Publications associées à Masse molaire

Stepwise synthesis of heterotrimetallic FeII/PdII/AuI coordination cages

Kay Severin, Farzaneh Fadaei Tirani, Noga Eren

The synthesis of heterotrimetallic molecular cages is reported. The assemblies contain three types of coordination compounds: FeII clathrochelate complexes, AuI3(pyrazolate)3 complexes, and [PdII(pyridine)4]2+ complexes. The cages were obtained in a stepwi ...

2024

Study of backward Brillouin scattering in gas-filled anti-resonant fibers

Luc Thévenaz, Malak Mohamed Hossameldeen Omar Mohamed Galal, Li Zhang

Brillouin scattering in gas shows unmatched gain properties in hollow-core optical fibers filled at high pressure. Here, the gain characteristics are studied for two common gases, namely, N2 and CO2, which show distinct features and are compared to expecte ...

2023

Secondary aerosol formation during the dark oxidation of residential biomass burning emissions

Athanasios Nenes, Spyros Pandis

Particulate matter from biomass burning emissions affects air quality, ecosystems and climate; however, quantifying these effects requires that the connection between primary emissions and secondary aerosol production is firmly established. We performed at ...

ROYAL SOC CHEMISTRY2022

Effect of minor amounts of beta-calcium pyrophosphate and hydroxyapatite on the physico-chemical properties and osteoclastic resorption of beta-tricalcium phosphate cylinders

Paul Bowen, Gabrielle Anne Laguisma Sblendorio

beta-Tricalcium Phosphate (beta-TCP), one of the most used bone graft substitutes, may contain up to 5 wt% foreign phase according to standards. Typical foreign phases include beta-calcium pyrophosphate (beta-CPP) and hydroxyapatite (HA). Currently, the ef ...

KEAI PUBLISHING LTD2022

Rapid Gas Transport from Block-Copolymer Templated Nanoporous Carbon Films

Kumar Varoon Agrawal, Kuang-Jung Hsu, Marina Micari, Xuekui Duan, Mostapha Dakhchoune, Luis Francisco Villalobos Vazquez de la Parra, Jing Zhao

Porous carbon films, attributed to their superior thermal and chemical robustness, are attractive for a number of applications. In the context of molecular separation, a major focus has been on films where the effective pore diameter is lower than 1 nm, e. ...

AMER CHEMICAL SOC2021

Constraining the response factors of an extractive electrospray ionization mass spectrometer for near-molecular aerosol speciation

Julia Schmale, Imad El Haddad, Yandong Tong

Online characterization of aerosol composition at the near-molecular level is key to understanding chemical reaction mechanisms, kinetics, and sources under various atmospheric conditions. The recently developed extractive electrospray ionization time-of-f ...

2021

Ultrafast carbothermal reduction of silica to silicon using a CO2 laser beam

Jaeki Jeong

We report the extraction of silicon via a carbothermal reduction process using a CO2 laser beam as a heat source. The surface of a mixture of silica and carbon black powder became brown after laser beam irradiation for a few tens of seconds, and clear peak ...

NATURE RESEARCH2020

Selection of Water-Soluble Chitosan by Microwave-Assisted Degradation and pH-Controlled Precipitation

Sandrine Gerber, Yann Lavanchy, Céline Marie Anne Journot, Laura Camille Louise Nicolle

In the field of gene therapy, chitosan (CS) gained interest for its promise as a non-viral DNA vector. However, commercial sources of CS lack precise characterization and do not generally reach sufficient solubility in aqueous media for in vitro and in viv ...

2020

Efficiency of pre-oxidation of natural organic matter for the mitigation of disinfection byproducts: Electron donating capacity and UV absorbance as surrogate parameters

Urs von Gunten

Pre-oxidation is often used before disinfection with chlorine to decrease the reactivity of the water matrix and mitigate the formation of regulated disinfection byproducts (DBPs). This study provides insights on the impact of oxidative pre-treatment with ...

PERGAMON-ELSEVIER SCIENCE LTD2020

Quenched convergence and strong local equilibrium for asymmetric zero-range process with site disorder

Thomas Mountford

We study asymmetric zero-range processes on Z with nearest-neighbour jumps and site disorder. The jump rate of particles is an arbitrary but bounded nondecreasing function of the number of particles. We prove quenched strong local equilibrium at subcritica ...

SPRINGER HEIDELBERG2020

Composition and method for the preparation of sheets, films, fibers, and molded parts

Holger Frauenrath, Daniel Görl, Oguzhan Oguz

The invention describes a composition containing a) a functionalized polymer (10) that comprises at least one polyester segment (13) and at least one, in particular at least two, polymer aggregating segment (11, 12) capable of forming non-covalent bonds ba ...

2020

Observation of New Resonances in the Lambda(0)(b)pi(+)pi(-) System

Olivier Schneider, Aurelio Bay, Yiming Li, Guido Haefeli, Frédéric Blanc, Christoph Frei, Tatsuya Nakada, Michel De Cian, Luca Pescatore, Chitsanu Khurewathanakul, Veronica Sølund Kirsebom, François Fleuret, Matthieu Philippe Luther Marinangeli, Minh Tâm Tran, Elena Graverini, Pietro Marino, Federico Leo Redi, Renato Quagliani, Plamen Hristov Hopchev, Federico Betti, Guido Andreassi, Violaine Bellée, Aravindhan Venkateswaran, Olivier Göran Girard, Luis Miguel Garcia Martin, Axel Kuonen, Vitalii Lisovskyi, Preema Rennee Pais, Pavol Stefko, Elisabeth Maria Niel, Tara Nanut, Jian Wang, Maria Elena Stramaglia, Mingkui Wang, Vladimir Macko, Guillaume Max Pietrzyk, Zhirui Xu, Yi Zhang, Sebastian Schulte, Xiaoqing Zhou, , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , , ,

The Diverse Nature of Ion Speciation at the Nanoscale Hydrophobic/Water Interface

Sylvie Roke, Halil Ibrahim Okur, Evangelia Zdrali

Many biological systems are composed of nanoscale structures having hydrophobic and hydrophilic groups adjacent to one another and in contact with aqueous electrolyte solution. The interaction of ions with such structures is of fundamental importance. Alth ...

AMER CHEMICAL SOC2019

Composition containing a polymer and an additive

John Christopher Plummer, Holger Frauenrath, Daniel Görl

The invention describes a composition containing a) a functionalized polymer (10) that comprises at least one polymer segment (13) and at least two polymer aggregating segments (11,12) capable of forming non-covalent bonds based on a supramolecular interac ...

2019

The underappreciated role of nonvolatile cations in aerosol ammonium-sulfate molar ratios

Athanasios Nenes, Hairun Guo

Overprediction of fine-particle ammonium-sulfate molar ratios (R) by thermodynamic models is suggested as evidence for interactions with organic constituents that inhibit the equilibration of gas-phase ammonia with aerosol sulfate and questions the equilib ...

Copernicus Publications2018

An integrated concentrated solar fuel generator utilizing a tubular solid oxide electrolysis cell as solar absorber

Sophia Haussener, Meng Lin

We numerically assessed the potential of a solar reactor concept for efficient fuel processing under concentrated solar irradiation. This design integrates a cavity receiver, a tubular solid oxide electrolyzer, and the concentrated photovoltaic cells into ...

2018

Comparison of liquid hot water (LHW) and high boiling alcohol/water (HBAW) pretreatments for improving enzymatic saccharification of cellulose in bamboo

Li Chen, Li Shuai, Jing Liu, Meng Li, Yubo Zhao

Liquid hot water (LHW) and high-boiling point alcohol/water (HBAW) pretreatments were compared to improve enzymatic saccharification of cellulose in moso bamboo. When pretreatments were conducted at 200 degrees C for 40 min, HBAW (20% (v/v) 1,4- butanediol ...

Elsevier Science Bv2017

Effect of Surface Charge on Surface-Initiated Atom Transfer Radical Polymerization from Cellulose Nanocrystals in Aqueous Media

Harm-Anton Klok, Justin Orazio Zoppe, Xingyu Xu

Cellulose nanocrystals (CNCs) with different charge densities were utilized to examine the role of electrostatic interactions on surface-initiated atom transfer radical polymerization (SI-ATRP) in aqueous media. To this end, growth of hydrophilic uncharged ...

American Chemical Society2016

Microalloying for the controllable delay of precipitate formation in metal alloys

William Curtin, Michael Frederick Francis

A model is presented to predict the effectiveness of dilute solutes in delaying precipitate formation, with application to natural and artificial aging in metal alloys. Control of aging is achieved via the binding, at natural aging temperatures, and releas ...

Elsevier2016

Effect of molecular weight in diketopyrrolopyrrole-based polymers in transistor and photovoltaic applications

Kevin Sivula, Xavier Adrian Jeanbourquin, Andrea Gasperini

Uncovering the precise effect of the conjugated polymer chain length on the semiconducting properties in thin-film devices is confounded by the step-growth polymerization techniques typically used. Here, we use preparatory size exclusion chromatography to ...

Wiley-Blackwell2016