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Related publications (30)

The Contribution of Mechanical Spectroscopy to Understanding Grain Boundary Sliding

Daniele Mari

This review paper shows that grain boundary sliding (GBS) is a general phenomenon occurring in all classes of inorganic materials: ceramics, metals and composite materials. The occurrence of relaxations attributed to GBS is also quite general and therefore ...

UNIV FED SAO CARLOS, DEPT ENGENHARIA MATERIALS2018

Synthesis and Photophysical Characterization of Cyclometalated Ruthenium Complexes with N-Heterocyclic Carbene Ligands

Mohammad Khaja Nazeeruddin, Sadig Aghazada, Iwan Zimmermann, Valeriu Scutelnic

In the search of new ligand environment for the ruthenium(II) complexes with pyridine-type ligands, we developed seven new cyclometalated ruthenium complexes with N-heterocyclic carbenes (NHCs). In a two-step procedure, we synthesized complexes with the ge ...

American Chemical Society2017

Mechanisms of perfect absorption in nano-composite systems

Olivier Martin, Sebastian Mader

Near-perfect absorption across the entire VIS based on metallic nano-composite materials was realized experimentally by Hedayati et.al. in 2011 and optimized based on simulations by Etrich et.al. in 2014. However, both works did not reveal the mechanisms t ...

2017

Determination of Conduction and Valence Band Electronic Structure of LaTiOxNy Thin Film

Nicola Marzari, Ivano Eligio Castelli, Alexander Wokaun

The nitrogen substitution into the oxygen sites of several oxide materials leads to a reduction of the band gap to the visible-light energy range, which makes these oxynitride semiconductors potential photocatalysts for efficient solar water splitting. Oxy ...

Wiley-V C H Verlag Gmbh2017

Non-invasive continuous monitoring of pro-oxidant effects of engineered nanoparticles on aquatic microorganisms

Olivier Martin, Paul Bowen, Christian Santschi, Volodymyr Koman, Nadia Rachel Von Moos

Engineered nanomaterials (ENMs) are key drivers for the development of highly sophisticated new technologies. As all new attainments, the rapidly increasing used of ENMs raise concerns about their safety for the environment and humans. There is growing evi ...

2017

Spectroelectrochemical analysis of the mechanism of (photo)electrochemical hydrogen evolution at a catalytic interface

Michael Graetzel, Florian Le Formal, Matthew Thomas Mayer, Stanley David Tilley

Multi-electron heterogeneous catalysis is a pivotal element in the ( photo) electrochemical generation of solar fuels. However, mechanistic studies of these systems are difficult to elucidate by means of electrochemical methods alone. Here we report a spec ...

Springer Nature2017

Incremental Kinetic Modeling of Spectroscopic Data using a Reduced Calibration Model

Dominique Bonvin, Julien Léo Billeter

The identification of kinetic models is an important step for the monitoring, control and optimization of chemical processes. Kinetic models are often based on first principles that describe the evolution of concentrations by means of conservation and cons ...

2017

Water-Mediated Ion Pairing: Occurrence and Relevance

Sylvie Roke

We present an overview of the studies of ion pairing in aqueous media of the past decade. In these studies, interactions between ions, and between ions and water, are investigated with relatively novel approaches, including dielectric relaxation spectrosco ...

American Chemical Society2016

Secondary hardening in Co-Ni-Cr super-alloy investigated by Mechanical Spectroscopy

Daniele Mari, Raffaele Cosimati

The effects of thermal treatments on a Co-Ni-Cr super-alloy in the temperature range from 250 degrees C to 900 degrees C, resulting in secondary hardening, have been studied by Mechanical Spectroscopy. The simultaneous evolution of the internal friction sp ...

Elsevier2016

Band-gap tuning of lead halide perovskite using a single step spin-coating deposition process

Mohammad Khaja Nazeeruddin

In this paper, we present a study of the structural and optical properties of organic-inorganic halide-based perovskite semiconductors with band gaps varying from NIR to visible at room temperature. Thin films of nanocrystalline CH3NH3PbI3 with different c ...

Elsevier Science Bv2016

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