Nuclear magnetic resonance spectroscopyNuclear magnetic resonance spectroscopy, most commonly known as NMR spectroscopy or magnetic resonance spectroscopy (MRS), is a spectroscopic technique to observe local magnetic fields around atomic nuclei. This spectroscopy is based on the measurement of absorption of electromagnetic radiations in the radio frequency region from roughly 4 to 900 MHz. Absorption of radio waves in the presence of magnetic field is accompanied by a special type of nuclear transition, and for this reason, such type of spectroscopy is known as Nuclear Magnetic Resonance Spectroscopy.
Nuclear magnetic resonanceNuclear magnetic resonance (NMR) is a physical phenomenon in which nuclei in a strong constant magnetic field are perturbed by a weak oscillating magnetic field (in the near field) and respond by producing an electromagnetic signal with a frequency characteristic of the magnetic field at the nucleus. This process occurs near resonance, when the oscillation frequency matches the intrinsic frequency of the nuclei, which depends on the strength of the static magnetic field, the chemical environment, and the magnetic properties of the isotope involved; in practical applications with static magnetic fields up to ca.
Main sequenceIn astronomy, the main sequence is a continuous and distinctive band of stars that appears on plots of stellar color versus brightness. These color-magnitude plots are known as Hertzsprung–Russell diagrams after their co-developers, Ejnar Hertzsprung and Henry Norris Russell. Stars on this band are known as main-sequence stars or dwarf stars. These are the most numerous true stars in the universe and include the Sun. After condensation and ignition of a star, it generates thermal energy in its dense core region through nuclear fusion of hydrogen into helium.
Design of experimentsThe design of experiments (DOE or DOX), also known as experiment design or experimental design, is the design of any task that aims to describe and explain the variation of information under conditions that are hypothesized to reflect the variation. The term is generally associated with experiments in which the design introduces conditions that directly affect the variation, but may also refer to the design of quasi-experiments, in which natural conditions that influence the variation are selected for observation.
Pre-main-sequence starA pre-main-sequence star (also known as a PMS star and PMS object) is a star in the stage when it has not yet reached the main sequence. Earlier in its life, the object is a protostar that grows by acquiring mass from its surrounding envelope of interstellar dust and gas. After the protostar blows away this envelope, it is optically visible, and appears on the stellar birthline in the Hertzsprung-Russell diagram. At this point, the star has acquired nearly all of its mass but has not yet started hydrogen burning (i.
A-type main-sequence starAn A-type main-sequence star (A) or A dwarf star is a main-sequence (hydrogen burning) star of spectral type A and luminosity class (five). These stars have spectra defined by strong hydrogen Balmer absorption lines. They measure between 1.4 and 2.1 solar masses () and have surface temperatures between 7,600 and 10,000 K. Bright and nearby examples are Altair (A7), Sirius A (A1), and Vega (A0). A-type stars do not have convective zones and thus are not expected to harbor magnetic dynamos.
G-type main-sequence starA G-type main-sequence star (spectral type: G-V), also often, and imprecisely called a yellow dwarf, or G star, is a main-sequence star (luminosity class V) of spectral type G. Such a star has about 0.9 to 1.1 solar masses and an effective temperature between about 5,300 and 6,000 K. Like other main-sequence stars, a G-type main-sequence star converts the element hydrogen to helium in its core by means of nuclear fusion, but can also fuse helium when hydrogen runs out.
B-type main-sequence starA B-type main-sequence star (B V) is a main-sequence (hydrogen-burning) star of spectral type B and luminosity class V. These stars have from 2 to 16 times the mass of the Sun and surface temperatures between 10,000 and 30,000 K. B-type stars are extremely luminous and blue. Their spectra have strong neutral helium absorption lines, which are most prominent at the B2 subclass, and moderately strong hydrogen lines. Examples include Regulus and Algol A.
F-type main-sequence starAn F-type main-sequence star (F V) is a main-sequence, hydrogen-fusing star of spectral type F and luminosity class V. These stars have from 1.0 to 1.4 times the mass of the Sun and surface temperatures between 6,000 and 7,600 K.Tables VII and VIII. This temperature range gives the F-type stars a whitish hue when observed by the atmosphere. Because a main-sequence star is referred to as a dwarf star, this class of star may also be termed a yellow-white dwarf (not to be confused with white dwarfs, remnant stars that are a possible final stage of stellar evolution).
Nuclear Overhauser effectThe nuclear Overhauser effect (NOE) is the transfer of nuclear spin polarization from one population of spin-active nuclei (e.g. 1H, 13C, 15N etc.) to another via cross-relaxation. A phenomenological definition of the NOE in nuclear magnetic resonance spectroscopy (NMR) is the change in the integrated intensity (positive or negative) of one NMR resonance that occurs when another is saturated by irradiation with an RF field. The change in resonance intensity of a nucleus is a consequence of the nucleus being close in space to those directly affected by the RF perturbation.
K-type main-sequence starA K-type main-sequence star, also referred to as a K-type dwarf red dwarf, or orange dwarf, is a main-sequence (hydrogen-burning) star of spectral type K and luminosity class V. These stars are intermediate in size between red M-type main-sequence stars ("red dwarfs") and yellow/white G-type main-sequence stars. They have masses between 0.6 and 0.9 times the mass of the Sun and surface temperatures between 3,900 and 5,300 K. These stars are of particular interest in the search for extraterrestrial life due to their stability and long lifespan.
In vivo magnetic resonance spectroscopyIn vivo magnetic resonance spectroscopy (MRS) is a specialized technique associated with magnetic resonance imaging (MRI). Magnetic resonance spectroscopy (MRS), also known as nuclear magnetic resonance (NMR) spectroscopy, is a non-invasive, ionizing-radiation-free analytical technique that has been used to study metabolic changes in brain tumors, strokes, seizure disorders, Alzheimer's disease, depression, and other diseases affecting the brain. It has also been used to study the metabolism of other organs such as muscles.
O-type main-sequence starAn O-type main-sequence star (O V) is a main-sequence (core hydrogen-burning) star of spectral type O and luminosity class V. These stars have between 15 and 90 times the mass of the Sun and surface temperatures between 30,000 and 50,000 K. They are between 40,000 and 1,000,000 times as luminous as the Sun. The "anchor" standards which define the MK classification grid for O-type main-sequence stars, i.e. those standards which have not changed since the early 20th century, are (O7 V) and (O9 V).
ExperimentAn experiment is a procedure carried out to support or refute a hypothesis, or determine the efficacy or likelihood of something previously untried. Experiments provide insight into cause-and-effect by demonstrating what outcome occurs when a particular factor is manipulated. Experiments vary greatly in goal and scale but always rely on repeatable procedure and logical analysis of the results. There also exist natural experimental studies.
Scientific controlInformal improvements in any process or enquiry have been made by comparison between what was done previously and the new method for thousands of years. A scientific control is a modern formal experiment or observation designed to minimize the effects of variables other than the independent variable (i.e. confounding variables). This increases the reliability of the results, often through a comparison between control measurements and the other measurements. Scientific controls are a part of the scientific method.
Quasi-experimentA quasi-experiment is an empirical interventional study used to estimate the causal impact of an intervention on target population without random assignment. Quasi-experimental research shares similarities with the traditional experimental design or randomized controlled trial, but it specifically lacks the element of random assignment to treatment or control. Instead, quasi-experimental designs typically allow the researcher to control the assignment to the treatment condition, but using some criterion other than random assignment (e.
Protocol (science)In natural and social science research, a protocol is most commonly a predefined procedural method in the design and implementation of an experiment. Protocols are written whenever it is desirable to standardize a laboratory method to ensure successful replication of results by others in the same laboratory or by other laboratories. Additionally, and by extension, protocols have the advantage of facilitating the assessment of experimental results through peer review.
ResonanceResonance describes the phenomenon of increased amplitude that occurs when the frequency of an applied periodic force (or a Fourier component of it) is equal or close to a natural frequency of the system on which it acts. When an oscillating force is applied at a resonant frequency of a dynamic system, the system will oscillate at a higher amplitude than when the same force is applied at other, non-resonant frequencies. Frequencies at which the response amplitude is a relative maximum are also known as resonant frequencies or resonance frequencies of the system.
Observational studyIn fields such as epidemiology, social sciences, psychology and statistics, an observational study draws inferences from a sample to a population where the independent variable is not under the control of the researcher because of ethical concerns or logistical constraints. One common observational study is about the possible effect of a treatment on subjects, where the assignment of subjects into a treated group versus a control group is outside the control of the investigator.
Electron paramagnetic resonanceElectron paramagnetic resonance (EPR) or electron spin resonance (ESR) spectroscopy is a method for studying materials that have unpaired electrons. The basic concepts of EPR are analogous to those of nuclear magnetic resonance (NMR), but the spins excited are those of the electrons instead of the atomic nuclei. EPR spectroscopy is particularly useful for studying metal complexes and organic radicals. EPR was first observed in Kazan State University by Soviet physicist Yevgeny Zavoisky in 1944, and was developed independently at the same time by Brebis Bleaney at the University of Oxford.
