Publications associées à Éthanol cellulosique

Development of Sustainable Carbohydrate-Based Solvents by Acetal Functionalisation of Biomass

Organic solvents are ubiquitous in industrial and domestic applications from the production of pharmaceuticals to household consumer products. The negative impact of most traditional solvents, especially aprotic types, on the environment, health, and safet ...

EPFL2024

Design and Synthesis of Bio-based Amphiphiles from Lignocellulosic Biomass

Songlan Sun

In the pursuit of a carbon-neutral chemical industry, minimizing fossil feedstock consumption while integrating renewable carbon sources is imperative. Surfactants, inherently amphiphilic, pose challenges in separation and recovery processes. Given their e ...

EPFL2024

New Polymers from Biomass-Derived Hydroxycinnamic Acid Derivatives

Ghezae Tekleab

Polymers play a central role in shaping our world across various fields, but their heavy reliance on petrochemicals poses climate change, environmental and health risks. To address and alleviate these issues, transitioning to sustainable polymers, sourced ...

EPFL2024

Selecting Suitable Near-Native Lignins for Research

Jeremy Luterbacher

There are several methods to isolate near-native lignins, including milled-wood lignin, enzymatic lignin, cellulolytic enzyme lignin, and enzymatic mild-acidolysis lignin. Which one is the most representative of the native lignin? Herein, near-native ligni ...

Amer Chemical Soc2023

Origin of the Activity Trend in the Oxidative Dehydrogenation of Ethanol over VOx/CeO2

Oliver Kröcher, Rob Jeremiah G. Nuguid, Anna Zabilska, Olga Safonova

Supported vanadia (VOx) is a versatile catalyst for various redox processes where ceria-supported VOx have shown to be particularly active in the oxidative dehydrogenation (ODH) of alcohols. In this work, we clarify the origin of the volcano-shaped ethanol ...

Wiley-VCH Verlag GmbH2023

A Sprayable Electrically Conductive Edible Coating for Piezoresistive Strain Sensing

Dario Floreano, Bokeon Kwak, Pietro Rossi

Edible electronics leverages the electronic properties of food-derived materials to deliver safer technologies that can be degraded (or digested) in the environment (or body) at the end-of-life. Sensors will be central to future smart edible robots, and ed ...

2024

Cotton yarns decorated with hydrothermally reduced graphene oxide for flexible supercapacitors

Dou Du, Xing Wang, Lin Li

Cotton fibers, a natural cellulose, have played a critical role in the development of wearable energy storage, owning to their wearability, integrability, eco-benignity, and cost effectiveness. Graphene, a two-dimensional carbon material, possesses excelle ...

Elsevier2023

Model-based scale-up of a continuously operated consolidated bioprocess based on a microbial consortium for the production of ethanol

David Beat Dempfle

This work demonstrated that consolidated bioprocessing is a promising concept for conversion of lignocellulose to ethanol at industrial scale. CBP offers great cost saving potential, is feasible to be operated continuously and may be scaled up due to exten ...

EPFL2022

Tandem effect of Ag@C@Cu catalysts enhances ethanol selectivity for electrochemical CO2 reduction in flow reactors

Andreas Züttel, Thi Ha My Pham, Cedric David Koolen, Wen Luo, Jie Zhang, Mo Li, Youngdon Ko, Liping Zhong

CO-selective metals (e.g., Ag) on Cu catalysts improve the selec-tivity of multi-carbon (C2+) products in electrochemical CO2 reduc-tion. However, the origin of the improvement remains unclear due to the convolution of tandem and interface effects. Here, A ...

ELSEVIER2022

Sustainable polyesters via direct functionalization of lignocellulosic sugars

François Maréchal, Harm-Anton Klok, Véronique Michaud, Jeremy Luterbacher, Yves Leterrier, Maxime Alexandre Clément Hedou, Adrien Julien Demongeot, Graham Reid Dick, Christèle Rayroud, Thibault Rambert

The development of sustainable plastics from abundant renewable feedstocks has been limited by the complexity and efficiency of their production, as well as their lack of competitive material properties. Here we demonstrate the direct transformation of the ...

2022

An optimized high throughput platform, from genetic transformation to fermentation, to screen for secreted laccases in Aspergillus niger

Laure Marie Colette Leynaud-Kieffer Curran

Many challenges are faced in the conversion of biomass into advanced biofuels, one of which is finding the correct organism for the job. The filamentous fungus Aspergillus niger has been chosen as a biocatalyst for cellulose, hemicellulose, and lignin degr ...

EPFL2021

Developing structure-oriented models for enzymatic hydrolysis of lignocellulosic biomass

Jessica Charlène Rohrbach

With the unsustainable use of fossil fuels increasing strains on human institutions and ecosystems, the development of a renewable energy alternative is of paramount importance. Second generation biorefineries, based on the production of fuels and chemical ...

EPFL2021

Techno-economic assessment of bioethanol production from lignocellulose by consortium-based consolidated bioprocessing at industrial scale

Oliver Kröcher

Lignocellulose-based biofuels are of major importance to mitigate the impact of international traffic and transport on climate change while sustaining agricultural land for food supply. Highly integrated systems like consolidated bioprocessing (CBP), where ...

ELSEVIER2021

Exergy and exergoeconomic analyses of sustainable furfural production via reactive distillation

François Maréchal

Lignocellulosic biomass is a potential renewable resource for production of high-value, sustainable products. Furfural is among the important bio-based chemicals in biorefineries. However, the conventional process of furfural production using a reaction-se ...

2021

Toward waste valorization by converting bioethanol production residues into nanoparticles and nanocomposite films

Xun Liao, Muhammad Farooq

A "waste-valorization" approach was developed to transform recalcitrant hydrolysis lignin (HL) from secondgeneration bioethanol production into multifunctional bio-based products. The hydrolysis lignin (HL) was extracted with aqueous acetone, yielding two ...

ELSEVIER2021

Advanced characterization of regioselectively substituted methylcellulose model compounds by DNP enhanced solid-state NMR spectroscopy

David Lyndon Emsley, Pierrick Berruyer, Pinelopi Moutzouri, Michel Bardet

Dynamic Nuclear Polarization MAS NMR is introduced to characterize model methylcellulose ether compounds at natural isotopic abundance. In particular an approach is provided to determine the position of the methyl ether group within the repeating unit. Spe ...

2021

Exergy assessment and techno-economic optimization of bioethanol production routes

François Maréchal

Currently, electricity generation and second-generation ethanol production from lignocellulosic feedstocks represent technological alternatives in the bioenergy sector. Nevertheless, the introduction of new production processes denotes a real challenge due ...

2020

Aldehyde-Assisted Fractionation Enhances Lignin Valorization in Endocarp Waste Biomass

Jeremy Luterbacher, Jean Thierry C Behaghel de Bueren, Florent Emmanuel Héroguel, Raymond Gérard Buser, Graham Reid Dick, Chloé Wegmann

Endocarp biomass, which forms much of the inedible portion of nuts and stone fruits, is a promising feedstock for aromatic chemical production due to its high lignin content and because it is a food industry waste. Here, we tested the nut shells and fruit ...

2020

Transformation of Glucose to 5-Hydroxymethylfurfural Over Regenerated Cellulose Supported Nb2O5 center dot nH(2)O in Aqueous Solution

Paul Joseph Dyson, Zhaofu Fei, Lu Chen, Fangmin Huang

Niobic acid (Nb2O5 center dot nH(2)O) was immobilized on regenerated cellulose (Re-Cellulose) to afford a heterogeneous catalyst, termed Nb2O5 center dot nH(2)O@Re-Cellulose, that was characterized by powder X-ray diffraction, microscopy (SEM and TEM) and ...

SPRINGER2020

Aldehyde-Assisted Lignocellulose Fractionation Provides Unique Lignin Oligomers for the Design of Tunable Polyurethane Bioresins

Jeremy Luterbacher, Jean Thierry C Behaghel de Bueren, Florent Emmanuel Héroguel, Raymond Gérard Buser, Chloé Wegmann

Thanks to chemical stabilization, aldehyde-assisted fractionation (AAF) of lignocellulosic biomass has recently emerged as a powerful tool for the production of largely uncondensed lignin. Depolymerization of AAF lignin via ether deavage provides aromatic ...

American Chemical Society2020