Publications related to Photopolymer

Biobased Composites from Eugenol- and Coumarin-Derived Methacrylic Latex and Hemp Nanocellulose: Cross-Linking via [2+2] Photocycloaddition and Barrier Properties

A novel-biobased latex was synthesized by redox-initiated emulsion copolymerization of ethoxy dihydroeugenyl methacrylate with 5 wt % of a photosensitive methacrylate containing a coumarin group. A stable copolymer latex having 16 wt % solids content and a ...

Amer Chemical Soc2024

Multimaterial Volumetric Printing of Silica-Based Glasses

Christophe Moser, Paul Delrot, Damien Claude-Marie Loterie, Jorge Andres Madrid Wolff, Antoine Vincent Boniface, Roberto Arturo Emma

Silicate glasses have played a major role as structural and functional materials in human civilization since ancient Egypt. Despite their widespread use and importance in modern society, silica glasses with complex geometries are only fabricated in automat ...

Wiley2024

Supramolecular Polymer Brushes Grown by Surface-Initiated Atom Transfer Radical Polymerization from Cucurbit[7]uril-based Non-Covalent Initiators

Harm-Anton Klok, Friederike Katharina Metze, Irene Filipucci

Polymer brushes are densely grafted, chain end-tethered assemblies of polymers that can be produced via surface-initiated polymerization. Typically, this is accomplished using initiators or chain transfer agents that are covalently attached to the substrat ...

Wiley-VCH Verlag GmbH2023

Photocured Nanocellulose Composites: Recent Advances

Yves Leterrier, Aigoul Schreier, Mohammed Arif Poothanari, Julien Bras

This perspective gives an overview of recent progress in thefield of photocured polymer composites based on variousforms of nanocelluloses, with a focus on cellulose nanofibrils. The manufacturing processes and performances of these nanocellulosecomposites ...

AMER CHEMICAL SOC2022

Controlling Light in Scattering Materials for Volumetric Additive Manufacturing

Christophe Moser, Paul Delrot, Jorge Andres Madrid Wolff, Damien Claude-Marie Loterie, Antoine Vincent Boniface

3D printing has revolutionized the manufacturing of volumetric components and structures in many areas. Several fully volumetric light-based techniques have been recently developed thanks to the advent of photocurable resins, promising to reach unprecedent ...

WILEY2022

Three-dimensional fabrication of sub-micron optical waveguides in PDMS and other polymer materials

Giulia Panusa

Optical waveguides are one of the most important photonic components. They are indispensable tools in many of todayâ s technologies because of their capacity of guiding light. In particular, compact, low loss, flexible polymer optical waveguides are cruci ...

EPFL2021

High-resolution tomographic volumetric additive manufacturing

Christophe Moser, Paul Delrot, Damien Claude-Marie Loterie

Tomographic additive manufacturing produces complex parts with a wide range of printable materials but remains limited in terms of resolution. Here, the authors tune the etendue of the light source and accurately control the photopolymerization kinetics us ...

Nature Publishing Group2020

Light-Activated, Bioadhesive, Poly(2-hydroxyethyl methacrylate) Brush Coatings

Dominique Pioletti, Harm-Anton Klok, Peyman Karami, Jian Wang, Nariye Cavusoglu Ataman

Rapid adhesion between tissue and synthetic materials is relevant to accelerate wound healing and to facilitate the integration of implantable medical devices. Most frequently, tissue adhesives are applied as a gel or a liquid formulation. This manuscript ...

American Chemical Society2020

Photoresponsive materials for volumetric additive manufacturing

Christophe Moser, Paul Delrot, Damien Claude-Marie Loterie

Photoresponsive materials for use with a volumetric additive manufacturing system are described herein. Some embodiments of photoresponsive materials described herein include at least one constituent selected from the group consisting of (i) a thiol-contai ...

2020

Photoinitiator-free multi-photon fabrication of compact optical waveguides in polydimethylsiloxane

Demetri Psaltis, Christophe Moser, Ye Pu, Giulia Panusa, Jieping Wang

Compact, low loss flexible optical waveguides are crucial in optofluidic and microfluidic devices for a dense integration of optical functionalities. We demonstrate the fabrication of compact optical waveguides in polydimethylsiloxane through multiphoton l ...

2019

Photoinitiator-free Laser Fabrication of Ultra-compact, Low-loss Waveguides in Polydimethylsiloxane

Demetri Psaltis, Christophe Moser, Ye Pu, Giulia Panusa, Jieping Wang

Owing to its excellent elasticity, wide spectral range of transparency, and outstanding chemical and thermal stability, polydimethylsiloxane (PDMS) is an elastomer of great technological importance, being widely used in the fabrication of microfluidic and ...

SPIE-INT SOC OPTICAL ENGINEERING2018

Development of an in situ controllable polymerization tool and process for hydrogel used to replace nucleus pulposus

Dominique Pioletti, Pierre-Etienne Bourban, Christophe Moser, Andreas Schmocker, Azadeh Khoushabi

Currently implants or tissue replacements are inserted either as a whole implant or by injecting a liquid which polymerizes to form a solid implant at the appropriate location. This is either highly invasive or not controllable. We developed a tool to perf ...

Spie-Int Soc Optical Engineering2015

Miniature probe for the delivery and monitoring of a photopolymerizable material

Dominique Pioletti, Pierre-Etienne Bourban, Christophe Moser, Andreas Schmocker, Azadeh Khoushabi

Photopolymerization is a common method to cure materials initially in a liquid state, such as dental implants or bone or tissue fillers. Recent advances in the development of biocompatible gel- and cement-systems open up an avenue for in situ photopolymeri ...

SPIE Society of Photo-optical Instrumentation Engineers2015

Photopolymerization device for minimally invasive implants: application to nucleus pulposus replacement

Dominique Pioletti, Pierre-Etienne Bourban, Christophe Moser, Andreas Schmocker, Azadeh Khoushabi

Photopolymerization is a common tool to harden materials initially in a liquid state. A surgeon can directly trigger the solidification of a dental implant or a bone or tissue filler. Traditionally, photopolymerization has been used mainly in dentistry. Ov ...

Springer2015

The effectiveness of resin-based repairs on the inert strength recovery of glass

Pieter Christian Louter

Glass used in buildings is often exposed to sources of surface damage which can have a significant effect on its strength. Existing research suggests that the flaws in glass can successfully be repaired by transparent polymeric resins, but the reasons for ...

Elsevier2015

Stress reduction mechanisms during photopolymerization of functionally graded polymer nanocomposite coatings

Véronique Michaud, Yves Leterrier, Tommaso Nardi, Florian Dujonc, Michael Hausmann

From the experimental analysis of the photocuring process in terms of reaction kinetics as well as modulus and shrinkage build-up, the residual stresses arising during the photopolymerization of functionally graded composite coatings based on an acrylate m ...

2015

Inkjet Printed Nanohydrogel Coated Carbon Nanotubes Electrodes For Matrix Independent Sensing

Hubert Girault, Andreas Stephan Lesch, Fernando Cortes Salazar, Véronique Amstutz

Polyacrylamide (PA) based hydrogels are used in several applications including polyacrylamide gel electrophoresis and sensing devices. Homogeneous and compact PA films can be prepared based on chemical or photopolymerization processes. However, the accurat ...

2015

Minimally Invasive Photopolymerization In Intervertebral Disc Tissue Cavities

Dominique Pioletti, Christophe Moser, Pierre-Etienne Bourban, Andreas Schmocker, Azadeh Khoushabi

Photopolymerized hydrogels are commonly used for a broad range of biomedical applications. As long as the polymer volume is accessible, gels can easily be hardened using light illumination. However, in clinics, especially for minimally invasive surgery, it ...

Spie-Int Soc Optical Engineering2014

Characterization of the Network Structure of PEG Diacrylate Hydrogels Formed in the Presence of N-Vinyl Pyrrolidone

Jeffrey Alan Hubbell, Nicola Tirelli

PEGDA hydrogels copolymerized with NVP using free-radical photopolymerization are used in biomedical applications. These networks consist of a poly(acrylate-co-vinyl pyrrolidone) backbone crosslinked with PEG chains whose crosslink density is dependent on ...

Wiley-V C H Verlag Gmbh2014

One-pot photoinduced synthesis of conductive polythiophene-epoxy network films

Marco Sangermano, Federica Sordo

In this paper, we describe a novel methodology for fabricating conductive epoxy-polythiophene network films by simultaneous photoinduced step-growth and cationic ring opening polymerization processes. For this purpose, formulations containing a bifunctiona ...

Elsevier Sci Ltd2013