Publications related to Picosecond solvation dynamics of alkali cations in superfluid 4He nanodroplets

Characterization of two electronic subsystems in cuprates through optical conductivity

Neven Barisic, Ana Akrap, Edoardo Martino

Understanding the physical properties of unconventional superconductors as well as of other correlated materials presents a formidable challenge. Their unusual evolution with doping, frequency, and temperature has frequently led to non-Fermi-liquid (non-FL ...

2023

Anionic character of the conduction band of sodium chloride

Klaus Kern, Abhishek Grewal

The alkali halides are ionic compounds. Each alkali atom donates an electron to a halogen atom, leading to ions with full shells. The valence band is mainly located on halogen atoms, while, in a traditional picture, the conduction band is mainly located on ...

Nature Portfolio2022

Computational Studies of the Proton-Coupled Metal Ion Transport in the SLC11/NRAMP Family of Transporters

Maria Letizia Merlini

In the last years, it has been demonstrated a link between the overload of metal ions inside nervous system cells and the onset of severe neurodegenerative diseases. This prompted the investigation of the structural and functional properties of transporter ...

EPFL2022

Semiclassical methods in conformal field theories scrutinized by the epsilon-expansion

Gil Badel

Conformal Field Theories (CFTs) are crucial for our understanding of Quantum Field Theory (QFT). Because of their powerful symmetry properties, they play the role of signposts in the space of QFTs. Any method that gives us information about their structure ...

EPFL2022

Scaling of the translational velocity of vortex rings behind conical objects

Karen Ann J Mulleners, Guillaume de Guyon-Crozier

Ring vortices are efficient at transporting fluid across long distances. They can be found in nature in various ways: they propel squids, inject blood in the heart, and entertain dolphins. These vortices are generally produced by ejecting a volume of fluid ...

2021

Angular Momentum in Rotating Superfluid Droplets

Camila Bacellar Cases Da Silveira, Christoph Bostedt

The angular momentum of rotating superfluid droplets originates from quantized vortices and capillary waves, the interplay between which remains to be uncovered. Here, the rotation of isolated submicrometer superfluid He-4 droplets is studied by ultrafast ...

AMER PHYSICAL SOC2020

Ultrafast relaxation of photoexcited superfluid He nanodroplets

Marcel Drabbels, Alberto Hernando de Castro

The relaxation of photoexcited nanosystems is a fundamental process of light–matter interaction. Depending on the couplings of the internal degrees of freedom, relaxation can be ultrafast, converting electronic energy in a few fs, or slow, if the energy is ...

Nature Research2020

Accelerated Discovery of Metal-Organic Frameworks (MOFs) For Energy Related Applications

Arunraj Chidambaram

Metal-Organic Frameworks (MOFs) are an emerging class of materials that consist of metal ions which are linked with organic ligands via coordination bonds to form extended networks. MOF structures consists predominantly of open voids which makes them among ...

EPFL2020

Large charge, semiclassics and superfluids : from broken symmetries to conformal field theories

Gabriel Francisco Cuomo

This thesis explores the application of semiclassical methods in the study of states with large quantum numbers for theories invariant under internal symmetries. In the first part of the thesis, we study zero-temperature superfluids. These provide a gener ...

EPFL2020

Highly stable enzyme-mimicking nanocomposite of antioxidant activity

Bálint Náfrádi, Marko Pavlovic

A highly stable nanocomposite of antioxidant activity was developed by immobilization of a superoxide dismutase-mimicking metal complex on copolymer-functionalized nanoclay. The layered double hydroxide (LDH) nanoclays were synthesized and surface modifica ...

2019

Helium-induced electronic transitions in photo-excited Ba+–Hen exciplexes

Marcel Drabbels

The possibility for helium-induced electronic transitions in a photo-excited atom is investigated using Ba+ excited to the 6p 2P state as a prototypical example. A diabatization scheme has been designed to obtain the necessary potential energy surfaces and ...

2018

Mastering the statistical properties of microcavity polaritons

Albert Adiyatullin

Microcavity polaritons are hybrid quasiparticles emerging from the strong coupling between quantum well excitons and light in the resonator. Their unique half-light half-matter nature brings in specific properties like low effective mass, nonlinearity due ...

EPFL2017

Complexation of [Gd(DTTA–Me)(H2O)2]− by Fluoride and Its Consequences to Water Exchange

Loïck Moriggi, Lothar Helm, Shima Karimi, Gail Ruth Hunter

The displacement of water molecule(s) from the inner coordination sphere of [Gd(DTTA–Me)(H2O)2]− (DTTA = ethylenetriamine-N,N,N″,N″-tetraacetate) by fluoride has been studied by multinuclear NMR relaxation (1H, 17O, 19F) and DFT calculations. Fluoride anio ...

American Chemical Society2016

Synthesis and Structure of Nitride-Bridged Uranium(III) Complexes

Rosario Scopelliti, Marinella Mazzanti, Lucile Sylvie Danielle Chatelain

The reduction of the nitride-bridged diuranium(IV) complex Cs[{U(OSi((OBu)-Bu-t)(3))(3)}(2)(mu-N)] affords the first example of a uranium nitride complex containing uranium in the +III oxidation state. Two nitride-bridged complexes containing the heteromet ...

2016

Synthesis of molecular complexes for small molecule activation

Julie Renée Michelle Andrez

The redox chemistry of f-elements is drawing the attention of inorganic chemists due to their unusual reaction pathways. Notably low-valent f-element complexes have been shown to be able to activate small molecules such as CO2 and N2 in mild conditions. Co ...

EPFL2016

Exciton-Polariton Bose-Einstein Condensates

Benoît Marie Joseph Deveaud

Exciton-polaritons, mixed light-matter quasiparticles in semiconductors, have recently shown evidence for Bose-Einstein condensation. Some of the properties of condensates of exciton-polaritons are reviewed in this article. We first discuss the spontaneous ...

Annual Reviews2015

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

Marinella Mazzanti, Julie Renée Michelle Andrez

Multimetallic cooperative binding of heteroallenes provides an attractive route to their activation, but the reduction of CS2 at heterobimetallic sites, associating an electron-rich metal with a main group Lewis acid has not been explored. Here we show tha ...

Royal Soc Chemistry2015

Nucleation of quantized vortex rings in 4He nanodroplets

Marcel Drabbels, Xiaohang Zhang

Whereas most of the phenomena associated with superfluidity have been observed in finite-size helium systems, the nucleation of quantized vortices has proven elusive. Here we show that the solvation of a Ba+ ion created by photoionization of neutral Ba at ...

American Institute of Physics2014

Magnetic field dependence of the basal-plane superconducting anisotropy in YBa2Cu4O8 from small-angle neutron scattering measurements of the vortex lattice

Joël Mesot, Jonathan White

We report a study of the basal-plane anisotropy of the superfluid density in underdoped YBa2Cu4O8 (Y124), showing the effects of both the CuO2 planes and the fully occupied CuO chains. From small-angle neutron scattering measurements of the vortex lattice, ...

American Physical Society2014

Conventional superconductivity and hysteretic Campbell penetration depth in single crystals MgCNi3

Sergiy Katrych

Single crystals of MgCNi3, with areas sized up to 1 mm(2), were grown by the self-flux method using a cubic anvil high-pressure technique. In low applied fields, the dc magnetization exhibited a very narrow transition into the superconducting state, demons ...

Amer Physical Soc2013