Publication

On measured activation volumes as relevant to ratcheting or cyclic creep

Related publications (30)

Transfer learning application of self-supervised learning in ARPES

There is a growing recognition that electronic band structure is a local property of materials and devices, and there is steep growth in capabilities to collect the relevant data. New photon sources, from small-laboratory-based lasers to free electron lase ...

IOP Publishing Ltd2023

Flowing Gas Experiments Reveal Mechanistic Details of Interfacial Reactions on a Molecular Level at Knudsen Flow Conditions

Michel Rossi, Christian Ludwig, Riccardo Iannarelli

Knudsen flow experiments and its interpretation in terms of adsorption/desorption kinetics as well as quantitative uptake on substrates of interest is presented together with the description of critical design parameters of the Knudsen Flow Reactor (KFR). ...

2022

Molecular dynamics simulations of the evaporation of hydrated ions from aqueous solution

Philip Robin Loche

Although important for atmospheric processes and gas-phase catalysis, very little is known about the hydration state of ions in the vapor phase. Here we study the evaporation energetics and kinetics of a chloride ion from liquid water by molecular dynamics ...

NATURE PORTFOLIO2022

An Open-Source Whole Slide Image Registration Workflow at Cellular Precision Using Fiji, QuPath and Elastix

Olivier Burri, Jessica Sordet, Arne Seitz, Romain Guiet, Nicolas René Chiaruttini

Image analysis workflows for Histology increasingly require the correlation and combination of measurements across several whole slide images. Indeed, for multiplexing, as well as multimodal imaging, it is indispensable that the same sample is imaged multi ...

FRONTIERS MEDIA SA2022

Characterization of water sorption cycle in the cement microstructure of controlled oxide composition

Monisha Rastogi

This thesis investigates the water vapour sorption behaviour of samples with maximized calcium-silicate-hydrate (C-S-H) content. Primarily, the role of heterogeneous and homogeneous cavitation has been studied during the drying of cementitious materials. C ...

EPFL2022

Process-informed adsorbent design guidelines for direct air capture

Berend Smit, Susana Garcia Lopez, Fergus Robert Lloyd Mcilwaine

Direct air capture using solid adsorbents is a proven technology critical to reducing our net greenhouse gas emissions to zero and beyond. Currently, academic research into the technology mainly focuses on the devel-opment of new adsorbents. However, there ...

ELSEVIER SCIENCE SA2022

Dissociative Sticking Probability of Methane on Pt(110)-(2×1)

Rainer Beck, Ana Gutiérrez González

In this work, we revisit the dissociative sticking of methane on Pt(110)-(2×1) using quasi-classical trajectory (QCT) calculations and supersonic molecular beam (SMB) experiments. Experimentally, we apply the King and Wells method and the reflection absorp ...

2021

Infrared Activities of Adsorbed Species on Metal Surfaces: The Puzzle of Adsorbed Methyl (CH3)

Rainer Beck, Harmina Vejayan

Reflection–absorption infrared spectroscopy (RAIRS) is widely used to identify molecular adsorbates on metals during surface chemical reactions, but the interpretation of RAIRS data can be difficult with experiment alone. Here, we reveal from first-princip ...

2021

A Real-time Synchrophasor Data Compression Method Using Singular Value Decomposition

Mario Paolone

The proliferation of phasor measurement units (PMUs) presents new challenges in archiving and processing large amounts of synchrophasor data which necessitates advanced data compression methods. This paper proposes a singular value decomposition (SVD)-base ...

2021

Static and Dynamic Self-Assembly of Pearl-Like-Chains of Magnetic Colloids Confined at Fluid Interfaces

Ignacio Pagonabarraga Mora

Magnetic colloids adsorbed at a fluid interface are unique model systems to understand self-assembly in confined environments, both in equilibrium and out of equilibrium, with important potential applications. In this work the pearl-chain-like self-assembl ...

2021

Toward catchment hydro-biogeochemical theories

Ilja van Meerveld, Andrea Rinaldo, Li Li, Paolo Benettin

Headwater catchments are the fundamental units that connect the land to the ocean. Hydrological flow and biogeochemical processes are intricately coupled, yet their respective sciences have progressed without much integration. Reaction kinetic theories tha ...

WILEY2020

Mechanisms of the Heterogeneously Catalyzed Reaction of CO2 Hydrogenation on Transition Metal Surfaces

Kun Zhao

Renewable energy supply and energy storage in a closed materials cycle are the urgent global challenges of the 21st century. Carbon dioxide (CO2) hydrogenation over catalysts is a method to produce synthetic fuels from renewable energy in a CO2 neutral cyc ...

EPFL2020

Dynamic wetting in pressure-infiltration of ceramic particle preforms by molten metal

Gionata Schneider

This thesis investigates the interaction between mechanically induced flow of a liquid metal into a porous solid, and kinetic effects at the triple line. The approach is experimental and focuses on metal-ceramic systems for which the literature gives value ...

EPFL2019

Two dimensional diffusion-controlled triplet–triplet annihilation kinetics

Pierre-François Marie Brevet, Hubert Girault, Astrid Johana Olaya Avendano, Grégoire Clément Gschwend, Morgan Kazmierczak

Diffusion controlled chemical reactions are usually observed in three dimensionalmedia. In contrast, planar bimolecular reactions taking place between reagents adsorbed at a soft interface are two-dimensional and therefore cannot be studied within the same ...

2019

Accurate and efficient interpretation of load-test data for asset-management

Sai Ganesh Sarvotham Pai

Increasing demand for new infrastructure and ageing of existing infrastructure has made management of infrastructure a key challenge of this century. Replacement of all ageing civil infrastructure is economically and environmentally unsustainable. Civil in ...

EPFL2019

Composite Materials Based on (Cymene)Ru(II) Curcumin Additives Loaded on Porous Carbon Adsorbents from Agricultural Residues Display Efficient Antibacterial Activity

Paul Joseph Dyson

Alternative composite materials with antibacterial activity have been developed by combining the porosity of carbon materials and the antibacterial activity of half sandwich (cymene)Ru-curcumin complexes. Different types of activated carbon were used, from ...

2018

In situ Control of the Adsorption Species in CO2 Hydrogenation: Determination of Intermediates and Byproducts

Andreas Züttel, Kun Zhao, Ligang Wang, Marco Calizzi, Emanuele Moioli

CO2 hydrogenation over catalysts is a potentially exciting method to produce fuels while closing the CO2 cycle and mitigating global warming. The mechanism of this process has been controversial due to the difficulty in clearly identifying the species pres ...

2018

Airborne Hyperspectral Imaging of Lakes

Kevin Sylvain Barbieux

In a time of rising concern about climate change and pollution, the water quality of large lakes acts as an indicator of the health of the environment. To study the water quality at a large scale - up to several hundreds of kilometres - hyperspectral remot ...

EPFL2018

Design of Surface-Supported Bio-inspired Networks for CO2 and O2 Activation at Room Temperature

Daniel Eduardo Hurtado Salinas

The structure of a biological system defines its function. Therefore, nature has developed sophisticated systems that catalyze chemical reactions that are vital for life on earth. For instance, the photosynthesis is a biological process that is partially r ...

EPFL2018

A Practical Engineering Approach to Interpreting Measurement Data in Uncertain Contexts

Ian Smith, Sai Ganesh Sarvotham Pai

Measurement data interpretation has the potential to improve asset management through quantification of reserve capacity and execution of well-engineered interventions. Many recent proposals for data interpretation that include uncertainty are not appropri ...

ASCE2017