Publications by Gaia De Angelis

Control of Buckling of Colloidal Supraparticles

The properties of clusters of colloidal particles, often termed supraparticles, are determined by the arrangement of the primary particles. Therefore, controlling the structure formation process is of key importance. While buckled morphologies can result f ...

Wiley2025

Influence of the hydrophile-lipophile balance of perfluorinated surfactants on the emulsion stability

Esther Amstad, Gaia De Angelis

Emulsions are omnipresent in our everyday life; for example, in food, certain drug and cosmetic formulations, agriculture, and as paints. Moreover, they are frequently used to perform high-throughput screening assays with minimum sample volumes. Key to the ...

Springer Heidelberg2024

From Surfactants to 3D Printing: How Ion-Chelator Pair Interactions Affect the Mechanical Properties of Bioinspired Materials

Gaia De Angelis

The remarkable adaptability observed in marine ecosystems has often inspired researchers when developing new soft materials. The research undertaken in this thesis explores how ion chelator pair interactions influence the mechanical properties of bioinspir ...

EPFL2024

Recyclable 3D printable single network granular hydrogels

Esther Amstad, Lorenzo Lucherini, Gaia De Angelis

Spherical microgels can be conveniently direct ink written into granular hydrogels because of their rheological properties when jammed. Yet, due to weak interparticle interactions, the resulting granular hydrogels are soft and often disassemble if immersed ...

2024

Integrated Conversion of Lignocellulosic Biomass to Bio-Based Amphiphiles using a Functionalization-Defunctionalization Approach

Jeremy Luterbacher, Esther Amstad, Graham Reid Dick, Stefania Bertella, Songlan Sun, Gaia De Angelis

Concerns over the sustainability and end-of-life properties of fossil-derived surfactants have driven interest in bio-based alternatives. Lignocellulosic biomass with its polar functional groups is an obvious feedstock for surfactant production but its use ...

Wiley-VCH Verlag GmbH2023

Single emulsion drops for photocatalytic water splitting as a membrane-free approach to product separation

Sophia Haussener, Esther Amstad, Swarnava Nandy, Sangram Ashok Savant, Gaia De Angelis

The coevolution of hydrogen and oxygen during photocatalytic water splitting presents a challenge for efficient product separation. Here, we demonstrate membrane-free, drop-based photocatalytic water splitting with inherent product separation and competiti ...

2023

From Surfactants to Viscoelastic Capsules

Esther Amstad, Gaia De Angelis, Natascha Ilena Gray

Micrometer sized capsules are often used as single entities for the encapsulation and release of active ingredients, for example in food, cosmetics, and drug delivery. Important parameters that determine the stability of capsules and the release of reagent ...

WILEY2023

Additive Manufacturing of Porous Biominerals

Esther Amstad, Matteo Hirsch, Gaia De Angelis, Ran Zhao, Tianyu Yuan

Nature fabricates hard functional materials from soft organic scaffolds that are mineralized. To enable an energy-efficient locomotion of these creatures while maintaining their structural stability, nature often renders parts of these minerals porous. Unf ...

WILEY-V C H VERLAG GMBH2023

Rheological Properties of Ionically Crosslinked Viscoelastic 2D Films vs. Corresponding 3D Bulk Hydrogels

Esther Amstad, Gaia De Angelis

Ionically crosslinked hydrogels containing metal coordination motifs have piqued the interest of researchers in recent decades due to their self-healing and adhesive properties. In particular, catechol-functionalized bulk hydrogels have received a lot of a ...

AMER CHEMICAL SOC2023

Extraction and Surfactant Properties of Glyoxylic Acid-Functionalized Lignin

Jeremy Luterbacher, Esther Amstad, Stefania Bertella, Gaia De Angelis

The amphiphilic chemical structure of native lignin, composed by a hydrophobic aromatic core and hydrophilic hydroxy groups, makes it a promising alternative for the development of bio-based surface-active compounds. However, the severe conditions traditio ...

2022