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Related publications (27)

Synthesis and Structure of Nitride-Bridged Uranium(III) Complexes

Rosario Scopelliti, Marinella Mazzanti, Lucile Sylvie Danielle Chatelain

The reduction of the nitride-bridged diuranium(IV) complex Cs[{U(OSi((OBu)-Bu-t)(3))(3)}(2)(mu-N)] affords the first example of a uranium nitride complex containing uranium in the +III oxidation state. Two nitride-bridged complexes containing the heteromet ...

2016

Facile CO Cleavage by a Multimetallic CsU2 Nitride Complex

Rosario Scopelliti, Marinella Mazzanti, Marta Falcone

Uranium nitrides are important materials with potential for application as fuels for nuclear power generation, and as highly active catalysts. Molecular nitride compounds could provide important insight into the nature of the uranium–nitride bond, but curr ...

Wiley-VCH Verlag GmbH2016

Heterometallic Fe-2(II)-U-V and Ni-2(II)-U-V Exchange-Coupled Single-Molecule Magnets: Effect of the 3d Ion on the Magnetic Properties

Marinella Mazzanti, Lucile Sylvie Danielle Chatelain

Uranium-based compounds have been put forward as ideal candidates for the design of single-molecule magnets (SMMs) with improved properties, but to date, only two examples of exchange-coupled 3d-5f SMM containing uranium have been reported and both are bas ...

Wiley-Blackwell2015

Reduction and immobilization of uranium in the subsurface : controls, mechanisms, and implications for in situ bioremediation

Malgorzata Alicja Stylo

Decades of uranium (U) mining, milling and military use left a legacy of U contamination around the world. The radioactivity and chemical toxicity of U at contaminated sites pose an acute and long-term hazard to human health and the surrounding environment ...

EPFL2015

Valuation of a pumped-storage hydro-plant in a multiple markets framework : a Swiss Case Study

Nikolaos Iliadis

There has been an evolving electricity market structure starting from the spot market and its derivatives, to several other markets such as the Intraday Market, the Balancing Market and the Reserve Capacity Market. The participation in these markets has ch ...

EPFL2015

Speciation and reactivity of uranium products formed during in situ bioremediation in a shallow alluvial aquifer

Rizlan Bernier-Latmani, Elena Suvorova Buffat, Daniel Scott Alessi

In this study, we report the results of in situ U(VI) bioreduction experiments at the Integrated Field Research Challenge site in Rifle, Colorado, USA. Columns filled with sediments were deployed into a groundwater well at the site and, after a period of c ...

Amer Chemical Soc2014

Uranium redox transition pathways in acetate-amended sediments

Rizlan Bernier-Latmani, Elena Suvorova Buffat, Daniel Scott Alessi, Malgorzata Alicja Stylo

Redox transitions of uranium [from U(VI) to U(IV)] in low-temperature sediments govern the mobility of uranium in the environment and the accumulation of uranium in ore bodies, and inform our understanding of Earth's geochemical history. The molecular-scal ...

National Academy of Sciences2013

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