Publication

Solution-Processed Ultrathin SnS2-Pt Nanoplates for Photoelectrochemical Water Oxidation

Kevin Sivula, Liang Yao, Nestor Guijarro Carratala, Yongpeng Liu, Xiaoyun Yu, Ting Zhang, Yong Zuo
2019
Journal Articles

Abstract

Tin disulfide (SnS2) is attracting significant interest because of the abundance of its elements and its excellent optoelectronic properties in part related to its layered structure. In this work, we specify the preparation of ultrathin SnS2 nanoplates (NPLs) through a hot-injection solution-based process. Subsequently, Pt was grown on their surface via in situ reduction of a Pt salt. The photoelectrochemical (PEC) performance of such nanoheterostructures as photoanode toward water oxidation was tested afterwards. Optimized SnS2-Pt photoanodes provided significantly higher photocurrent densities than bare SnS2 and SnS2-based photoanodes of previously reported study. Mott-Schottky analysis and PEC impedance spectroscopy (PEIS) were used to analyze in more detail the effect of Pt on the PEC performance. From these analyses, we attribute the enhanced activity of SnS2-Pt photoanodes reported here to a combination of the very thin SnS2 NPLs and the proper electronic contact between Pt nanoparticles (NPs) and SnS2.

Official source

https://infoscience.epfl.ch/entities/publication/54a42fd9-fb8d-4485-a522-30acaf2ddc25

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Kevin Sivula, Liang Yao, Nestor Guijarro Carratala, Yongpeng Liu, Xiaoyun Yu, Ting Zhang, Yong Zuo
2019
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/54a42fd9-fb8d-4485-a522-30acaf2ddc25

About this result

Related concepts (4)

Photoelectrochemical cell

A "photoelectrochemical cell" is one of two distinct classes of device. The first produces electrical energy similarly to a dye-sensitized photovoltaic cell, which meets the standard definition of a photovoltaic cell. The second is a photoelectrolytic cell, that is, a device which uses light incident on a photosensitizer, semiconductor, or aqueous metal immersed in an electrolytic solution to directly cause a chemical reaction, for example to produce hydrogen via the electrolysis of water.

Water splitting

Water splitting is the chemical reaction in which water is broken down into oxygen and hydrogen: 2 H2O → 2 H2 + O2 Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy, based on green hydrogen. A version of water splitting occurs in photosynthesis, but hydrogen is not produced. The reverse of water splitting is the basis of the hydrogen fuel cell. Electrolysis of water Electrolysis of water is the decomposition of water (H2O) into oxygen (O2) and hydrogen (H2) due to an electric current being passed through the water.

Photocatalytic water splitting

Photocatalytic water splitting is a process that uses photocatalysis for the dissociation of water (H2O) into hydrogen (H2) and oxygen (O2). Only light energy (photons), water, and a catalyst(s) are needed, since this is what naturally occurs in natural photosynthetic oxygen production and CO2 fixation. Photocatalytic water splitting is done by dispersing photocatalyst particles in water or depositing them on a substrate, unlike Photoelectrochemical cell, which are assembled into a cell with a photoelectrode.

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