Publications associées à DLVO theory

Second harmonic scattering of nanoparticles: A journey into the electrical double layer

In aqueous solutions, a charged surface causes the redistribution of nearby ions. The ion layers formed are known as the electrical double layer (EDL), and are widespread in many systems involving electrochemistry, colloidal science, biomedicine, and energ ...

EPFL2024

Spinel Protective Coatings for Solid Oxide Cell (SOC) Interconnects (ICs)

Samaneh Daviran

Abstract The degradation of metal interconnects (ICs) in Solid Oxide Cells (SOCs) primarily results from chromium (Cr) oxide scale growth on stainless-steel substrates, causing ohmic loss and air-side electrode poisoning by Cr. This thesis addresses these ...

EPFL2024

Effect of a temperature gradient on the screening properties of ionic fluids

Andrea Grisafi, Federico Grasselli

The electrostatic screening properties of ionic fluids are of paramount importance in countless physical processes. Yet the screening behavior of ionic conductors out of thermal equilibrium has to date mainly been studied in the context of thermoelectric p ...

AMER PHYSICAL SOC2023

Evolution of the electrical double layer with electrolyte concentration probed by second harmonic scattering

Sylvie Roke, Arianna Marchioro, Bingxin Chu, Marie Bischoff

Investigating the electrical double layer (EDL) structure has been a long-standing challenge and has seen the emergence of several sophisticated techniques able to probe selectively the few molecular layers of a solid/water interface. While a qualitative e ...

ROYAL SOC CHEMISTRY2023

Modulating the Surface Properties of Lithium Niobate Nanoparticles by Multifunctional Coatings Using Water-in-Oil Microemulsions

Sandrine Gerber, Alessandra Spada, Adrian Stefan Gheata, Manon Inès Noëlla Wittwer

Inorganic nanoparticles (NPs) have emerged as promising tools in biomedical applications, owing to their inherent physicochemical properties and their ease of functionalization. In all potential applications, the surface functionalization strategy is a key ...

2023

Molecular insights into the electrical double layer of colloidal oxide particles obtained through second harmonic scattering

Marie Bischoff

Photocatalytic applications play an essential role in the search for alternative energy sources and environmental decontamination techniques. It is of fundamental interest to understand on a molecular level the aqueous solid/liquid interface, where photoca ...

EPFL2022

In-situ Investigations on Gold Nanoparticles Stabilization Mechanisms in Biological Environments Containing HSA

Francesco Stellacci, Quy Ong Khac, Antonia Neels, Marianne Liebi

Nanoparticles (NPs) developments advance innovative biomedical applications. However, complex interactions and the low colloidal stability of NPs in biological media restrict their widespread utilization. The influence of NPs properties on the colloidal st ...

WILEY-V C H VERLAG GMBH2021

On the stability and necessary electrophoretic mobility of bare oil nanodroplets in water

Sylvie Roke, Saranya Pullanchery Sankara Narayanan, Halil Ibrahim Okur, Hilton Barbosa De Aguiar, Sergey Kulik

Hydrophobic oil droplets, particles, and air bubbles can be dispersed in water as kinetically stabilized dispersions. It has been established since the 19th century that such objects harbor a negative electrostatic potential roughly twice larger than the t ...

AMER INST PHYSICS2020

New approach for time-resolved and dynamic investigations on nanoparticles agglomeration

Francesco Stellacci, Antonia Neels, Urszula Beata Cendrowska, Alex Dommann, Claudio Toncelli

Nanoparticle (NP) colloidal stability plays a crucial role in biomedical application not only for human and environmental safety but also for NP efficiency and functionality. NP agglomeration is considered as a possible process in monodispersed NP colloida ...

TSINGHUA UNIV PRESS2020

Self-Propulsion of Active Colloids via Ion Release: Theory and Experiments

Ignacio Pagonabarraga Mora, Samuel Sanchez

We study the self-propulsion of a charged colloidal particle that releases ionic species using theory and experiments. We relax the assumptions of thin Debye length and weak nonequilibrium effects assumed in classical phoretic models. This leads to a numbe ...

2020

Porous granules by freeze granulation of Pickering emulsions stabilized with halloysite particles

Paul Bowen

Pickering emulsions stabilized with a natural silicate mineral, halloysite, were dried by freeze granulation in order to prepare porous granules. Different formulations were studied, by varying the pH of the suspension, the ionic strength and with the addi ...

ELSEVIER2020

How to polarise an interface with ions: the discrete Helmholtz model

Hubert Girault, Astrid Johana Olaya Avendano, Grégoire Clément Gschwend

The distribution of electrolytes in an electric field usually relies on theories based on the Poisson-Boltzmann formalism. These models predict that, in the case of a metallic electrode, ionic charges screen the electrode potential, leading to concentratio ...

2020

Specific Ion Effects at the Interface of Nanometer-Sized Droplets in Water: Structure and Stability

Sylvie Roke, Halil Ibrahim Okur, Evangelia Zdrali

The interaction of ions with interfaces influences numerous processes in chemistry, physics, and biology, while different ion species behave differently at hydrophobic or hydrophilic interfaces. Despite its importance, ion specificity and its relation to s ...

2019

Universal Oxide Shell Growth Enables in Situ Structural Studies of Perovskite Nanocrystals during the Anion Exchange Reaction

Raffaella Buonsanti, Anna Loiudice, Seryio Saris, Michal Stanislaw Strach

The ability to tune thin oxide coatings by wet-chemistry is desirable for many applications, yet it remains a key synthetic challenge. In this work, we introduce a general colloidal atomic layer deposition (c-ALD) synthesis to grow an alumina shell with tu ...

AMER CHEMICAL SOC2019

Communication: Mean-field theory of water-water correlations in electrolyte solutions

Michele Ceriotti, Sylvie Roke, David Mark Wilkins

Long-range ion induced water-water correlations were recently observed in femtosecond elastic second harmonic scattering experiments of electrolyte solutions. To further the qualitative understanding of these correlations, we derive an analytical expressio ...

American Institute of Physics2017

Versatility of Pyridoxal Phosphate as a Coating of Iron Oxide Nanoparticles

Heinrich Hofmann, Marijana Mionic Ebersold, Josefina Adriana Maria Bastiaansen, Ulrich Aschauer, Débora Bonvin

Pyridoxal 5'-phosphate (PLP) is the most important cofactor of vitamin B-6-dependent enzymes, which catalyses a wide range of essential body functions (e.g., metabolism) that could be exploited to specifically target highly metabolic cells, such as tumour ...

Mdpi Ag2017

On the Coherence in the Boundary Layer: Development of a Canopy Interface Model

Dasaraden Mauree, Alain Clappier

A 1D Canopy Interface Model (CIM) is developed to act as an interface between a meso-scale and a micro-scale atmospheric model and to better resolve the surface turbulent fluxes in the urban canopy layer. A new discretisation is proposed to solve the TKE e ...

Frontiers Media Sa2017

Simulation and Theory of Antibody Binding to Crowded Antigen-Covered Surfaces

Paolo De Los Rios, Giuseppe Foffi, Francesco Piazza

In this paper we introduce a fully flexible coarse-grained model of immunoglobulin G (IgG) antibodies parametrized directly on cryo-EM data and simulate the binding dynamics of many IgGs to antigens adsorbed on a surface at increasing densities. Moreover, ...

Public Library Science2016

Predicting the yield stress of paraffin-wax suspensions

Paul Bowen

An empirical modification of the Yodel model was developed for the prediction of the yield stress of concentrated, particulate, paraffin-wax suspensions, with a solids loading in the range of 47-57 vol.%, used in the low-pressure injection moulding (LPIM). ...

Elsevier2016

Dendrimer-Stabilized Titanate Nanowire Dispersions as Potential Nanocarriers

László Forró, Endre Horvath, Marko Pavlovic

The effect of poly(amido amine) (PAMAM) dendrimers of generations G2, G6, and G10 on the dispersion stability of titanate nanowires (TiONWs) as potential nanocarriers was clarified in order to develop biocompatible delivery systems. The PAMAMs adsorbed str ...

Amer Chemical Soc2015