Publications related to Hydron (chemistry)

The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface

H2O2 is a versatile chemical and can be generated by the oxygen reduction reaction (ORR) in proton donor solution in molecular solvents or room temperature ionic liquids (IL). We investigated this reaction at interfaces formed by eleven hydrophobic ILs and ...

2021

Negative hydrogen ion dynamics inside the plasma volume of a linear device: Estimates from particle-in-cell calculations

Ivo Furno, Alan Howling, Philippe Frédérique Bruno Guittienne, Rémy Jacquier, Riccardo Agnello

Negative hydrogen or deuterium ions are the precursor particles used to generate a high power beam of neutrals in order to heat the tokamak plasma core of magnetic fusion devices, inject current, and to some extent control instabilities. In the case of ITE ...

2021

Solvent- and Catalyst-Free Carbon Dioxide Capture and Reduction to Formate with Borohydride Ionic Liquid

Paul Joseph Dyson, Andreas Züttel, Loris Giovanni Lombardo, Kun Zhao, Heena Yang

The Cover Feature shows the application of a pyrrolidinium-based ionic liquid with a borohydride anion to simultaneously capture and reduce large amounts of CO2. The ionic liquid cation interacts with CO2, allowing the borohydride to fix and reduce it to t ...

WILEY-V C H VERLAG GMBH2020

Ruthenium on phosphorous-modified alumina as an effective and stable catalyst for catalytic transfer hydrogenation of furfural

Oliver Kröcher, Davide Ferri, Gaël Peng, Thibault Xavier Florian Fovanna

Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorous was introduced on a Ru/Al2O3 based catalyst upon impregnation with ammonium hypophosphite followed b ...

2020

New Approach to Synthesis of Tetralin via Naphthalene Hydrogenation in Supercritical Conditions Using Polymer-Stabilized Pt Nanoparticles

Lioubov Kiwi

Supercritical (SC) fluid technologies are well-established methods in modern green chemical synthesis. Using SC fluids as solvents instead of traditional liquids gives benefits of higher diffusivity and lower viscosity, which allows mass transfer intensifi ...

2020

Surface Potential and Interfacial Water Order at the Amorphous TiO2 Nanoparticle/Aqueous Interface

Sylvie Roke, Arianna Marchioro, Marie Bischoff

Colloidal nanoparticles exhibit unique size-dependent properties differing from their bulk counterpart, which can be particularly relevant for catalytic applications. To optimize surface-mediated chemical reactions, the understanding of the microscopic str ...

2020

Investigation of the low-energy stereodynamics in the Ne(3P2) + N2, CO reactions

Andreas Osterwalder, Junwen Zou

We report on an experimental investigation of the low-energy stereodynamics of the energy transfer reactions Ne(3P2) + X, producing Ne(1S) + X+ and [Ne–X]+ (X = N2 or CO). Collision energies in the range 0.2 K–700 K are obtained by using the merged beam te ...

2020

Specific Ion Effects at the Interface of Nanometer-Sized Droplets in Water: Structure and Stability

Sylvie Roke, Halil Ibrahim Okur, Evangelia Zdrali

The interaction of ions with interfaces influences numerous processes in chemistry, physics, and biology, while different ion species behave differently at hydrophobic or hydrophilic interfaces. Despite its importance, ion specificity and its relation to s ...

2019

Control of the hydrogen:deuterium isotope mixture using pellets in JET

Olivier Sauter, Ambrogio Fasoli, Yiming Li, Basil Duval, Jonathan Graves, Duccio Testa, Patrick Blanchard, Federico Alberto Alfredo Felici, Henri Weisen, Alessandro Pau, Federico Nespoli, Hamish William Patten, Cristian Sommariva, Antoine Pierre Emmanuel Alexis Merle, Samuel Lanthaler, Haomin Sun, Michele Marin, Richard Pitts, Yann Camenen, Jan Horacek, Javier García Hernández, Marco Wischmeier, Nicola Vianello, Mikhail Maslov, Yao Zhou, Davide Galassi, Antonio José Pereira de Figueiredo, Emiliano Fable, Francesca Maria Poli, Daniele Brunetti, Anna Teplukhina, Alberto Mariani, Kenji Tanaka, Bernhard Sieglin, Otto Asunta, Gergely Papp, Leonardo Pigatto

Deuterium pellets are injected into an initially pure hydrogen H-mode plasma in order to control the hydrogen: deuterium (H:D) isotope mixture. The pellets are deposited in the outer 20% of the minor radius, similar to that expected in ITER, creating trans ...

2019

The Diverse Nature of Ion Speciation at the Nanoscale Hydrophobic/Water Interface

Sylvie Roke, Halil Ibrahim Okur, Evangelia Zdrali

Many biological systems are composed of nanoscale structures having hydrophobic and hydrophilic groups adjacent to one another and in contact with aqueous electrolyte solution. The interaction of ions with such structures is of fundamental importance. Alth ...

AMER CHEMICAL SOC2019

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Qian Wang, Jieping Zhu, Wangqing Kong

Pd-catalyzed intramolecular asymmetric carbopalladation of N-aryl acrylamides followed by reduction of C(sp3)-Pd intermediate using diboron–water as a hydride source afforded enantioenriched 3,3-disubstituted oxindoles in high yields and enantioselectiviti ...

Wiley-Blackwell2017

Effects of Pore and Cage Topology on the Thermodynamics of n-Alkane Adsorption at Bronsted Protons in Zeolites at High Temperature

Berend Smit

Monte Carlo simulations are used to systematically investigate the effects of structural topology on the thermodynamics of n-alkanes adsorbed at Bronsted protons in zeolites having one-dimensional channel systems. In zeolites without cages, the enthalpy an ...

American Chemical Society2017

Investigation of the RF efficiency of Inductively Coupled Hydrogen Plasmas at 1MHz

Minh Quang Tran, Stefano Mattei

The power requirements of RF heated sources for negative hydrogen ions in fusion are substantial, which poses strong demands on the generators and components of the RF circuit. Consequently, an increase of the RF coupling efficiency would be highly benefic ...

Amer Inst Physics2017

Synthetic NPA diagnostic for energetic particles in JET plasmas

Henri Weisen

Neutral particle analysis (NPA) is one of the few methods for diagnosing fast ions inside a plasma by measuring neutral atom fluxes emitted due to charge exchange reactions. The JET tokamak features an NPA diagnostic which measures neutral atom fluxes and ...

Iop Publishing Ltd2017

H- ion source for CERN's Linac4 accelerator : simulation, experimental validation and optimization of the hydrogen plasma

Stefano Mattei

Linac4 is the new negative hydrogen ion (H-) linear accelerator of the European Organization for Nuclear Research (CERN). Its ion source operates on the principle of Radio-Frequency Inductively Coupled Plasma (RF-ICP) and it is required to provide 50 mA of ...

EPFL2017

Helicon wave-generated plasmas for negative ion beams for fusion

Ivo Furno, Alan Howling, Philippe Frédérique Bruno Guittienne, Rémy Jacquier, Riccardo Agnello, Gennady Plyushchev, Claudio Marini

In the next generation of fusion reactors, such as DEMO, neutral beam injectors (NBIs) of high energy (0.8-1 MeV) deuterium atom swith high wall-plug efficiency (>50%) will be required to reach burning plasma conditions and to provide a significant amount ...

2017

Efficiency of SPIONs functionalized with polyethylene glycol bis (amine) for heavy metal removal

Heinrich Hofmann, Yongyuth Wanna

Hybrid magnetic nanoparticles based on poly(methylmethacrylate) (PMMA) and super-paramagnetic iron oxide nanopaticles (SPIONs) with selective surface modification has been developed for heavy metal removal by applying external magnetic fields. The nanopart ...

Elsevier2016

Effects of Zeolite Structural Confinement on Adsorption Thermodynamics and Reaction Kinetics for Monomolecular Cracking and Dehydrogenation of n-Butane

Berend Smit

The effects of zeolite structure on the kinetics of n-butane monomolecular cracking and dehydrogenation are investigated for eight zeolites differing in the topology of channels and cages. Monte Carlo simulations are used to calculate enthalpy and entropy ...

American Chemical Society2016

A Simple Liquid-Liquid Biphasic System for Hydrogen Peroxide Generation

Hubert Girault, Gunther Wittstock

Although electron transfer reactions at liquid liquid interfaces have been thoroughly studied in the presence of deliberately added potential determining ions or phase transfer catalysts, little is known about these reactions in the absence of the above sp ...

American Chemical Society2015

Aqueous-phase hydrogenation of alkenes and arenes: The growing role of nano scale catalysts

Paul Joseph Dyson, Zhaofu Fei, Ning Yan, Sviatlana Siankevich, Safak Bulut

In this article we highlight some of the recent developments in the aqueous-phase hydrogenation of alkenes and arenes. The traditional types of water-soluble catalysts applied in aqueous media are outlined together with recent trends towards the developmen ...

Elsevier Science Bv2015