Angular momentum operatorIn quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum problems involving rotational symmetry. Such an operator is applied to a mathematical representation of the physical state of a system and yields an angular momentum value if the state has a definite value for it.
Structure constantsIn mathematics, the structure constants or structure coefficients of an algebra over a field are the coefficients of the basis expansion (into linear combination of basis vectors) of the products of basis vectors. Because the product operation in the algebra is bilinear, by linearity knowing the product of basis vectors allows to compute the product of any elements (just like a matrix allows to compute the action of the linear operator on any vector by providing the action of the operator on basis vectors).
Canonical commutation relationIn quantum mechanics, the canonical commutation relation is the fundamental relation between canonical conjugate quantities (quantities which are related by definition such that one is the Fourier transform of another). For example, between the position operator x and momentum operator px in the x direction of a point particle in one dimension, where [x , px] = x px − px x is the commutator of x and px , i is the imaginary unit, and ħ is the reduced Planck's constant h/2π, and is the unit operator.
Spin (physics)Spin is an intrinsic form of angular momentum carried by elementary particles, and thus by composite particles such as hadrons, atomic nuclei, and atoms. Spin should not be understood as in the "rotating internal mass" sense: spin is a quantized wave property. The existence of electron spin angular momentum is inferred from experiments, such as the Stern–Gerlach experiment, in which silver atoms were observed to possess two possible discrete angular momenta despite having no orbital angular momentum.