Publication

Self-Assembly of a 3d-5f Trinuclear Single-Molecule Magnet from a Pentavalent Uranyl Complex

Marinella Mazzanti, Lucile Sylvie Danielle Chatelain
2014
Journal Articles

Abstract

Mixed-metal uranium compounds are very attractive candidates in the design of single-molecule magnets (SMMs), but only one 3d-5f hetero-polymetallic SMM containing a uranium center is known. Herein, we report two trimeric heterodimetallic 3d-5f complexes self-assembled by cation-cation interactions between a uranyl(V) complex and a TPA-capped M-II complex (M=Mn (1), Cd (2); TPA = tris(2-pyridylmethyl) amine). The metal centers were strategically chosen to promote the formation of discrete molecules rather than extended chains. Compound 1, which contains an almost linear {Mn-O=U=O-Mn} core, exhibits SMM behavior with a relaxation barrier of 81 +/- 0.5 K-the highest reported for a mono-uranium system-arising from intra-molecular Mn-U exchange interactions combined with the high Ising anisotropy of the uranyl(V) moiety. Compound 1 also exhibits an open magnetic hysteresis loop at temperatures less than 3 K, with a significant coercive field of 1.9 T at 1.8 K.

Official source

https://infoscience.epfl.ch/entities/publication/a49308eb-7f1f-420d-a1ca-a4932937e497

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Marinella Mazzanti, Lucile Sylvie Danielle Chatelain
2014
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/a49308eb-7f1f-420d-a1ca-a4932937e497

About this result

Related concepts (29)

Single-molecule magnet

A single-molecule magnet (SMM) is a metal-organic compound that has superparamagnetic behavior below a certain blocking temperature at the molecular scale. In this temperature range, a SMM exhibits magnetic hysteresis of purely molecular origin. In contrast to conventional bulk magnets and molecule-based magnets, collective long-range magnetic ordering of magnetic moments is not necessary. Although the term "single-molecule magnet" was first employed in 1996, the first single-molecule magnet, [Mn12O12(OAc)16(H2O)4] (nicknamed "Mn12") was reported in 1991.

Uranium mining

Uranium mining is the process of extraction of uranium ore from the ground. Over 50 thousand tons of uranium were produced in 2019. Kazakhstan, Canada, and Australia were the top three uranium producers, respectively, and together account for 68% of world production. Other countries producing more than 1,000 tons per year included Namibia, Niger, Russia, Uzbekistan, the United States, and China. Nearly all of the world's mined uranium is used to power nuclear power plants.

Magnet

A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nickel, cobalt, etc. and attracts or repels other magnets. A permanent magnet is an object made from a material that is magnetized and creates its own persistent magnetic field. An everyday example is a refrigerator magnet used to hold notes on a refrigerator door.

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