Rubidium chlorideRubidium chloride is the chemical compound with the formula RbCl. This alkali metal halide salt is composed of rubidium and chlorine, and finds diverse uses ranging from electrochemistry to molecular biology. In its gas phase, RbCl is diatomic with a bond length estimated at 2.7868 Å. This distance increases to 3.285 Å for cubic RbCl, reflecting the higher coordination number of the ions in the solid phase. Depending on conditions, solid RbCl exists in one of three arrangements or polymorphs as determined with holographic imaging: The sodium chloride (NaCl) polymorph is most common.
Quantum vortexIn physics, a quantum vortex represents a quantized flux circulation of some physical quantity. In most cases, quantum vortices are a type of topological defect exhibited in superfluids and superconductors. The existence of quantum vortices was first predicted by Lars Onsager in 1949 in connection with superfluid helium. Onsager reasoned that quantisation of vorticity is a direct consequence of the existence of a superfluid order parameter as a spatially continuous wavefunction.
Surface tensionSurface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged. At liquid–air interfaces, surface tension results from the greater attraction of liquid molecules to each other (due to cohesion) than to the molecules in the air (due to adhesion). There are two primary mechanisms in play.
Alkali metalThe alkali metals consist of the chemical elements lithium (Li), sodium (Na), potassium (K), rubidium (Rb), caesium (Cs), and francium (Fr). Together with hydrogen they constitute group 1, which lies in the s-block of the periodic table. All alkali metals have their outermost electron in an s-orbital: this shared electron configuration results in their having very similar characteristic properties. Indeed, the alkali metals provide the best example of group trends in properties in the periodic table, with elements exhibiting well-characterised homologous behaviour.
Caesium fluorideCaesium fluoride or cesium fluoride is an inorganic compound with the formula CsF and it is a hygroscopic white salt. Caesium fluoride can be used in organic synthesis as a source of the fluoride anion. Caesium also has the highest electropositivity of all known elements and fluorine has the highest electronegativity of all known elements. Caesium fluoride can be prepared by the reaction of caesium hydroxide (CsOH) with hydrofluoric acid (HF) and the resulting salt can then be purified by recrystallization.
Caesium chlorideCaesium chloride or cesium chloride is the inorganic compound with the formula CsCl. This colorless salt is an important source of caesium ions in a variety of niche applications. Its crystal structure forms a major structural type where each caesium ion is coordinated by 8 chloride ions. Caesium chloride dissolves in water. CsCl changes to NaCl structure on heating. Caesium chloride occurs naturally as impurities in carnallite (up to 0.002%), sylvite and kainite.
Magnetic flux quantumThe magnetic flux, represented by the symbol Φ, threading some contour or loop is defined as the magnetic field B multiplied by the loop area S, i.e. Φ = B ⋅ S. Both B and S can be arbitrary, meaning Φ can be as well. However, if one deals with the superconducting loop or a hole in a bulk superconductor, the magnetic flux threading such a hole/loop is quantized. The (superconducting) magnetic flux quantum Φ0 = h/(2e) ≈ is a combination of fundamental physical constants: the Planck constant h and the electron charge e.
CaesiumCaesium (IUPAC spelling; cesium in American English) is a chemical element with the symbol Cs and atomic number 55. It is a soft, silvery-golden alkali metal with a melting point of , which makes it one of only five elemental metals that are liquid at or near room temperature. Caesium has physical and chemical properties similar to those of rubidium and potassium. It is pyrophoric and reacts with water even at . It is the least electronegative element, with a value of 0.79 on the Pauling scale.
Macroscopic quantum phenomenaMacroscopic quantum phenomena are processes showing quantum behavior at the macroscopic scale, rather than at the atomic scale where quantum effects are prevalent. The best-known examples of macroscopic quantum phenomena are superfluidity and superconductivity; other examples include the quantum Hall effect and topological order. Since 2000 there has been extensive experimental work on quantum gases, particularly Bose–Einstein condensates. Between 1996 and 2016 six Nobel Prizes were given for work related to macroscopic quantum phenomena.
Quantum turbulenceQuantum turbulence is the name given to the turbulent flow – the chaotic motion of a fluid at high flow rates – of quantum fluids, such as superfluids. The idea that a form of turbulence might be possible in a superfluid via the quantized vortex lines was first suggested by Richard Feynman. The dynamics of quantum fluids are governed by quantum mechanics, rather than classical physics which govern classical (ordinary) fluids.
Metal ions in aqueous solutionA metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H2O)n]z+. The solvation number, n, determined by a variety of experimental methods is 4 for Li+ and Be2+ and 6 for most elements in periods 3 and 4 of the periodic table. Lanthanide and actinide aqua ions have higher solvation numbers (often 8 to 9), with the highest known being 11 for Ac3+. The strength of the bonds between the metal ion and water molecules in the primary solvation shell increases with the electrical charge, z, on the metal ion and decreases as its ionic radius, r, increases.
RubidiumRubidium is the chemical element with the symbol Rb and atomic number 37. It is a very soft, whitish-grey solid in the alkali metal group, similar to potassium and caesium. Rubidium is the first alkali metal in the group to have a density higher than water. On Earth, natural rubidium comprises two isotopes: 72% is a stable isotope 85Rb, and 28% is slightly radioactive 87Rb, with a half-life of 48.8 billion years—more than three times as long as the estimated age of the universe.
Superfluid helium-4Superfluid helium-4 is the superfluid form of helium-4, an isotope of the element helium. A superfluid is a state of matter in which matter behaves like a fluid with zero viscosity. The substance, which looks like a normal liquid, flows without friction past any surface, which allows it to continue to circulate over obstructions and through pores in containers which hold it, subject only to its own inertia. The formation of the superfluid is known to be related to the formation of a Bose–Einstein condensate.
Density functional theoryDensity-functional theory (DFT) is a computational quantum mechanical modelling method used in physics, chemistry and materials science to investigate the electronic structure (or nuclear structure) (principally the ground state) of many-body systems, in particular atoms, molecules, and the condensed phases. Using this theory, the properties of a many-electron system can be determined by using functionals, i.e. functions of another function. In the case of DFT, these are functionals of the spatially dependent electron density.
FemtosecondA femtosecond is a unit of time in the International System of Units (SI) equal to 10^-15 or of a second; that is, one quadrillionth, or one millionth of one billionth, of a second. For context, a femtosecond is to a second as a second is to about 31.71 million years; a ray of light travels approximately 0.3 μm (micrometers) in 1 femtosecond, a distance comparable to the diameter of a virus. The word femtosecond is formed by the SI prefix femto and the SI unit second. Its symbol is fs.
Bubble (physics)A bubble is a globule of a gas substance in a liquid. In the opposite case, a globule of a liquid in a gas, it's called a drop. Due to the Marangoni effect, bubbles may remain intact when they reach the surface of the immersive substance. Bubbles are seen in many places in everyday life, for example: As spontaneous nucleation of supersaturated carbon dioxide in soft drinks As water vapor in boiling water As air mixed into agitated water, such as below a waterfall As sea foam As a soap bubble As given off in chemical reactions, e.
Calculation in kindNOTOC Calculation in kind or calculation in-natura is a way of valuating resources and a system of accounting that uses disaggregated physical magnitudes as opposed to a common unit of calculation. As the basis for a socialist economy, it was proposed to replace money and financial calculation. In an in-kind economy products are produced for their use values (their utility) and accounted in physical terms. By contrast, in money-based economies, commodities are produced for their exchange value and accounted in monetary terms.
Socialist calculation debateThe socialist calculation debate, sometimes known as the economic calculation debate, was a discourse on the subject of how a socialist economy would perform economic calculation given the absence of the law of value, money, financial prices for capital goods and private ownership of the means of production. More specifically, the debate was centered on the application of economic planning for the allocation of the means of production as a substitute for capital markets and whether or not such an arrangement would be superior to capitalism in terms of efficiency and productivity.
AttosecondAn attosecond (symbol as) is a unit of time in the International System of Units (SI) equal to 1×10−18 of a second (one quintillionth of a second). For comparison, an attosecond is to a second what a second is to about 31.71 billion years. The word "attosecond" is formed by the prefix atto and the unit second. Atto- was derived from the Danish word for eighteen (atten). Its symbol is as. An attosecond is equal to 1000 zeptoseconds, or of a femtosecond.
Valence electronIn chemistry and physics, a valence electron is an electron in the outer shell associated with an atom, and that can participate in the formation of a chemical bond if the outer shell is not closed. In a single covalent bond, a shared pair forms with both atoms in the bond each contributing one valence electron. The presence of valence electrons can determine the element's chemical properties, such as its valence—whether it may bond with other elements and, if so, how readily and with how many.
