Publication
Tropospheric ozone is a climate relevant greenhouse gas, as well as an atmospheric pollutant. Its abundance in the troposphere is mainly governed by the influx of stratospheric air masses and the photochemical production due to anthropogenic and biogenic ozone precursors. Precise model simulations and measurements are needed to assess the exact impact of these sources onto the total tropospheric ozone content. In the latter case, vertical tropospheric ozone profiles are commonly obtained from in-situ balloon-borne soundings. These routine observations are performed with a maximum frequency of several measurements per week. Therefore, they are not suited to resolve the rather fast changes in the tropospheric ozone concentration. However, accurate vertical ozone profiles with temporal and spatial resolutions suitable for studying those changes have been produced for decades using remote sensing by means of the ozone UV differential absorption lidar (DIAL) technique. The main goals of this thesis aimed to address some of the unresolved problems of the ozone origin and evolution in the upper troposphere and lower stratosphere and were: to develop an UV DIAL for the observation of the vertical ozone distribution in the free troposphere and at the tropopause region. to perform experimental measurements of vertical ozone profiles in the free troposphere and the tropopause in order to assess the ability of the ozone UV DIAL to observe fast variations in vertical ozone distribution caused by stratosphere-troposphere exchange (STE), long range transport, and advection from the boundary layer. to assess the feasibility of systematic ozone profile retrieval by the ozone UV DIAL technique from the High Altitude Research Station Jungfraujoch (HARSJ, 3580 m ASL, 7°59'2''E, 46°32'53''N). The HARSJ was chosen for the experiment because of its location, which allows ozone UV DIAL measurements of the tropopause region without perturbation of the lower troposphere. Furthermore, previous atmospheric studies have shown that because of the station's location, the upper tropospheric data taken at the HARSJ can be regarded as representative for central and western Europe. During the first two and a half years of the thesis project the ozone UV DIAL was designed and built. The ozone UV DIAL transmitter is based on a commercial, fourth harmonic Nd:YAG laser. The on- (284 nm) and off- (304 nm) ozone UV DIAL wavelengths are produced by stimulated Raman scattering in high-pressure nitrogen. The receiver uses the existing astronomical Cassegrain telescope (76 cm in diameter) at the HARSJ. Spectral separation of the backscattered ozone UV DIAL wavelengths is carried out by a polychromator based on an concave imaging diffraction grating. The entire ozone UV DIAL detection unit is integrated into the existing long-range multi-wavelength polychromator box optically coupled at the Cassegrain telescope's rear end. With the current design, the ozone UV DIAL system provides hourly ave
Roman Pohorsky, Julia Schmale, Andrea Baccarini