist of cholesteric liquid crystal (CLC) droplets prepared by the mixture of chiral-doped thermotropic LCs encapsulated by cellulose nanocrystals (CNCs) that have been dried under ambient conditions. The ch ...

Academic Press Inc Elsevier Science2024

Tandem catalysis enables chlorine-containing waste as chlorination reagents

Paul Joseph Dyson, Mingyang Liu, Xinbang Wu

Chlorinated compounds are ubiquitous. However, accumulation of chlorine-containing waste has a negative impact on human health and the environment due to the inapplicability of common disposal methods, such as landfill and incineration. Here we report a su ...

Nature Portfolio2024

Electrolyte engineering via ether solvent fluorination for developing stable non-aqueous lithium metal batteries

Mounir Driss Mensi, Yubo Zhao

Fluorination of solvents, useful for non-aqueous lithium-based batteries, improves the electrochemical stability but decreases the ionic conductivity. Here, the authors report a targeted functionalization of an ether solvent to balance the electrolyte ioni ...

Nature Portfolio2023

A novel interfacial polymerization assisted phase inversion process for the facile fabrication of ion-selective nanofiltration membranes

Zongyao Zhou, Tao Liu, Shijie Hu

Interfacial polymerization (IP) and non-solvent induced phase inversion (NIPS) are the two most commonly used mainstream technologies to fabricate separation membranes. Taking their advantages, we developed a simple, facile and scalable method to integrate ...

Elsevier Science Sa2023

Peptide-Hypervalent Iodine Reagent Chimeras: Enabling Peptide Functionalization and Macrocyclization

Jérôme Waser, Christian Heinis, Xinjian Ji, Xingyu Liu

Herein, we report a novel strategy for the modification of peptides based on the introduction of highly reactive hypervalent iodine reagents-ethynylbenziodoxolones (EBXs)-onto peptides. These peptide-EBXs can be readily accessed, by both solution- and soli ...

Wiley-VCH Verlag GmbH2023

Homogenization theory captures macroscopic flow discontinuities across Janus membranes

François Gallaire, Pier Giuseppe Ledda, Giuseppe Antonio Zampogna, Kevin Wittkowski

Janus membranes, thin permeable structures with chemical and geometrical asymmetric properties, show great potential in industrial separation processes. Yet the link between the micro- and macro-scale behaviours of these membranes needs to be established r ...

Cambridge University Press2023

Tunnel junction sensing of TATP explosive at the single-molecule level

Helena Miljkovic, Radomir Zikic

Triacetone triperoxide (TATP) is a highly potent homemade explosive commonly used in terrorist attacks. Its detection poses a significant challenge due to its volatility, and the lack of portability of current sensing techniques. To address this issue, we ...

Royal Soc Chemistry2023

Role of Ionic Liquids in Perovskite Solar Cells

Mohammad Khaja Nazeeruddin, Yong Ding, Bin Ding, Xianfu Zhang

Although the power conversion efficiency of perovskite solar cells (PSCs) has reached 25.7%, there is still great potential for improvement in their performance and stability. In the past few years, ionic liquids (ILs) have been extensively investigated an ...

WILEY-V C H VERLAG GMBH2023

A colloidal aqueous electrolyte modulated by oleic acid for durable zinc metal anode

Kangning Zhao, Xu Zhang, Di Yang

Continuous dendrites growth, as well as corrosion and side reactions of Zn metal anode seriously hinder the development of aqueous zinc ion batteries. To address these issues, oleic acid (OA) is dispersed into a 2 M ZnSO4 solution to form a novel colloidal ...

ELSEVIER SCIENCE SA2023

Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Dieuwertje Katelijn Modder

In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...

EPFL2023

Green solvents for chemical reactions

Jeremy Luterbacher, Anastasiia Komarova

The present invention relates to Use of a compound of the general formula (I), (II), (III), (IV), (V) or (VI) wherein R1 and R1', R21 and R21', R31 and R31' are the same and are hydrogen, a linear or branched C1 to C18 alkyl, a linear or branched C2 to C18 ...

2022

Mapping Catalyst‐Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions

Nicolai Cramer, Matthew Wodrich, Anne-Clémence Corminboeuf, Miyeon Chang, Simone Gallarati

Group 9 metals, in particular Rh III complexes with cyclopentadienyl ligands, are competent C–H activation catalysts. Recently, a Cp*Rh III catalyzed reaction of alkenes with N -enoxyphthalimides showed divergent outcome based on the solvent, with carboami ...

2022

Solvent-Free Synthesis and Processing of Conductive Elastomer Composites for Green Dielectric Elastomer Transducers

Frank Nüesch

Stretchable electrodes are more suitable for dielectric elastomer transducers (DET) the closer the mechanical characteristics of the electrodes and elastomer are. Here, a solvent-free synthesis and processing of conductive composites with excellent electri ...

WILEY-V C H VERLAG GMBH2022

Modeling non-covalent interactions in condensed phase

Veronika Juraskova

The modeling of non-covalent interactions, solvation effects, and chemical reactions in complex molecular environment is a challenging task. Current state-of-the-art approaches often rely on static computations using implicit solvent models and harmonic ap ...

EPFL2022

Two-dimensional atomically bridged nanoporous silicate-based membranes for gas separation

Mostapha Dakhchoune

The synthesis of molecular-sieving two-dimensional zeolitic membranes by the assembly of crystalline building blocks without resorting to the secondary growth process is highly desirable. The precise pore size for molecular sieving, ultrathin thickness, an ...

EPFL2021

Bioaccessibility of Organic Compounds Associated with Tire Particles Using a Fish In Vitro Digestive Model: Solubilization Kinetics and Effects of Food Coingestion

Kristin Schirmer, Florian Frédéric Vincent Breider, Dominique Grandjean, Benoît Jean Dominique Ferrari, Thibault Béranger Masset, Luke Christopher Harris

Tire and road wear particles (TRWP) account for an important part of the polymer particles released into the environment. There are scientific knowledge gaps as to the potential bioaccessibility of chemicals associated with TRWP to aquatic organisms. This ...

2022