The chemoselective three-phase hydrogenation of an Ombrabulinintermediate based on a nitro-stilbene framework was used as a case study for the formation of the primary amine without affecting the double bond. Two catalysts were tested: Pt nanoparticles sup ...
Reduction of hypochlorite is the most important side reaction in the sodium chlorate reactor leading to high energy losses. Today chromate is added to the reactor solution to minimize the hypochlorite reduction but a replacement is necessary due to health ...
The poisoning effect by hydrogen chloride (HCl) on state-of-the-art Ni anode-supported solid oxide fuel cells (SOFCs) at 750 degrees C is evaluated in either hydrogen or syngas fuel. Experiments are performed on single cells and short stacks and HCl concen ...
Aluminium is a metal extracted from bauxite ore using electrolysis process in cells of big size. A huge electric current goes in the cell through an electrolytic bath and aluminium liquid. These currents generate strong magnetic forces that allow the bath ...
Hematite (alpha-Fe2O3) is a promising semiconductor as photoanode in solar hydrogen production from photoelectrolysis of water due to its appropriate band gap, low cost and high electrochemical stability in aqueous caustic electrolytes. Operation of such p ...
Supplementary cementitious materials (SCM) lower the environmental impact of cement and concrete but react more slowly than Portland cement, which therefore limits the levels of substitution possible as reasonable early strengths are necessary. One of the ...
Calcium silicate hydrate (C-S-H) was synthetized at 20 degrees C to investigate the effect of aluminium uptake (Al/Si = 0-0.33) in the presence and absence of alkalis on the composition and the solubility of a C-S-H with a Ca/Si equal to 1.0. C-S-H incorpo ...
The present paper investigates the variation in performances in steam electrolysis and co-electrolysis of steam/CO2 on SOEC single cells.In electrolysis mode, a sensitivity analysis was performed looking in particular at the effects of temperature (750°C a ...
Calcium silicate hydrate (C-S-H) is the main hydrate phase in Portland cements. Its composition
varies depending on the Ca/Si ratio and on the presence of other ions such as aluminium (called CA-
S-H) or alkalis.
This thesis aimed to study the compositi ...