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Molecular imine cages with π-basic Au3(pyrazolate) faces

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Noga Eren

One tetrahedral and two trigonal prismatic cages with π-basic Au3(pyrazolate)3 faces were obtained by connection of pre-formed gold complexes via dynamic covalent imine chemistry. The parallel arrangement of the Au3(pyrazolate)3 complexes in the prismatic ...

2024

Dilution versus fractionation: Separation technologies hyphenated with spICP-MS for characterizing metallic nanoparticles in aerosols

Christian Ludwig, Andrea Testino, Jian Wang, Tianyu Cen

The presence of metal salts has become one of the major limitations for measuring metallic nanoparticles (NPs) in single particle inductively coupled plasma mass spectrometry (spICP-MS). Their presence generates a background signal in spICP-MS that can be ...

2024

Plasmonically enhanced molecular junctions for investigation of atomic-scale fluctuations in self-assembled monolayers

Sakthi Priya Amirtharaj

Molecular junctions represent a fascinating frontier in the realm of nanotechnology and are one of the smallest optoelectronic devices possible, consisting of individual molecules or a group of molecules that serve as the active element sandwiched between ...

EPFL2024

Stencil-Based Selective Surface Functionalization of Silicon Nanowires in 3D Device Architectures for Next-Generation Biochemical Sensors

Yusuf Leblebici, Mohammad Nasr Esfahani, Ece Öztürk

Surface functionalization of 1D materials such as silicon nanowires is a critical preparation technology for biochemical sensing. However, existing nonselective functionalization techniques result in nonlocal binding and contamination, with potential devic ...

Amer Chemical Soc2024

A customized MOF-polymer composite for rapid gold extraction from water matrices

Wendy Lee Queen, Daniel Teav Sun, Shuliang Yang, Jun Li, Li Peng, Olga Syzgantseva

With the fast-growing accumulation of electronic waste and rising demand for rare metals, it is compelling to develop technologies that can promotionally recover targeted metals, like gold, from waste, a process referred to as urban mining. Thus, there is ...

AMER ASSOC ADVANCEMENT SCIENCE2023

Natural aging and vacancy trapping in Al-6xxx

William Curtin, Michele Ceriotti

Undesirable natural aging (NA) in Al-6xxx delays subsequent artificial aging (AA) but the size, composition, and evolution of clustering are challenging to measure. Here, atomistic details of early-stage clustering in Al-1% Mg-0.6%Si during NA are studied ...

Springer Heidelberg2023

Nonlinear Photoluminescence in Gold Thin Films

Sergejs Boroviks

Promisingapplications in photonics are driven by the ability tofabricate crystal-quality metal thin films of controlled thicknessdown to a few nanometers. In particular, these materials exhibit ahighly nonlinear response to optical fields owing to the indu ...

AMER CHEMICAL SOC2023

Optoelectronic or photovoltaic device with metal halide perovskite film treated by passivating agent

Michael Graetzel, Shaik Mohammed Zakeeruddin, Lukas Pfeifer, Essa Awadh R Alharbi, Anurag Krishna

This invention relates to an optoelectronic or photovoltaic device comprising a perovskite or metal halide perovskite film treated by one or more compounds of formula (I): ((R1-NH(R2)-R3)+)nW (I), wherein n is an integer selected from 1, 2, or 3; R1, R2, R ...

2023

Optical manipulation of plasmonic nanoparticles: Applications in surface chemistry and nano-optics

Jeonghyeon Kim

Optical tweezers are devices that can manipulate nano- and microparticles using a laser. The principle of optical tweezers is to apply a force to an object using the momentum of light. This force is very small, but it is sufficient to move things in the mi ...

EPFL2023

Persistence of variant selection in red gold alloys

Roland Logé, Cyril Cayron, Margaux Nathalie Dominique Larcher

Recently, a new thermally activated distortion with amplification (TADA) effect has been reported in red gold alloys caused by the A1 -> L1(0) phase transformation. The macroscopic amplification is due to the persistence of variant selection nucleated unde ...

ELSEVIER SCIENCE SA2022

Ultimate Limit for Optical Losses in Gold, Revealed by Quantitative Near-Field Microscopy

Sergejs Boroviks

We report thorough measurements of surface plasmon polaritons (SPPs) running along nearly perfect air-gold interfaces formed by atomically flat surfaces of chemically synthesized gold monocrystals. By means of amplitude-and phase-resolved near-field micros ...

AMER CHEMICAL SOC2022

Design guidelines for next-generation sodium-nickel-chloride batteries

Daniel Alexander Landmann

Sodium-nickel-chloride batteries have a proven track record for backup power applications, but also show great potential for large-scale stationary electricity storage currently dominated by lithium-ion batteries. While lithium-ion cells rely on critical c ...

EPFL2022

Monitoring and understanding Cu catalyst dissolution during CO2 electroreduction

Jan Vávra

Electrochemical reduction of carbon dioxide is a promising approach to decrease the amount of anthropogenic CO2 being released into the atmosphere, provided that a surplus of renewable electrical energy is available. Copper based materials are at the cente ...

EPFL2022

Understanding Thermomechanical Treatments Induced by Laser Powder Bed Fusion Process

Hossein Ghasemi Tabasi

Additive Manufacturing (AM) is referred to technologies that produce directly 3D parts in a layer-by-layer fashion. Laser Powder Bed Fusion (L-PBF) is one of the most important AM processes, enabling production of very complex metallic objects from a compu ...

EPFL2021

Phase transformation induced distortions in red gold alloys

Margaux Nathalie Dominique Larcher

Red gold alloys owe their warm and attractive colour to the combination of gold and copper atoms. Thanks to their good mechanical properties and resistance to corrosion, red gold alloys are used in luxury industries as well as in dentistry. Around the equi ...

EPFL2021

Mapping Spatial Distribution of Pores in an Additively Manufactured Gold Alloy Using Neutron Microtomography

Roland Logé, Jamasp Jhabvala, Hossein Ghasemi Tabasi, Markus Strobl, Michaël Meyer

A crucial criterion for the quality of the additively manufactured parts is the porosity content for achieving an acceptable final relative density. In addition, for jewelry applications, visible pores are unacceptable at or in the vicinity of the surface. ...

2021

A new set of analytical formulae for the computation of the bootstrap current and the neoclassical conductivity in tokamaks

Olivier Sauter

A new set of analytical formulae for calculating the bootstrap current and the neoclassical conductivity in tokamak experiments is presented. Previous works comparing the widely used Sauter model with results of recently developed numerical neoclassical so ...

AMER INST PHYSICS2021

Stable Palladium Oxide Clusters Encapsulated in Silicalite-1 for Complete Methane Oxidation

Oliver Kröcher, Davide Ferri, Teng Li, Olga Safonova

Zeolite-supported metal catalysts are widely employed in a number of chemical processes, and the stability of the catalytically active species is one of the most critical factors determining the reaction performance. A good example is the Pd/zeolite cataly ...

AMER CHEMICAL SOC2021

Direct-write laser-induced self-organization and metallization beyond the focal volume in tellurite glass

Yves Bellouard, Gözden Torun

We report on a self-organized process initiated on a potassium-tungsten-tellurite glass surface under repetitive femtosecond laser irradiation in a regime where cumulative effects lead to a localized melting. Specifically, we show that self-organized perio ...

2021

Gold Chain Formation via Local Lifting of Surface Reconstruction by Hot Electron Injection on H-2(D-2)/Au(111)

Klaus Kern, Anna Maria Roslawska, Abhishek Grewal

The hexagonal close packed surface of gold shows a 22 x root 3 "herringbone" surface reconstruction which makes it unique among the (111) surfaces of all metals. This long-range energetically favored dislocation pattern appears in response to the strong te ...

AMER CHEMICAL SOC2020