Self-adjoint operatorIn mathematics, a self-adjoint operator on an infinite-dimensional complex vector space V with inner product (equivalently, a Hermitian operator in the finite-dimensional case) is a linear map A (from V to itself) that is its own adjoint. If V is finite-dimensional with a given orthonormal basis, this is equivalent to the condition that the matrix of A is a Hermitian matrix, i.e., equal to its conjugate transpose A^∗. By the finite-dimensional spectral theorem, V has an orthonormal basis such that the matrix of A relative to this basis is a diagonal matrix with entries in the real numbers.
Creation and annihilation operatorsCreation operators and annihilation operators are mathematical operators that have widespread applications in quantum mechanics, notably in the study of quantum harmonic oscillators and many-particle systems. An annihilation operator (usually denoted ) lowers the number of particles in a given state by one. A creation operator (usually denoted ) increases the number of particles in a given state by one, and it is the adjoint of the annihilation operator.
Schrödinger pictureIn physics, the Schrödinger picture or Schrödinger representation is a formulation of quantum mechanics in which the state vectors evolve in time, but the operators (observables and others) are mostly constant with respect to time (an exception is the Hamiltonian which may change if the potential changes). This differs from the Heisenberg picture which keeps the states constant while the observables evolve in time, and from the interaction picture in which both the states and the observables evolve in time.
Compact operator on Hilbert spaceIn the mathematical discipline of functional analysis, the concept of a compact operator on Hilbert space is an extension of the concept of a matrix acting on a finite-dimensional vector space; in Hilbert space, compact operators are precisely the closure of finite-rank operators (representable by finite-dimensional matrices) in the topology induced by the operator norm. As such, results from matrix theory can sometimes be extended to compact operators using similar arguments.
Hilbert spaceIn mathematics, Hilbert spaces (named after David Hilbert) allow the methods of linear algebra and calculus to be generalized from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise naturally and frequently in mathematics and physics, typically as function spaces. Formally, a Hilbert space is a vector space equipped with an inner product that induces a distance function for which the space is a complete metric space.
Differential operatorIn mathematics, a differential operator is an operator defined as a function of the differentiation operator. It is helpful, as a matter of notation first, to consider differentiation as an abstract operation that accepts a function and returns another function (in the style of a higher-order function in computer science). This article considers mainly linear differential operators, which are the most common type. However, non-linear differential operators also exist, such as the Schwarzian derivative.
Self-adjointIn mathematics, and more specifically in abstract algebra, an element x of a *-algebra is self-adjoint if . A self-adjoint element is also Hermitian, though the reverse doesn't necessarily hold. A collection C of elements of a star-algebra is self-adjoint if it is closed under the involution operation. For example, if then since in a star-algebra, the set {x,y} is a self-adjoint set even though x and y need not be self-adjoint elements. In functional analysis, a linear operator on a Hilbert space is called self-adjoint if it is equal to its own adjoint A^∗.
Spectrum (functional analysis)In mathematics, particularly in functional analysis, the spectrum of a bounded linear operator (or, more generally, an unbounded linear operator) is a generalisation of the set of eigenvalues of a matrix. Specifically, a complex number is said to be in the spectrum of a bounded linear operator if either has no set-theoretic inverse; or the set-theoretic inverse is either unbounded or defined on a non-dense subset. Here, is the identity operator. By the closed graph theorem, is in the spectrum if and only if the bounded operator is non-bijective on .
Schrödinger equationThe Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. Its discovery was a significant landmark in the development of quantum mechanics. The equation is named after Erwin Schrödinger, who postulated the equation in 1925 and published it in 1926, forming the basis for the work that resulted in his Nobel Prize in Physics in 1933. Conceptually, the Schrödinger equation is the quantum counterpart of Newton's second law in classical mechanics.
Hermitian adjointIn mathematics, specifically in operator theory, each linear operator on an inner product space defines a Hermitian adjoint (or adjoint) operator on that space according to the rule where is the inner product on the vector space. The adjoint may also be called the Hermitian conjugate or simply the Hermitian after Charles Hermite. It is often denoted by A† in fields like physics, especially when used in conjunction with bra–ket notation in quantum mechanics.
Unbounded operatorIn mathematics, more specifically functional analysis and operator theory, the notion of unbounded operator provides an abstract framework for dealing with differential operators, unbounded observables in quantum mechanics, and other cases. The term "unbounded operator" can be misleading, since "unbounded" should sometimes be understood as "not necessarily bounded"; "operator" should be understood as "linear operator" (as in the case of "bounded operator"); the domain of the operator is a linear subspace, not necessarily the whole space; this linear subspace is not necessarily closed; often (but not always) it is assumed to be dense; in the special case of a bounded operator, still, the domain is usually assumed to be the whole space.
Rigged Hilbert spaceIn mathematics, a rigged Hilbert space (Gelfand triple, nested Hilbert space, equipped Hilbert space) is a construction designed to link the distribution and square-integrable aspects of functional analysis. Such spaces were introduced to study spectral theory in the broad sense. They bring together the 'bound state' (eigenvector) and 'continuous spectrum', in one place. A function such as is an eigenfunction of the differential operator on the real line R, but isn't square-integrable for the usual Borel measure on R.
Quadratic formIn mathematics, a quadratic form is a polynomial with terms all of degree two ("form" is another name for a homogeneous polynomial). For example, is a quadratic form in the variables x and y. The coefficients usually belong to a fixed field K, such as the real or complex numbers, and one speaks of a quadratic form over K. If , and the quadratic form equals zero only when all variables are simultaneously zero, then it is a definite quadratic form; otherwise it is an isotropic quadratic form.
Operator algebraIn functional analysis, a branch of mathematics, an operator algebra is an algebra of continuous linear operators on a topological vector space, with the multiplication given by the composition of mappings. The results obtained in the study of operator algebras are often phrased in algebraic terms, while the techniques used are often highly analytic. Although the study of operator algebras is usually classified as a branch of functional analysis, it has direct applications to representation theory, differential geometry, quantum statistical mechanics, quantum information, and quantum field theory.
Discrete Laplace operatorIn mathematics, the discrete Laplace operator is an analog of the continuous Laplace operator, defined so that it has meaning on a graph or a discrete grid. For the case of a finite-dimensional graph (having a finite number of edges and vertices), the discrete Laplace operator is more commonly called the Laplacian matrix. The discrete Laplace operator occurs in physics problems such as the Ising model and loop quantum gravity, as well as in the study of discrete dynamical systems.
Decomposition of spectrum (functional analysis)The spectrum of a linear operator that operates on a Banach space is a fundamental concept of functional analysis. The spectrum consists of all scalars such that the operator does not have a bounded inverse on . The spectrum has a standard decomposition into three parts: a point spectrum, consisting of the eigenvalues of ; a continuous spectrum, consisting of the scalars that are not eigenvalues but make the range of a proper dense subset of the space; a residual spectrum, consisting of all other scalars in the spectrum.
Eigenvalues and eigenvectorsIn linear algebra, an eigenvector (ˈaɪgənˌvɛktər) or characteristic vector of a linear transformation is a nonzero vector that changes at most by a constant factor when that linear transformation is applied to it. The corresponding eigenvalue, often represented by , is the multiplying factor. Geometrically, a transformation matrix rotates, stretches, or shears the vectors it acts upon. The eigenvectors for a linear transformation matrix are the set of vectors that are only stretched, with no rotation or shear.
Normal operatorIn mathematics, especially functional analysis, a normal operator on a complex Hilbert space H is a continuous linear operator N : H → H that commutes with its hermitian adjoint N*, that is: NN* = NN. Normal operators are important because the spectral theorem holds for them. The class of normal operators is well understood. Examples of normal operators are unitary operators: N = N−1 Hermitian operators (i.e., self-adjoint operators): N* = N Skew-Hermitian operators: N* = −N positive operators: N = MM* for some M (so N is self-adjoint).
Quantum chemistryQuantum chemistry, also called molecular quantum mechanics, is a branch of physical chemistry focused on the application of quantum mechanics to chemical systems, particularly towards the quantum-mechanical calculation of electronic contributions to physical and chemical properties of molecules, materials, and solutions at the atomic level. These calculations include systematically applied approximations intended to make calculations computationally feasible while still capturing as much information about important contributions to the computed wave functions as well as to observable properties such as structures, spectra, and thermodynamic properties.
Operators in C and C++This is a list of operators in the C and C++ programming languages. All the operators (except typeof) listed exist in C++; the column "Included in C", states whether an operator is also present in C. Note that C does not support operator overloading. When not overloaded, for the operators &&, ||, and , (the comma operator), there is a sequence point after the evaluation of the first operand. C++ also contains the type conversion operators const_cast, static_cast, dynamic_cast, and reinterpret_cast.
