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Publications associées (25)

Variant and Invariant States for Chemical Reaction Systems

Dominique Bonvin, Julien Léo Billeter, Sriniketh Srinivasan, Diogo Filipe Mateus Rodrigues

Models of open non-isothermal heterogeneous reaction systems can be quite complex as they include information regarding the reactions, the inlet and outlet flows, the transfer of species between phases and the transfer of energy. This paper builds on the c ...

Elsevier2015

Reaction Mechanism and Catalytic Fingerprint of Allantoin Racemase

Matteo Dal Peraro, Marco Stenta, Thomas Lemmin, Matteo Thomas Degiacomi, Christophe Bovigny

The stereospecific oxidative decomposition of urate into allantoin is the core of purine catabolism in many organisms. The spontaneous decomposition of upstream intermediates and the nonenzymatic racemization of allantoin lead to an accumulation of (R)-all ...

Amer Chemical Soc2014

Degradation of Eight Relevant Micropollutants in Different Water Matrices by Neutral Photo-Fenton Process under UV254 and Simulated Solar Light Irradiation – a comparative study

César Pulgarin, Andrzej Sienkiewicz, Dominique Grandjean, Luiz Felippe De Alencastro

This is a comparative study of photolytic degradation under exposure to UV254 nm and solar-simulator irradiation of a mixture of eight equally concentrated relevant micropollutants in the presence of H2O2 and Fe(II) in ultrapure water, Lake Geneva water, a ...

Elsevier Science Bv2014

On the stability enhancement of cuprous oxide water splitting photocathodes by low temperature steam annealing

Michael Graetzel, Morgan Mertens Stefik, Stanley David Tilley, Ludmilla Steier

Given the intermittent nature of solar radiation, the large-scale use of solar energy requires an efficient energy storage solution. So far, the only practical way to store such large amounts of energy is in the form of a chemical energy carrier, i.e., a f ...

Royal Soc Chemistry2014

A Pyridinol Acyl Cofactor in the Active Site of [Fe]-hydrogenase Evidenced by the Reactivity of Model Complexes

Xile Hu, Dafa Chen, Bowen Hu

The decomposition reaction of a water-soluble complex (see scheme; 1) in H2O confirms the existence of a unique bidentate pyridinol cofactor in [Fe]-hydrogenase. This unique moiety is confirmed for the first time by the decomposition of a well-defined mode ...

Wiley-V C H Verlag Gmbh2012

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