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Publications associées (29)

Structural characterization of framework-gas interactions in the metal-organic framework Co-2(dobdc) by in situ single-crystal X-ray diffraction

Wendy Lee Queen, Miguel Gonzalez

The crystallographic characterization of framework-guest interactions in metal-organic frameworks allows the location of guest binding sites and provides meaningful information on the nature of these interactions, enabling the correlation of structure with ...

2017

Entropy-Driven Selectivity for Chain Scission: Where Macromolecules Cleave

Ganna Gryn'ova

We show that, all other conditions being equal, bond cleavage in the middle of molecules is entropically much more favored than bond cleavage at the end. Multiple experimental and theoretical approaches have been used to study the selectivity for bond clea ...

Wiley-VCH Verlag GmbH2016

Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

Nicolai Cramer, David Kossler, Christopher Gordon Newton

Application of chiral derivatives of the versatile and ubiquitous cyclopentadienyl ligand has long remained an underdeveloped area in asymmetric catalysis. In this Perspective we highlight recent exciting results that demonstrate their enormous potential. ...

American Chemical Society2016

Surface functionalization of dinuclear clathrochelates via Pd-catalyzed cross-coupling reactions: facile synthesis of polypyridyl metalloligands

Rosario Scopelliti, Kay Severin, Philip Pattison, Euro Solari, Giacomo Cecot, Mathieu Jérémie Marmier

Dinuclear clathrochelate complexes are easily accessible by reaction of zinc(II) triflate or cobalt(II) nitrate with arylboronic acids and phenoldioximes. The utilization of brominated arylboronic acids and/or brominated phenoldioximes allows preparing cla ...

2016

Facile synthesis of oligoyne amphiphiles and their rotaxanes

Holger Frauenrath, Stephen Schrettl, Tobias Hoheisel, Martin Fritzsche, Ruth Szilluweit, Emmanuel Romaric Contal

Carbon-rich organic compounds containing a series of conjugated triple bonds (oligoynes) are relevant synthetic targets, but an improved access to oligoynes bearing functional groups would be desirable. Here, we report the straightforward synthesis of two ...

Royal Soc Chemistry2015

Reversible Local and Global Switching in Multicomponent Supramolecular Networks: Controlled Guest Release and Capture at the Solution/Solid Interface

Magalí Alejandra Lingenfelder, Fernando Pablo Cometto

Dynamically switchable supramolecular systems offer exciting possibilities in building smart surfaces, the structure and thus the function of which can be controlled by using external stimuli. Here we demonstrate an elegant approach where the guest binding ...

Amer Chemical Soc2015

Reversible supramolecular modification of surfaces

Negar Moridi

Enzymes are biocatalysts widely used in a large number of industrial biotech processes as they offer clear advantages over their chemical counterparts. Indeed, enzymes often show high substrate selectivity along with elevated turnover rates. Enzymatic cata ...

EPFL2015

Local Conformational Switching of Supramolecular Networks at the Solid/Liquid Interface

Klaus Kern, Magalí Alejandra Lingenfelder, Fernando Pablo Cometto

We use the electric field in a scanning tunneling microscope to manipulate the transition between open and close packed 2D supramolecular networks of neutral molecules in nonpolar media. We found that while the magnitude of the applied field is not decisiv ...

Amer Chemical Soc2015

Characterization of Solid-Liquid Interfaces with High-Resolution Atomic Force Microscopy

Maria Ricci

Solid-liquid interfaces are ubiquitous. Despite the unquestioned relevance, many scientific research fields rely on simplified or macroscopic descriptions, discarding the molecular nature of the constituents. However, it is the specific molecular interacti ...

EPFL2015

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