Publication

Molecular Optomechanics with Plasmons: Backaction at the nanoscale

Christophe Marcel Georges Galland, Tobias Kippenberg, Nicolas Piro Mastracchio
2015
Conference Papers

Abstract

The plasmonic systems used in surface-enhanced Raman scattering are shown to be quivalent to optomechanical cavities. The new backaction force of the plasmon on the molecular vibration could lead to coherent amplification of vibrational motion.

Official source

https://infoscience.epfl.ch/entities/publication/386782ab-7f90-410b-b8b7-560feb02ecc6

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Christophe Marcel Georges Galland, Tobias Kippenberg, Nicolas Piro Mastracchio
2015
Conference Papers

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/386782ab-7f90-410b-b8b7-560feb02ecc6

About this result

Related concepts (12)

Molecular vibration

A molecular vibration is a periodic motion of the atoms of a molecule relative to each other, such that the center of mass of the molecule remains unchanged. The typical vibrational frequencies range from less than 1013 Hz to approximately 1014 Hz, corresponding to wavenumbers of approximately 300 to 3000 cm−1 and wavelengths of approximately 30 to 3 μm. For a diatomic molecule A−B, the vibrational frequency in s−1 is given by , where k is the force constant in dyne/cm or erg/cm2 and μ is the reduced mass given by .

Rotational–vibrational spectroscopy

Rotational–vibrational spectroscopy is a branch of molecular spectroscopy concerned with infrared and Raman spectra of molecules in the gas phase. Transitions involving changes in both vibrational and rotational states can be abbreviated as rovibrational (or ro-vibrational) transitions. When such transitions emit or absorb photons (electromagnetic radiation), the frequency is proportional to the difference in energy levels and can be detected by certain kinds of spectroscopy.

Resonance Raman spectroscopy

Resonance Raman spectroscopy (RR spectroscopy or RRS) is a variant of Raman spectroscopy in which the incident photon energy is close in energy to an electronic transition of a compound or material under examination. This similarity in energy (resonance) leads to greatly increased intensity of the Raman scattering of certain vibrational modes, compared to ordinary Raman spectroscopy. Resonance Raman spectroscopy has much greater sensitivity than non-resonance Raman spectroscopy, allowing for the analysis of compounds with inherently weak Raman scattering intensities, or at very low concentrations.

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