Publications associées à Air separation

Gas Separation Membranes with Atom-Thick Nanopores: The Potential of Nanoporous Single-Layer Graphene

Kumar Varoon Agrawal, Kuang-Jung Hsu, Cédric Karel J Van Goethem, Luis Francisco Villalobos Vazquez de la Parra, Deepu Joseph Babu

Gas separation is one of the most important industrial processes and is poised to take a larger role in the transition to renewable energy, e.g., carbon capture and hydrogen purification. Conventional gas separation processes involving cryogenic distillati ...

AMER CHEMICAL SOC2022

Two-dimensional atomically bridged nanoporous silicate-based membranes for gas separation

Mostapha Dakhchoune

The synthesis of molecular-sieving two-dimensional zeolitic membranes by the assembly of crystalline building blocks without resorting to the secondary growth process is highly desirable. The precise pore size for molecular sieving, ultrathin thickness, an ...

EPFL2021

Oxygen enrichment of air: Performance guidelines for membranes based on techno-economic assessment

Kumar Varoon Agrawal, Marina Micari

The use of oxygen-enriched air (OEA) is an important strategy for reducing process cost and CO2 emissions in several industrial processes. Membrane-based processes, attributing to their high energy efficiency, are promising alternatives to cryogenic distil ...

ELSEVIER2022

Rapid Gas Transport from Block-Copolymer Templated Nanoporous Carbon Films

Kumar Varoon Agrawal, Kuang-Jung Hsu, Marina Micari, Xuekui Duan, Mostapha Dakhchoune, Luis Francisco Villalobos Vazquez de la Parra, Jing Zhao

Porous carbon films, attributed to their superior thermal and chemical robustness, are attractive for a number of applications. In the context of molecular separation, a major focus has been on films where the effective pore diameter is lower than 1 nm, e. ...

AMER CHEMICAL SOC2021

Adhesion of a tape loop

Harmeet Singh

In this work, we revisit experimentally and theoretically the mechanics of a tape loop. Using primarily elastic materials (polydimethylsiloxane, PDMS, or polycarbonate, PC) and confocal microscopy, we monitor the shape as well as the applied forces during ...

ROYAL SOC CHEMISTRY2020

Gas-sieving zeolitic membranes fabricated by condensation of precursor nanosheets

Michele Ceriotti, Kumar Varoon Agrawal, Pascal Alexander Schouwink, Luis Francisco Villalobos Vazquez de la Parra, Mostapha Dakhchoune, Claudia Esther Avalos, Yu Han, Rocio Semino Barbaresi

The synthesis of molecular-sieving zeolitic membranes by the assembly of building blocks, avoiding the hydrothermal treatment, is highly desired to improve reproducibility and scalability. Here we report exfoliation of the sodalite precursor RUB-15 into cr ...

2020

Characterization of metal organic frameworks of interest for gas adsorption/separation applications

Mehrdad Asgari

Metal-Organic Frameworks (MOFs) are a class of porous materials that are applicable in many energy and environmentally relevant areas, due to their unique features including unprecedented internal surface areas and easy chemical tunability. Gas separation ...

EPFL2020

From Experiment to Kinetic and Thermodynamic Modelling of Precipitation: Examples of Calcium Silicate Hydrate (C-S-H) and Gold Nanoparticles

Mohammad Reza Andalibi

Precipitation is a process wherein a solid phase forms from a solution. Precipitation is at the heart of many industries producing pharmaceuticals, catalysts, ceramics, and nanoparticles. In addition to being a material synthesis route, precipitation has i ...

EPFL2019

Thermal water purification system and method for operating said system

Chin Lee Ong

The present invention relates to a thermal water purification system (10) for producing a distillate liquid from a raw liquid (LP, LB) comprising: - a plurality of distilling units (1 a-1h) which are consecutively flowed through by the raw feed liquid (LP, ...

2017

Understanding Small-Molecule Interactions in Metal-Organic Frameworks: Coupling Experiment with Theory

Berend Smit, Wendy Lee Queen

Metal-organic frameworks (MOFs) have gained much attention as next-generation porous media for various applications, especially gas separation/storage, and catalysis. New MOFs are regularly reported; however, to develop better materials in a timely manner ...

Wiley-Blackwell2015

What Are the Best Materials To Separate a Xenon/Krypton Mixture?

Berend Smit, Cory Matthew Simon, Rocio Mercado, Sondre Kvalvag Schnell

Accelerating progress in the discovery and deployment of advanced nanoporous materials relies on chemical insight and structure-property relationships for rational design. Because of the complexity of this problem, trial-and-error is heavily involved in th ...

American Chemical Society2015

Energy efficiency improvement by applying thermodynamic optimization of distillation columns in the site scale integration

François Maréchal, Nasibeh Pouransari

This study aims to improve the energy efficiency of an industrial site by applying the thermodynamic analysis of distillation columns together with the total site integration (TSI). Several methods have been proposed in the literatures for the thermodynami ...

2013

Parametric study of water column separation in Francis pump-turbine draft tube

François Avellan, Christophe Nicolet, Sébastien Alligné

The paper presents the modelling, simulation and analysis of the transient behaviour of a 340 MW pump-turbine in case of emergency shutdown in generation mode with particular attention to the possible draft tube water column separation. First, the model of ...

Soc Hydrotechnique France2012

A process and a plant for hydrothermal SNG production from waste biomass

François Maréchal, Martin Gassner, Frédéric Vogel

It is the aim of the present invention to provide a system and a process for hydrothermal SNG production from waste biomass having a design of the product separation that not only considers the grid quality specifications for SNG, but also the recovery of ...

2010

Improved stability of La0.5Sr0.5FeO3 by Ta-doping for oxygen separation membrane application

Jan Van Herle, Stefan Diethelm, Defne Bayraktar

(La,Sr)FeO3 mixed conducting perovskites are considered as interesting candidates for oxygen separation membranes but they suffer from limited structural stability in a large oxygen partial pressure (pO2) gradient, because of their propensity for chemical ...

2009

Numerical simulation and optimization of multi-step batch membrane processes

A simple numerical technique is presented for batch membrane filtration design. The underlying model accounts for variable solute rejection coefficients, and it has a modular structure which permits to easily describe the batch process involving different ...

2008

Lanthanide luminescent mesomorphic complexes with macrocycles derived from diaza-18-crown-6

Rosario Scopelliti, Jean-Claude Bünzli, Stéphane Suarez

Four tetracatenar (L1–L4) and one hexacatenar (L5) ligands, derived from the diaza-18-crown-6 framework, are synthesized and characterized. In these ligands, the amine functions are fitted with benzoyloxybenzyl linker groups, attached either with a carbony ...

2005

Liquid-core capsules as a tool in biotransformations

The aim of this thesis was to develop a new type of liquid-core capsules obtained by co-extrusion using the laminar jet break-up technique. These capsules, composed of an organic phase as the core and a hydrogel membrane, were meant to be applied as an in- ...

EPFL2005