Publication

[(Methylcarbamothioyl)disulfanyl]methyl N-methylcarbamodithioate

Christine Neuhausen
2010
Journal Articles

Abstract

The title compound, C5H10N2S5, was unintentionally obtained as the product of an attempted synthesis of a methyl-carbamodithioic acid using methylamine and carbon disulfide. In the molecule, two dithiocarbamate groups are bridged by a -CH2S- unit. The C-S-S-C torsion angle is -90.13 (11)degrees. The crystal structure is stabilized by N-H center dot center dot center dot S interactions between neighbouring molecules. An intramolecular N-H center dot center dot center dot S hydrogen bond also occurs.

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https://infoscience.epfl.ch/entities/publication/cb9c30a8-2b6c-4515-a99f-6bb1d36f75b4

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Christine Neuhausen
2010
Journal Articles

Abstract

Official source

https://infoscience.epfl.ch/entities/publication/cb9c30a8-2b6c-4515-a99f-6bb1d36f75b4

About this result

Related concepts (24)

Crystal structure

In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in the material that constitutes this repeating pattern is the unit cell of the structure.

Hydrogen bond

In chemistry, a hydrogen bond (or H-bond) is a primarily electrostatic force of attraction between a hydrogen (H) atom which is covalently bound to a more electronegative "donor" atom or group (Dn), and another electronegative atom bearing a lone pair of electrons—the hydrogen bond acceptor (Ac). Such an interacting system is generally denoted , where the solid line denotes a polar covalent bond, and the dotted or dashed line indicates the hydrogen bond.

Spiro compound

In organic chemistry, spiro compounds are compounds that have at least two molecular rings with only one common atom. The simplest spiro compounds are bicyclic (having just two rings), or have a bicyclic portion as part of the larger ring system, in either case with the two rings connected through the defining single common atom.

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