Publication

Cr-poisoning in (La,Sr)(Co,Fe)O-3 cathodes after 10,000 h SOFC stack testing

Jan Van Herle, Aïcha Hessler-Wyser, Josef Andreas Schuler, Zacharie Wuillemin
2012
Journal Articles

Abstract

After 10,000 h solid oxide fuel cell (SOFC) stack operation, the Cr-poisoning situation in (La0.6Sr0.4) (Co0.2Fe0.8)O-3 (LSCF)-based cathode material is depicted in this work. Systematic Cr profiling by energy-dispersive X-ray spectroscopy (EDS), from post-operation samples taken at different locations within the air flow field, reveals Cr accumulation in electrochemically active cathode regions, although the major amount of Cr is trapped in inactive surface-proximal cathode regions; the 20 m LSCF current collector does not fully impede the Cr access to the functional cathode.

Official source

https://infoscience.epfl.ch/entities/publication/0bd08dc5-78f1-42eb-b133-95b2e7511ca2

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Jan Van Herle, Aïcha Hessler-Wyser, Josef Andreas Schuler, Zacharie Wuillemin
2012
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/0bd08dc5-78f1-42eb-b133-95b2e7511ca2

About this result

Related concepts (23)

Solid oxide fuel cell

A solid oxide fuel cell (or SOFC) is an electrochemical conversion device that produces electricity directly from oxidizing a fuel. Fuel cells are characterized by their electrolyte material; the SOFC has a solid oxide or ceramic electrolyte. Advantages of this class of fuel cells include high combined heat and power efficiency, long-term stability, fuel flexibility, low emissions, and relatively low cost. The largest disadvantage is the high operating temperature which results in longer start-up times and mechanical and chemical compatibility issues.

Fuel cell

A fuel cell is an electrochemical cell that converts the chemical energy of a fuel (often hydrogen) and an oxidizing agent (often oxygen) into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen (usually from air) to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied.

Glossary of fuel cell terms

The Glossary of fuel cell terms lists the definitions of many terms used within the fuel cell industry. The terms in this fuel cell glossary may be used by fuel cell industry associations, in education material and fuel cell codes and standards to name but a few. Activation loss See overpotential Adsorption Adsorption is a process that occurs when a gas or liquid solute accumulates on the surface of a solid or a liquid (adsorbent), forming a film of molecules or atoms (the adsorbate).

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