Publications associées à Exothermic process

A novel reactor concept for thermal integration of naphtha reforming with propane ammoxidation

Alimohammad Bahmanpour, Samira Ebrahimian

In this study, propane ammoxidation as an exothermic process is thermally coupled with the endothermic naphtha reforming process which resulted in the elimination of the naphtha reforming furnaces. Both processes are available in petrochemical plants. Naph ...

2019

High-pressure NMR spectroscopic and calorimetric studies on formic acid dehydrogenation and carbon dioxide hydrogenation

Cornel Fink

Our current energy production is convenient and simple, but it is not sustainable. The negative impacts on our environment are omnipresent in the form of smog, extinction of species, and global warming. A major challenge of our generation is the transition ...

EPFL2018

Combined Exergy Analysis and Energy Integration for the Optimization of Nitrogen Fertilizer Plants

François Maréchal, Daniel Alexander Florez Orrego, Shivom Sharma

Modern ammonia production plants are equipped with efficient energy integration networks able to recover an important fraction of the enthalpy of reaction released by the exothermic chemical systems. However, to fully supply the exergy demands of the highl ...

University of San Diego2017

Alkali Activation of AOD Stainless Steel Slag Under Steam Curing Conditions

Muhammad Salman, Ruben Anton Snellings

Crystalline argon oxygen decarburization slag, in powdery form, was investigated for its hydration potential by alkali activation and curing at 80 degrees C. Na-silicate and K-silicate of the same modulus were used as activators. Isothermal calorimetry at ...

Wiley-Blackwell2015

Fine structuration of low-temperature co-fired ceramic (LTCC) microreactors

Paul Muralt, Albert Renken, Bo Jiang, Lioubov Kiwi, Thomas Maeder, Julien Haber

The development of microreactors that operate under harsh conditions is always of great interest for many applications. Here we present a microfabrication process based on low-temperature co-fired ceramic (LTCC) technology for producing microreactors which ...

Royal Society of Chemistry2015

Heat Management for Process Intensification of Fast Exothermic Reactions in Microstructured Reactors

Julien Haber

Nowadays, the production in fine chemical and pharmaceutical industry is mostly carried out in large scale batch reactors having typically dimensions of a few meters to satisfy the demand of the market. Even though this technology has been widely used and ...

EPFL2013

Role of Environment for Catalysis of the DNA Repair Enzyme MutY

Ursula Röthlisberger, Jeremy Samuel Arey, Elizabeth Claire Brunk

Control of the N-glycosylase reaction by the DNA repair enzyme, MutY, entails the organization of solvent molecules. Classical molecular dynamics and QM/MM simulations were used to investigate the solvent and environment effects contributing to catalysis. ...

2012

The dependence of the proton-triton thermo-nuclear fusion reaction rate on the temperature and total energy content of the high-energy proton distribution function

Duccio Testa, Christian Schlatter

The endothermic nuclear reaction between thermal tritons and high-energy protons can represent an important contribution to the total neutron yield in tokamak plasmas heated by radio-frequency waves, as the first JET experiments have demonstrated (see Mant ...

IOP2009

Editorial: Failure in multiphase geomaterials

Lyesse Laloui

The contributions assembled in the present volume proceed from the lectures of the 2009 ALERT Geomaterials School devoted to the Failure in the multiphase geomaterials. The multiphase behaviour of geomaterials used to be mainly considered from the point of ...

2009

“Sandwich Reactor” for Heterogeneous Catalytic Processes: N2O Decomposition as a Case Study

Albert Renken, Lioubov Kiwi, Bryan Bromley

A novel “sandwich” microreactor designed as a thin (∼ 300

\mu

m) porous plate of sintered metal fibers (SMF), sandwiched between metallic plates is reported. The SMF surface was coated by Fe-ZSM-5 thin film (< 2

\mu

m) rendering a catalyst highly active ...

2008

Optimization of reaction calorimetry for monitoring chemical reactions in supercritical fluids

Charalampos Mantelis

The PhD thesis deals with the optimization of the reaction calorimetry technique to monitor chemical reactions in supercritical fluids. The aim is to develop this thermal analysis technique to monitor the heat released by a chemical reaction in a high pres ...

EPFL2008

Structured fiber supports for ionic liquid-phase catalysis used in gas-phase continuous hydrogenation

Paul Joseph Dyson, Lioubov Kiwi, Gabor Laurenczy, Marina Ruta

Structured supported ionic liquid-phase (SSILP) catalysis is a new concept with the advantages of ionic liquids (ILs) used as solvents for homogeneous catalyst and the further benefits of structured heterogeneous catalysts. This is achieved by confining th ...

2007

Ionic liquid synthesis in a microstructured reactor for process intensification

Albert Renken, Lioubov Kiwi

Ionic liquids (IL) are the focus of growing interest over the last few years due to their low vapour pressure being beneficial for replacing common organic solvents with high vapour pressure. IL synthesised via alkylation are produced in batch or semi-batc ...

2007

Proton-triton nuclear reaction in ICRF heated plasmas in JET

Duccio Testa, Christian Schlatter

Fast protons can react with tritons in an endothermic nuclear reaction which can act as a source of neutrons in magnetically confined fusion plasmas. We have performed an experiment to systematically study this reaction in low tritium concentration (approx ...

2006

Microstructured reactors for catalytic reactions

Albert Renken, Lioubov Kiwi

A review. This review addresses the catalytic reactions performed in microstructured reactors, which are more and more recognized in recent years as a novel approach for chem. and chem. process industry. They are particularly suited for highly exothermic a ...

2005