We report a simple and effective method for producing lanthanide ion-doped lithium-fluoride-based nanocrystals (YLiF4). We utilized those nanoparticles for up-conversion in fabricated perovskite solar cells. The obtained results shows that the up-conversion YLiF4:Yb, Er nanoparticles improve alignment of energy levels at interface between titanium dioxide and perovskite layer. This increases power conversion efficiency of fabricated perovskite solar cells from 19.45 % to 21.32 %. To enhance comprehension of the recombination mechanism and its correlation with the conduction band offset and defects, device models are additionally integrated into the SCAPS simulator. Subsequently, the obtained J-V simulation outcomes exhibit a favorable concordance with the experimental observations.
Michael Graetzel, Shaik Mohammed Zakeeruddin, Peng Wang, Felix Thomas Eickemeyer, Ming Ren
Jun Ho Yum, Kevin Sivula, Jiyoun Seo, Parnian Ferdowsi
Manuel Cordova, David Lyndon Emsley, Aditya Mishra, Michael Allan Hope, Ümmügülsüm Günes