Publications associées à Période 3 du tableau périodique

Theory-guided development of homogeneous catalysts for the reduction of CO2 to formate, formaldehyde, and methanol derivatives

Matthew Wodrich, Anne-Clémence Corminboeuf, Shubhajit Das, Hanna Hinrika Cramer

The stepwise catalytic reduction of carbon dioxide (CO2) to formic acid, formaldehyde, and methanol opens non-fossil pathways to important platform chemicals. The present article aims at identifying molecular control parameters to steer the selectivity to ...

2023

Bacterial inactivation in sunlit surface waters is dominated by reactive species that emanate from the synergy between light, iron, and natural organic matter

César Pulgarin, Stefanos Giannakis, Jun Ma, Da Wang, Shuang Song

In this study, the synergistic and antagonistic effects of Fe species and coexisting natural organic matter (NOM) on the efficacy of solar light disinfection of water are investigated. Different initial iron species (Fe2+/Fe3+) and naturalorganic matter ty ...

Elsevier2023

Development of Cyclopentadienylcobalt(III) Catalyzed Asymmetric C-H Functionalizations

Kristers Ozols

Transition metal catalyzed C-H activation plays a major role in modern organic chemistry, affording mild, selective and atom-efficient protocols. Most of current developments in the field rely on the use of several precious metals. As a consequence, an int ...

EPFL2022

Optical spectroscopy of earth-abundant zinc pnictides for photovoltaics

Elias Zsolt Stutz

Zinc phosphide (Zn3P2) is an earth-abundant semiconductor with promising properties for applications as an absorber in photovoltaics. To beat the 40 years old record power conversion efficiency of solar cells made with this material, a deep understanding o ...

EPFL2022

Showcasing the optical properties of monocrystalline zinc phosphide thin films as an earth-abundant photovoltaic absorber

Anna Fontcuberta i Morral, Elias Zsolt Stutz, Jean-Baptiste Leran, Mahdi Zamani, Simon Robert Escobar Steinvall, Rajrupa Paul, Mirjana Dimitrievska, Léa Buswell

Zinc phosphide, Zn3P2, is a semiconductor with a high absorption coefficient in the spectral range relevant for single junction photovoltaic applications. It is made of elements abundant in the Earth's crust, opening up a pathway for large deployment of so ...

2022

Elemental and Thermo-gravimetric Characterization of Trace Metals in Leaves and Soils as Bioindicators of Pollution in Kyiv City

Christian Ludwig, Ajay Bhagwan Patil, Mohamed Tarik

In this study, leaf and soil samples were used as bio-monitors for different alkali and heavy metals at six different locations in Kyiv city. Using x–y plots of the inductively coupled plasma optical emission spectroscopy (ICP-OES) data measured the discre ...

2021

Towards versatile conversations with data-driven dialog management and its integration in commercial platforms

Conversational interfaces have recently become a ubiquitous element in both the personal sphere by easing access to services, and industrial environments by the automation of services, improved customer support and its corresponding cost savings. However, ...

2021

Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays

Andrea Cannizzo, Giulia Fulvia Mancini, Camila Bacellar Cases Da Silveira, Martin Beck, Victoria Kabanova, Samuel Menzi

OLED technology beyond small or expensive devices requires light-emitters, luminophores, based on earth-abundant elements. Understanding and experimental verification of charge transfer in luminophores are needed for this development. An organometallic mul ...

Nature Publishing Group2020

Growth and characterisation of earth-abundant semiconductor nanostructures for solar energy harvesting

Simon Robert Escobar Steinvall

Zinc phosphide (Zn3P2) is a compound semiconductor based on earth-abundant elements with functional properties ideal for solar cell applications. Cheap, abundant, and renewable energy sources are increasingly imperative due to the imminent threat posed by ...

EPFL2020

Nanoscale mechanism of UO2 formation through uranium reduction by magnetite

Rizlan Bernier-Latmani, Barbora Bártová, Thomas La Grange, Zezhen Pan

Uranium (U) is a ubiquitous element in the Earth's crust at similar to 2 ppm. In anoxic environments, soluble hexavalent uranium (U(VI)) is reduced and immobilized. The underlying reduction mechanism is unknown but likely of critical importance to explain ...

Nature Research2020

A multi-technique approach to study the microstructural properties of tin-based transparent conductive oxides

Federica Landucci

Transparent conductive oxides (TCOs) are semiconductor-like materials that exhibit high electrical conductivity and high optical transparency combined. They are adopted in various applications ranging from gas sensors, to electrochromic windows, to photovo ...

EPFL2019

Synthesis and Application of Transition Metal Oxides as Oxygen Evolution Catalysts

Laurent Liardet

Nowadays, mankind is facing an important energy challenge. Depletion in fossil fuels reserves and increasing energy demand, coupled with the problematic greenhouse effect induced by massive anthropogenic release of carbon dioxide into the atmosphere, are d ...

EPFL2019

On the necessity of improving the environmental impacts of furniture and appliances in net-zero energy buildings

Thomas Bernard Paul Jusselme, Endrit Hoxha

There is now clear evidence regarding the extensive use of furniture and appliances in daily human life, but there is less evidence of their impact on the environment. Responding to this gap in knowledge, this study focuses on an assessment of the environm ...

Elsevier2017

Parental arc magma compositions dominantly controlled by mantle-wedge thermal structure

Stéphane Laurent Escrig

The processes that lead to the fourfold variation in arc-averaged compositions of mafic arc iavas remain controversial. Control by the mantle-wedge thermal structure is supported by chemical correlations with the thickness of the underlying arc crust(1-3), ...

Nature Publishing Group2016

An Indium-Free Anode for Large-Area Flexible OLEDs: Defect-Free Transparent Conductive Zinc Tin Oxide

Christophe Ballif, Aïcha Hessler-Wyser, Quentin Thomas Jeangros, Ali Dabirian, Monica Morales Masis, Fabien Paul Jacques Dauzou

Flexible large-area organic light-emitting diodes (OLEDs) require highly conductive and transparent anodes for efficient and uniform light emission. Tin-doped indium oxide (ITO) is the standard anode in industry. However, due to the scarcity of indium, alt ...

Wiley-Blackwell2016

Ga-assisted growth of GaAs nanowires on silicon, comparison of surface SiOx of different nature

Anna Fontcuberta i Morral, Federico Matteini, Esther Alarcon Llado, Gözde Tütüncüoglu

Physical properties of surfaces are extremely important for initiation and nucleation of crystal growth, including nanowires. In recent years, fluctuations in surface characteristics have often been related to unreproducible growth of GaAs nanowires on Si ...

Elsevier2014

First-Principles Determination of Phonon Lifetimes, Mean Free Paths, and Thermal Conductivities in Crystalline Materials: Pure Silicon and Germanium

Nicola Marzari

The thermal properties of insulating, crystalline materials are essentially determined by their phonon dispersions, the finite-temperature excitations of their phonon populations-treated as a Bose-Einstein gas of harmonic oscillators-and the lifetimes of t ...

Springer-Verlag Berlin2014

Modelling oriented investigations of primary radiation damage in ultra high purity Fe and FeCr alloys

Anna Prokhodtseva

In the quest of the structural materials for the future fusion reactor, it has been shown that ferritic/martensitic (F/M) steels are very promising candidates, with a good radiation resistance in terms of damage accumulation in the microstructure relative ...

EPFL2013

ORIGIN: metal creation and evolution from the cosmic dawn

Mikhail Chapochnikov, Alexey Boyarsky, Oleg Ruchayskiy, Douglas Cameron Watson, Simone Campana

ORIGIN is a proposal for the M3 mission call of ESA aimed at the study of metal creation from the epoch of cosmic dawn. Using high-spectral resolution in the soft X-ray band, ORIGIN will be able to identify the physical conditions of all abundant elements ...

Springer2012

Cu-based p-type Oxide Photocathodes for Solar Hydrogen Production : a Study on Photoelectrochemical Performance and Stability

Adriana Paracchino

The actualization of a hydrogen economy requires cost-effective and environmentally benign solutions to hydrogen production. Chemical energy in the form of hydrogen is more interesting than electricity to satisfy our ever-increasing energy demand because i ...

EPFL2012