Publications associées à Dioxine

The Bioaccumulation of Ionizable Organic Compounds in Fish Cell Lines

Bioaccumulation is defined as the enrichment of a compound in an organism relative to the surrounding water or its food, and is an important endpoint in chemical risk assessment. Under laboratory conditions, bioaccumulation is measured as bioconcentration ...

EPFL2023

Widespread detection of chlorine oxyacids in the Arctic atmosphere

Julia Schmale, Ivo Fabio Beck, Hélène Paule Angot

Observations are reported of HClO3 and HClO4 in the atmosphere and their widespread occurrence over the pan-Arctic during spring, providing further insights into atmospheric chlorine cycling in the polar environment. ...

Nature Portfolio2023

Chlorination of arenes via the degradation of toxic chlorophenols

Paul Joseph Dyson, Mingyang Liu, Xuemei Yang

Aryl chlorides are among the most versatile synthetic precursors, and yet inexpensive and benign chlorination techniques to produce them are underdeveloped. We propose a process to generate aryl chlorides by chloro-group transfer from chlorophenol pollutan ...

2022

Biochar and environmental sustainability: Emerging trends and techno-economic perspectives

Edgard Gnansounou

Environmental pollutants including emerging contaminants are a growing concern worldwide. Organic wastes, such as food waste, compost, animal manure, crop residues, and sludge are generally used as feedstock. The conventional treatment methodologies (prima ...

Elsevier2021

Micropollutants as internal probe compounds to assess UV fluence and hydroxyl radical exposure in UV/H 2 O 2 treatment

Urs von Gunten, Silvio Canonica, Fabienne Eugster, Robin Wünsch, Thomas Wintgens

Organic micropollutants (MPs) are increasingly detected in water resources, which can be a concern for human health and the aquatic environment. Ultraviolet (UV) radiation based advanced oxidation processes (AOP) such as low-pressure mercury vapor arc lamp ...

PERGAMON-ELSEVIER SCIENCE LTD2021

Chlorination of Phenols Revisited: Unexpected Formation of α,β-Unsaturated C4-Dicarbonyl Ring Cleavage Products

Urs von Gunten

Despite decades of research on the fate of phenolic compounds when water is disinfected with hypochlorous acid (HOCl), there is still considerable uncertainty regarding the formation mechanisms and identity of ring cleavage products, especially at higher c ...

2020

Heavy metals and persistent organic pollutants contamination in river, estuary, and marine sediments from Atlantic Coast of Democratic Republic of the Congo

Florian Frédéric Vincent Breider, Dominique Grandjean

The pollution assessment and the evaluation of potential risks in the Atlantic Coastal Region of the Democratic Republic of the Congo are still very limited. Consequently, the present study investigates for the first time the concentrations of heavy metals ...

Springer2020

Assessing The Bioaccumulation Potential Of Ionizable Organic Compounds: Current Knowledge And Research Priorities

Kristin Schirmer

The objective of the present study was to review the current knowledge regarding the bioaccumulation potential of ionizable organic compounds (IOCs), with a focus on the availability of empirical data for fish. Aspects of the bioaccumulation potential of I ...

Society of Environmental Toxicology and Chemistry Press2017

Elevated Concentrations of 4-Bromobiphenyl and 1,3,5-Tribromobenzene Found in Deep Water of Lake Geneva Based on GCxGC-ENCI-TOFMS and GCxGC-mu ECD

Jeremy Samuel Arey, Saer Samanipour, Petros Dimitriou Christidis, Deedar Nabi

We quantified the concentrations of two little-studied brominated pollutants, 1,3,5-tribromobenzene (TBB) and 4-bromobiphenyl (4BBP), in the deep water column and sediments of Lake Geneva. We found aqueous concentrations of 625 +/- 68 pg L-1 for TBB and 66 ...

Amer Chemical Soc2017

Indirect Evidence Link PCB Dehalogenation with Geobacteraceae in Anaerobic Sediment-Free Microcosms

Christof Holliger, Pierre Rossi, Luiz Felippe De Alencastro, Martina Praveckova

Although polychlorinated biphenyls (PCBs) production was brought to a halt 30 years ago, recalcitrance to degradation makes them a major environmental pollutant at a global scale. Previous studies confirmed that organohalide-respiring bacteria (OHRB) were ...

Frontiers Media SA2016

Validation of an integrative methodology to assess and monitor reductive dechlorination of chlorinated ethenes in contaminated aquifers

Christof Holliger, Pierre Rossi, Sonia Estelle Tarnawski

Bioremediation of tetra-and trichloroethene-contaminated aquifers is requently hampered due to incomplete dechlorination to the more toxic dichloroethene (DCE) and vinyl chloride (VC), indicating insufficient knowledge about the biological mechanisms relat ...

2016

Nanotoxicology: 2D analysis in a 3D matrix

Anders Meibom, Louise Helene Soegaard Jensen

Engineered nanoparticles are the fastest growing nanotechnology product, and of increasing environmental concern. Examples include antimicrobial silver nanoparticles, iron oxide particles used in bulk scale for environmental remediation, and micro- and nan ...

2016

Divergent PCB organohalide-respiring consortia enriched from the efflux channel of a former Delor manufacturer in Eastern Europe

Christof Holliger, Pierre Rossi, Luiz Felippe De Alencastro, Martina Praveckova

Polychlorinated biphenyl (PCB) organohalide-respiring communities from the efflux channel of a former Delor manufacturer in Eastern Slovakia were assessed using metagenomic, statistical and cultivation-adapted approaches. Multivariate analysis of environme ...

Elsevier2015

Small-Molecule Adsorption in Open-Site Metal-Organic Frameworks: A Systematic Density Functional Theory Study for Rational Design

Berend Smit

Using density functional theory, we systematically compute and investigate the binding enthalpies of 14 different small molecules in a series of isostructural metalorganic frameworks, M-MOF-74, with M = Mg, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn. The small ...

American Chemical Society2015

Degradation of Eight Relevant Micropollutants in Different Water Matrices by Neutral Photo-Fenton Process under UV254 and Simulated Solar Light Irradiation – a comparative study

César Pulgarin, Andrzej Sienkiewicz, Dominique Grandjean, Luiz Felippe De Alencastro

This is a comparative study of photolytic degradation under exposure to UV254 nm and solar-simulator irradiation of a mixture of eight equally concentrated relevant micropollutants in the presence of H2O2 and Fe(II) in ultrapure water, Lake Geneva water, a ...

Elsevier Science Bv2014

Water use and quality in life cycle assessment : identifying good practices and developing operational spatial approaches

Anna Kounina Massé

Pressure on freshwater resources is increasingly covered by methodological developments addressing freshwater use in the field of Life Cycle Assessment (LCA). These developments ultimately lead to the publication of the ISO 14046 standard to define the pri ...

EPFL2014

Trace metals and persistent organic pollutants in sediments from river-reservoir systems in Democratic Republic of Congo (DRC): Spatial distribution and potential ecotoxicological effects

Dominique Grandjean, Luiz Felippe De Alencastro

This paper discusses the occurrence and spatial distribution of metals and persistent organic pollutants (POPs: including organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), Polybrominated diphenyl ethers (PBDEs), and polycyclic aromatic hy ...

Elsevier2014