Publications related to Natural abundance

The isotopic signature of U(V) during bacterial reduction

Marinella Mazzanti, Rizlan Bernier-Latmani, Margaux Camille Andréa Molinas, Radmila Faizova, Ashley Richards Brown

The two-step electron transfer during bacterial reduction of UVI to UIV is typically accompanied by mass-independent fractionation of the 238U and 235U isotopes, whereby the heavy isotope accumulates in the reduced product. However, the role of the UV inte ...

2024

The rule of four: anomalous distributions in the stoichiometries of inorganic compounds

Nicola Marzari, Marnik Bercx, Carl Simon Adorf, Elena Gazzarrini

Why are materials with specific characteristics more abundant than others? This is a fundamental question in materials science and one that is traditionally difficult to tackle, given the vastness of compositional and configurational space. We highlight he ...

Nature Portfolio2024

Magic Angle Spinning Solid-State 13C Photochemically Induced Dynamic Nuclear Polarization by a Synthetic Donor-Chromophore-Acceptor System at 9.4 T

David Lyndon Emsley, Federico De Biasi, Máté Visegrádi, Michael Allan Hope

Solid-state photochemically induced dynamic nuclear polarization (photo-CIDNP) is a nuclear magnetic resonance spectroscopy technique in which nuclear spin hyperpolarization is generated upon optical irradiation of an appropriate donor-acceptor system. Unt ...

Amer Chemical Soc2024

Homogeneous Environmental Selection Structures the Bacterial Communities of Benthic Biofilms in Proglacial Floodplain Streams

Tom Ian Battin, Hannes Markus Peter, Susheel Bhanu Busi, Grégoire Marie Octave Edouard Michoud, Leïla Ezzat, Massimo Bourquin, Jade Brandani, Tyler Joe Kohler, Stylianos Fodelianakis

Streams draining proglacial floodplains harbor benthic biofilms comprised of diverse microbial communities. These high-mountain ecosystems are rapidly changing with climate warming, and it is therefore critical to better understand the mechanisms underlyin ...

AMER SOC MICROBIOLOGY2023

Excess labile carbon promotes diazotroph abundance in heat-stressed octocorals

Claudia Isabella Pogoreutz

Nitrogen limitation is the foundation of stable coral-algal symbioses. Diazotrophs, prokaryotes capable of fixing N-2 into ammonia, support the productivity of corals in oligotrophic waters, but could contribute to the destabilization of holobiont function ...

ROYAL SOC2023

Assessing sublimation during snow transport and sublimation effects on the isotopic composition of water vapor

Armin Sigmund

Sublimation influences the water storage in snow covers and glaciers, which is important for water use and projections of the sea level rise. Yet, it is challenging to quantify sublimation for large areas or in conditions of snow transport. In-situ measure ...

EPFL2023

Analysis of accretion disc structure and stability using open code for vertical structure

Pascale Jablonka

Detailed chemical abundances of very metal-poor (VMP; [Fe/H] < -2) stars are important for better understanding the first stars, early star formation, and chemical enrichment of galaxies. Big on-going and coming high-resolution spectroscopic surveys provid ...

OXFORD UNIV PRESS2023

Dynamic nuclear polarisation of 1H in Gd-doped In(OH)3

David Lyndon Emsley, Michael Allan Hope, Amrit Venkatesh, Yuxuan Zhang

Dynamic nuclear polarisation (DNP) of solids doped with high-spin metal ions, such as Gd3+, is a useful strategy to enhance the nuclear magnetic resonance (NMR) sensitivity for these samples. Spin diffusion can relay polarisation throughout a sample, which ...

Academic Press Inc - Elsevier Science2023

How much metal did the first stars provide to the ultra-faint dwarfs?

Pascale Jablonka, Yves Revaz, Mahsa Sanati

Numerical simulations of dwarf galaxies have so far failed to reproduce the observed metallicity-luminosity relation, down to the regime of ultra-faint dwarfs (UFDs). We address this issue by exploring how the first generations of metal-free stars (Pop III ...

EDP SCIENCES S A2023

Isotope Ratio - Discharge Relationships of Solutes Derived From Weathering Reactions

Paolo Benettin

To date, the vast majority of studies seeking to link discharge to solute concentrations have been based on representations of fluid age distributions in watersheds that are time-invariant. As increasingly detailed spatial and temporal datasets become avai ...

Amer Journal Science2023

Persistence of the isotopic signature of pentavalent uranium in magnetite

Rizlan Bernier-Latmani, Barbora Bártová, Zezhen Pan

Original data pertaining to the manuscript 'Persistence of the isotopic signature of pentavalent uranium in magnetite' published in Environmental Science and Technology by Zezhen Pan, Yvonne Roebbert, Aaron Beck, Barbora Bartova, Tonya Vitova, Stefan Weyer ...

Zenodo2022

The Pristine survey - XV. A CHIT ESPaDOnS view on the Milky Way halo and disc populations

Pascale Jablonka, Willem Suter, Carmela Lardo, Romain Ely Roland Lucchesi

We present a one-dimensional, local thermodynamic equilibrium homogeneous analysis of 132 stars observed at high resolution with ESPaDOnS. This represents the largest sample observed at high resolution (R similar to 40 000) from the Pristine survey. This s ...

OXFORD UNIV PRESS2022

Presence of algal symbionts affects denitrifying bacterial communities in the sea anemone Aiptasia coral model

Anders Meibom, Nils Rädecker, Claudia Isabella Pogoreutz

The coral-algal symbiosis is maintained by a constant and limited nitrogen availability in the holobiont. Denitrifiers, i.e., prokaryotes reducing nitrate/nitrite to dinitrogen, could contribute to maintaining the nitrogen limitation in the coral holobiont ...

2022

The Pristine survey - XVII. The C-19 stream is dynamically hot and more extended than previously thought

Pascale Jablonka, Carmela Lardo

The C-19 stream is the most metal-poor stellar system ever discovered, with a mean metallicity [Fe/H] = -3.38 +/- 0.06. Its low metallicity dispersion (sigma([Fe/H]) < 0.18 at the 95 per cent confidence level) and variations in sodium abundances strongly s ...

OXFORD UNIV PRESS2022

Persistence of the isotopic signature of pentavalent uranium in magnetite

Rizlan Bernier-Latmani, Barbora Bártová, Zezhen Pan

Uranium isotopic signatures can be harnessed to monitor the reductive remediation of subsurface contamination or to reconstruct paleo-redox environments. However, the mechanistic underpinnings of the isotope fractionation associated with U reduction remain ...

2022

Influence of Microplastics on Microbial Structure, Function, and Mechanical Properties of Stream Periphyton

Kristin Schirmer, Ahmed Tlili, Renata Behra

Periphyton is a freshwater biofilm composed of prokaryotic and eukaryotic communities that occupy rocks and sediments, forming the base of the food web and playing a key role in nutrient cycling. Given the large surface that periphyton comprises, it may al ...

FRONTIERS MEDIA SA2022

Catchment characteristics and seasonality control the composition of microbial assemblages exported from three outlet glaciers of the Greenland Ice Sheet

Tyler Joe Kohler, Martina Andrea Schön

Glacial meltwater drains into proglacial rivers where it interacts with the surrounding landscape, collecting microbial cells as it travels downstream. Characterizing the composition of the resulting microbial assemblages in transport can inform us about i ...

Frontiers Media SA2022

High-useful yield and new autoionizing state of resonantly ionized tungsten

Reto Georg Trappitsch

In order to measure tungsten isotopic composition in presolar stardust grains that contain a limited number of atoms, we developed a new three-photon three-color resonance ionization scheme using titanium:sapphire lasers and the Laser Ionization of Neutral ...

ROYAL SOC CHEMISTRY2022

Oxygen diffusion in garnet: Experimental calibration and implications for timescales of metamorphic processes and retention of primary O isotopic signatures

Anders Meibom, Stéphane Laurent Escrig

Knowledge of oxygen diffusion in garnet is crucial for a correct interpretation of oxygen isotope signatures in natural samples. A series of experiments was undertaken to determine the diffusivity of oxygen in garnet, which remains poorly constrained. The ...

MINERALOGICAL SOC AMER2022

Four years of daily stable water isotope data in stream water and precipitation from three Swiss catchments

Jana Freiin von Freyberg

This dataset contains four years of daily measurements of the natural isotopic composition (2H, 18O) of precipitation and stream water at the Alp catchment (area 47 km2) in Central Switzerland and two of its tributaries (0.7 km2 and 1.6 km2). In addition, ...

Zenodo2021