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Publications associées (29)

Creation of Faceted Polyhedral Microgels from Compressed Emulsions

Esther Amstad, Jing Fan

Compressed monodisperse emulsions in confined space exhibit highly ordered structures. The influence of the volume fraction and the confinement geometry on the organized structures is investigated and the mechanism by which structural transition occurs is ...

Wiley-V C H Verlag Gmbh2017

The Molecular Mechanism of Nanodroplet Stability

Sylvie Roke, Evangelia Zdrali, Yixing Chen, Halil Ibrahim Okur, David Mark Wilkins

Mixtures of nano- and microscopic oil droplets in water have recently been rediscovered as miniature reaction vessels in microfluidic environments and are important constituents of many environmental systems, food, personal care, and medical products. The ...

Amer Chemical Soc2017

Oxidative stability and microstructure of 5% fish-oil-enriched granola bars added natural antioxidants derived from brown alga Fucus vesiculosus

Louise Helene Soegaard Jensen

The aims of this study were to (i) investigate the ability of Icelandic brown algae Fucus vesiculosus extracts to inhibit lipid oxidation in granola bars fortified with fish oil-in-water emulsion; (ii) investigate whether addition of the seaweed extracts a ...

Wiley-Blackwell2017

Influence of Fluorinated Surfactant Composition on the Stability of Emulsion Drops

Esther Amstad, Gianluca Nicolas Etienne, Michael David Kessler

Aqueous drops of a well-defined size are often used as small containers for conducting chemical and biochemical reactions, cell assays and as templates to produce microparticles. To prevent their coalescence, they must be stabilized, for example, using sur ...

Wiley-Blackwell2016

Freezing effects of oil-in-water emulsions studied by sum-frequency scattering spectroscopy

Sylvie Roke, Nikolay Smolentsev

Temperature-dependent sum-frequency scattering spectroscopy is used to study the properties of hexadecane and dodecane oil droplets in water. The sum-frequency scattering spectra contain vibrational bands that correspond to the symmetric and antisymmetric ...

Amer Inst Physics2016

Specific Ion Effects in Amphiphile Hydration and Interface Stabilization

Sylvie Roke, Yixing Chen, Rüdiger Scheu

Specific ion effects can influence many processes in aqueous solutions: protein folding, enzyme activity, self-assembly, and interface stabilization. Ionic amphiphiles are known to stabilize the oil/water interface, presumably by dipping their hydrophobic ...

Amer Chemical Soc2014

Surface Impurities Are Not Responsible For the Charge on the Oil/Water Interface: A Comment

Sylvie Roke, Rüdiger Scheu, Kailash Chandra Jena

A recent communication by Roger and Cabane[1] on the origin of negative charge on the interface between oil and water states that: "The basic assumption of all previous experimental and theoretical studies has been that these systems have "pristine" oil/wa ...

Wiley-VCH Verlag GmbH2012

Sodium dodecyl sulfate at water-hydrophobic interfaces: A simulation study

Sylvie Roke

Using molecular dynamics simulations, we have studied the water-vapor and water-oil (decane) interfaces of aqueous solutions of sodium dodecyl sulfate (SDS). The water-vapor interface is often used as a model for water-oil (hydrophobic) interfaces, yet we ...

Amer Chemical Soc2012

Polymer micelles with pyridyl disulfide-coupled antigen travel through lymphatics and show enhanced cellular responses following immunization

Jeffrey Alan Hubbell, Melody Swartz, Sachiko Hirosue, Conlin O'Neil, Karen Dane, Jackson Eby

Poly(ethylene glycol)-stabilized poly(propylene sulfide) core (PEG-PPS) nanoparticles (NPs) smaller than 50 nm efficiently travel to draining lymph nodes and interact with antigen-presenting cells (APCs) to induce potent immune responses following intrader ...

Elsevier Sci Ltd2012

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