Publications by Marko Stojanovic

The Rise of Dye-Sensitized Solar Cells: From Molecular Photovoltaics to Emerging Solid-State Photovoltaic Technologies

Shaik Mohammed Zakeeruddin, Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Marko Stojanovic, Natalie Flores Diaz, Yuhang Liu, Jovana Milic, Yameng Ren, Zhongjin Shen, Lukas Pfeifer

Over the past three decades, dye-sensitized solar cells (i. e. Gratzel cells) have evolved from a pioneering concept of molecular photovoltaics to large-scale industrial deployment. In this review article, we provide a historical overview of the developmen ...

WILEY-V C H VERLAG GMBH2021

Understanding the design principles of organic sensitizers for highly efficient dye sensitized solar cells

Marko Stojanovic

The conversion of solar to electrical power has presented itself as a solution to meet the growing energy demand and replace our current fossil fuel dependence, which causes dramatic damages to the environment. At the heart of this challenge lies the perfo ...

EPFL2021

A molecular photosensitizer achieves a Voc of 1.24 V enabling highly efficient and stable dye-sensitized solar cells with copper(II/I)-based electrolyte

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Yiming Cao, Marko Stojanovic, Etienne Christophe Socie, Felix Thomas Eickemeyer, Yameng Ren, Dan Zhang

To develop photosensitizers with high open-circuit photovoltage (Voc) is a crucial strategy to enhance the power conversion efficiency (PCE) of co-sensitized solar cells. Here, we show a judiciously tailored organic photosensitizer, coded MS5, featuring th ...

Nature Research2021

Liquid State and Zombie Dye Sensitized Solar Cells with Copper Bipyridine Complexes Functionalized with Alkoxy Groups

Michael Graetzel, Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Joël Teuscher, Rosario Scopelliti, Ulf Anders Hagfeldt, Marko Stojanovic, Yasemin Saygili, Marina Freitag, Hui-Seon Kim

Copper redox mediators can be employed in dye sensitized solar cells (DSCs) both as liquid electrolytes or as solid state hole transport materials (HTMs). The solid state devices that employ copper complex HTMs can be simply obtained by solvent evaporation ...

2020

Metal Coordination Complexes as Redox Mediators in Regenerative Dye-Sensitized Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Marko Stojanovic, Yasemin Saygili, Natalie Flores Diaz

Dye-sensitized solar cells (DSSCs) have attracted a substantial interest in the last 30 years for the conversion of solar power to electricity. An important component is the redox mediator effecting the transport of charge between the photoelectrode and th ...

2019

Effect of Coordination Sphere Geometry of Copper Redox Mediators on Regeneration and Recombination Behavior in Dye-Sensitized Solar Cell Applications

Jacques-Edouard Moser, Shaik Mohammed Zakeeruddin, Joël Teuscher, Ulf Anders Hagfeldt, Marko Stojanovic, Fabrizio Giordano, Yasemin Saygili, Marina Freitag, Jan Tiepelt

The recombination of injected electrons with oxidized redox species and regeneration behavior of copper redox mediators are investigated for four copper complexes, [Cu(dmby)2]2+/1+ (dmby = 6,6′-dimethyl-2,2′- bipyridine), [Cu(tmby)2]2+/1+ (tmby = 4,4′,6,6′ ...

2018

Electron-Affinity-Triggered Variations on the Optical and Electrical Properties of Dye Molecules Enabling Highly Efficient Dye-Sensitized Solar Cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Péter Kalman Péchy, Ulf Anders Hagfeldt, Yiming Cao, Marko Stojanovic, Mohammad Ibrahim Dar, Yasemin Saygili, Weiwei Zhang, Yuhang Liu

The synthesis, characterization, and photovoltaic performance of a series of indacenodithiophene (IDT)-based D--A organic dyes with varying electron-accepting units is presented. By control of the electron affinity, perfectly matching energy levels were ac ...

Wiley-VCH Verlag GmbH2018

Novel p-dopant toward highly efficient and stable perovskite solar cells

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Marko Stojanovic, Jiyoun Seo, Hui-Seon Kim, Seckin Akin

Li-TFSI is the most common p-dopant for the hole conductor spiro-MeOTAD in the normal structure (n-i-p) of perovskite solar cells (PSCs), which consistently yield the highest power conversion efficiency (PCE) albeit at the risk of lower long-term operation ...

ROYAL SOC CHEMISTRY2018

Redox melts formed by copper (i)/(ii) complexes as charge transfer and charge storage materials

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Yiming Cao, Marko Stojanovic, Marina Freitag

The present invention relates to a redox copper complex melt comprising a metalorganic complex of formula (I) [Cu (La) n ] (I), wherein n is an integer 2; and La is a bidentate ligand selected from a ligand according to any one of formulae (1) and (2): ...

2018

Additives, Hole Transporting Materials and Spectroscopic Methods to Characterize the Properties of Perovskite Films

Michael Graetzel, Shaik Mohammed Zakeeruddin, Nikolaos Vlachopoulos, Ulf Anders Hagfeldt, Marko Stojanovic, Amita Ummadisingu, Jiyoun Seo, Michael Saliba

The achievement of high efficiency and high stability in perovskite solar cells (PSCs) requires optimal selection and evaluation of the various components. After a brief introduction to the perovskite materials and their historical evolution, the first par ...

Schweizerische Chemische Gesellschaft2017

A Structure-Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki-Miyaura Coupling Reactions

Rosario Scopelliti, Xile Hu, Marko Stojanovic, Thomas Clément Di Franco, Sébastien Carlos Keller

A new series of Ni NNN pincer complexes were synthesized and characterized. The main difference among these complexes is the substituents on the side arm amino group(s). No major structural difference was found except for the C-N-C angle of the various sub ...

Wiley-Blackwell2016