Publications related to Co-Adsorption of Alcohols and Water in JUK-8 Studied Using Quasi-Equilibrated Thermodesorption

Adsorption of Copper by Naturally and Artificially Aged Polystyrene Microplastics and Subsequent Release in Simulated Gastrointestinal Fluid

Florian Frédéric Vincent Breider, Thibault Béranger Masset, Lu Zhou

Microplastics, especially aged microplastics can become vectors of metals from environment to organisms with potential negative effects on food chain. However, a few studies focused on the bioavailability of adsorbed metals and most studies related to aged ...

2024

Multilayer diffusion-barrier composites based on microfibrillated cellulose from wood, bacterial and algae sources

Aigoul Schreier

This work is driven by the effort towards increased environmental sustainability and aims to develop a new food packaging material based on renewable materials, and more specifically cellulose as the most abundant biomass resource on Earth. Focus was on mi ...

EPFL2024

Degradable and Printed Microstrip Line for Chipless Temperature and Humidity Sensing

Danick Briand, Xavier Aeby, James Alec Pierce Bourely, Jaemin Kim, Oleksandr Vorobyov

Research on chipless and passive architectures for environmental sensing is generating high interest because they do not require any semiconductor components or batteries to operate, thus resulting in an eco-friendlier footprint. This study demonstrates a ...

2024

In-Situ FTIR and Laser Induced Fluorescence RONS Characterization of Atmospheric Pressure Nanosecond-Pulsed Surface DBD Plasma for Indirect Treatments of E. Coli

Ivo Furno, Fabio Avino, Lorenzo Ibba, Rita Agus

We study the bactericidal efficacy of surface dielectric barrier discharge low-temperature plasma treatments, powered by nanosecond high voltage pulses. We achieve similar to 4-log reduction in Escherichia coli population, after 10 min treatments, at a dis ...

Springer2024

The Mn(VII)-H2O2 oxidation process: Abatement of electron-deficient N-containing organic compounds

Urs von Gunten, Ke Xu

Chemical oxidants applied in water treatment are electrophiles, which preferentially attack sites with higher electron density. This typically results in less efficient oxidative abatement of organic compounds with electronwithdrawing substituents. In this ...

Elsevier Science Sa2024

The molecular scale mechanism of deposition ice nucleation on silver iodide

Mária Lbadaoui-Darvas, Athanasios Nenes, André Welti

Heterogeneous ice nucleation is a ubiquitous process in the natural and built environment. Deposition ice nucleation, i.e. heterogeneous ice nucleation that - according to the traditional view - occurs in a subsaturated water vapor environment and in the a ...

Royal Soc Chemistry2024

Comparison of selected surface level ERA5 variables against in‐situ observations in the continental Arctic

Jules Gros-Daillon, Julia Schmale, Jakob Boyd Pernov

In this study, data from 17 ground-based, continental Arctic observatories areused to evaluate the performance of the European Centre for Medium-RangeWeather Forecasts Reanalysis version 5 (ERA5) reanalysis model. Three aspectsare evaluated: (i) the overal ...

2024

Probing Catalytic Sites and Adsorbate Spillover on Ultrathin FeO2-x Film on Ir(111) during CO Oxidation

Harald Brune, Hao Yin, Wei Fang

The spatially resolved identification of active sites on the heterogeneous catalyst surface is an essential step toward directly visualizing a catalytic reaction with atomic scale. To date, ferrous centers on platinum group metals have shown promising pote ...

Amer Chemical Soc2024

Implementation of the ISORROPIA-lite aerosol thermodynamics model into the EMAC chemistry climate model (based on MESSy v2.55): implications for aerosol composition and acidity

Athanasios Nenes, Spyros Pandis

This study explores the differences in performance and results by various versions of the ISORROPIA thermodynamic module implemented within the ECHAM/MESSy Atmospheric Chemistry (EMAC) model. Three different versions of the module were used, ISORROPIA II v ...

Copernicus Gesellschaft Mbh2024

Deposition freezing, pore condensation freezing and adsorption: three processes, one description?

Mária Lbadaoui-Darvas, Athanasios Nenes

Heterogeneous ice nucleation impacts the hydrological cycle and climate through affecting cloud microphysical state and radiative properties. Despite decades of research, a quantitative description and understanding of heterogeneous ice nucleation remains ...

Copernicus GmbH2023

Gas/Surface reactions probed by reflection absorption infrared spectroscopy

Harmina Vejayan

In my thesis, I present an investigation of the dissociation reactions of gas phase molecules on single crystal metal surfaces studied by a molecular beam in combination with Reflection Absorption Infrared Spectroscopy (RAIRS). Two gas/surface systems were ...

EPFL2023

Uncertainty analysis of polymer-based capacitive relative humidity sensor at negative temperatures and low humidity levels

Sandro Carrara, Amar Kapic, Andromachi Tsirou

Capacitive relative humidity sensors, widely used in industrial and environmental applications, should be interchangeable and ideally have parametrizable response to relative humidity changes. While the effects of temperatures in the range between 0 degree ...

ELSEVIER SCI LTD2023

Radiation-tolerant Multichannel Dew Point Temperature Monitoring System for High Energy Physics Applications

Amar Kapic

The next generation of high-energy physics (HEP) detectors will predominantly be silicon-based. As pixel sensor technology gains momentum and the number of channels surpasses one billion (for a volume of approximately 20 m3) to achieve the high resolution ...

EPFL2023

Development of a magnetic calcium-alginate hydrogel-sphere encapsulated with Fe-Mn-Zr ternary metal composite for heavy metal adsorption

Xinyi Huang

Heavy metal contamination has become one of the greatest global environmental problems. In this study, a magnetic calcium-alginate hydrogel-sphere encapsulated with Fe-Mn-Zr ternary-metal composite (MCHETC) was prepared through a combined co-precipitation ...

2023

Selection and Optimal Use of Nanoporous Materials for Adsorption Energy Technologies

Emanuele Piccoli

Due to the large waste of heat in the power and industrial sectors, our use of energy is inefficient. Moreover, it relies on rapidly depleting and greenhouse-gas-emitting sources such as fossil fuels. While the scarcity of energy resources is a relevant so ...

EPFL2023

Dataset for "Biodegradable materials as sensitive coatings for humidity sensing in S-band microwave frequencies"

Danick Briand, James Alec Pierce Bourely, Nicolas Francis Fumeaux, Leticia de Sousa, Oleksandr Vorobyov

This dataset contains the data collected during the SNSF BRIDGE GREENsPACK project (Grant no. 40B2-0_187223) in association with the recent publication entitled “Biodegradable materials as sensitive coatings for humidity sensing in S-band microwave frequen ...

Zenodo2023

Temperature and relative humidity in 10 min time resolution measured in the interstitial inlet of the Swiss container during MOSAiC 2019/2020

Benjamin Jérémy Laurent Heutte, Julia Schmale

This dataset contains the temperature and relative humidity in a bypass to the interstitial inlet, measured during the MOSAiC expedition from October 2019 to September 2020. The measurements were performed in the bypass of the interstitial inlet of the Swi ...

Zenodo2023

Temperature and relative humidity in 10 min time resolution measured in the total inlet of the Swiss container during MOSAiC 2019/2020

Benjamin Jérémy Laurent Heutte, Julia Schmale, Ivo Fabio Beck

This dataset contains the temperature and relative humidity in a bypass to the total inlet, measured during the MOSAiC expedition from October 2019 to September 2020. The measurements were performed in the bypass interstitial inlet of the Swiss container o ...

Zenodo2023

A Robust Framework for Generating Adsorption Isotherms to Screen Materials for Carbon Capture

Seyedmohamad Moosavi, Berend Smit, Elias Moubarak, Susana Garcia Lopez

To rank the performanceof materials for a given carbon captureprocess, we rely on pure component isotherms from which we predictthe mixture isotherms. For screening a large number of materials,we also increasingly rely on isotherms predicted from molecular ...

AMER CHEMICAL SOC2023

Synthesis and Applications of Ynimines and Enantioselective Total Synthesis of Artatrovirenol A

Rémi Hugo Lavernhe

The first chapter of this thesis describe the development of a general synthesis of ynimines, an under-exploited motif in organic chemistry. In the presence of an inexpensive copper catalyst and 2,2'-biquinoline, reaction of easily accessible O-acyloximes ...

EPFL2023