Publication

Modeling of amino acid nanofiltration by irreversible thermodynamics

2009
Journal Articles

Abstract

Starting from the classical Kedem-Katchalsky model for filtration through membranes, we derive an equation to compute the permeate flux and the rejection of diprotic amino acid compounds. We discuss the influence of the pH, the viscosity and the feed concentration of the solution on the transport parameters which characterize the membrane, and we improve the basic equation by accounting for these dependencies. We propose two possible strategies to estimate the transport parameters from experimental data. Finally, we compare our simulation results with experiments of tight ultrafiltration (UF) and nanofiltration (NF). (C) 2009 Elsevier B.V. All rights reserved.

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https://infoscience.epfl.ch/entities/publication/3fbc241c-b3ab-46bb-a5f7-122cc0cb9974

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2009
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/3fbc241c-b3ab-46bb-a5f7-122cc0cb9974

About this result

Related concepts (19)

Irreversible process

In science, a process that is not reversible is called irreversible. This concept arises frequently in thermodynamics. All complex natural processes are irreversible, although a phase transition at the coexistence temperature (e.g. melting of ice cubes in water) is well approximated as reversible. In thermodynamics, a change in the thermodynamic state of a system and all of its surroundings cannot be precisely restored to its initial state by infinitesimal changes in some property of the system without expenditure of energy.

Non-equilibrium thermodynamics

Non-equilibrium thermodynamics is a branch of thermodynamics that deals with physical systems that are not in thermodynamic equilibrium but can be described in terms of macroscopic quantities (non-equilibrium state variables) that represent an extrapolation of the variables used to specify the system in thermodynamic equilibrium. Non-equilibrium thermodynamics is concerned with transport processes and with the rates of chemical reactions.

Laws of thermodynamics

The laws of thermodynamics are a set of scientific laws which define a group of physical quantities, such as temperature, energy, and entropy, that characterize thermodynamic systems in thermodynamic equilibrium. The laws also use various parameters for thermodynamic processes, such as thermodynamic work and heat, and establish relationships between them. They state empirical facts that form a basis of precluding the possibility of certain phenomena, such as perpetual motion.

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