Publications associées à Acide sulfureux

Iodine oxoacids enhance nucleation of sulfuric acid particles in the atmosphere

Andrea Baccarini, Imad El Haddad, Mihnea Surdu, Lubna Dada, André Welti, Houssni Lamkaddam

The main nucleating vapor in the atmosphere is thought to be sulfuric acid (H2SO4), stabilized by ammonia (NH3). However, in marine and polar regions, NH3 is generally low, and H2SO4 is frequently found together with iodine oxoacids [HIOx, i.e., iodic acid ...

American Association for the Advancement of Science2023

Poisoning Effects of Cerium Oxide (CeO2) on the Performance of Proton Exchange Membrane Fuel Cells (PEMFCs)

Jan Van Herle, Hossein Pourrahmani

In this study, the poisoning effects of cerium oxide (CeO2) as the contaminant on the performance of proton exchange membrane fuel cells (PEMFCs) are evaluated. An experimental setup was developed to analyze the performance characteristic (I-V) curves in c ...

MDPI2022

Investigation of new particle formation mechanisms and aerosol processes at Marambio Station, Antarctic Peninsula

Lubna Dada

Understanding chemical processes leading to the formation of atmospheric aerosol particles is crucial to improve our capabilities in predicting the future climate. However, those mechanisms are still inadequately characterized, especially in polar regions. ...

Copernicus GmbH2022

An evaluation of new particle formation events in Helsinki during a Baltic Sea cyanobacterial summer bloom

Lubna Dada, Marjan Marbouti

Several studies have investigated new particle formation (NPF) events from various sites ranging from pristine locations, including forest sites, to urban areas. However, there is still a dearth of studies investigating NPF processes and subsequent aerosol ...

Copernicus GmbH2022

Low‐Volatility Vapors and New Particle Formation Over the Southern Ocean During the Antarctic Circumnavigation Expedition

Julia Schmale, Andrea Baccarini, Robin Lewis Modini

During summer, the Southern Ocean is largely unaffected by anthropogenic emissions, which makes this region an ideal place to investigate marine natural aerosol sources and processes. A better understanding of natural aerosol is key to constrain the preind ...

2021

Iodic acid, sulfuric acid and methanesulfonic acid collected during the Arctic Ocean 2018 expedition

Julia Schmale, Andrea Baccarini

Measurements of iodic acid, sulfuric acid and methanesulfonic acid concentration in the gas phase obtained with a nitrate chemical ionization mass spectrometer (we used an APi-TOF mass spectrometer produced by Tofwerk AG coupled with a Chemical ionization ...

2020

Frequent new particle formation over the high Arctic pack ice by enhanced iodine emissions

Julia Schmale, Andrea Baccarini

In the central Arctic Ocean the formation of clouds and their properties are sensitive to the availability of cloud condensation nuclei (CCN). The vapors responsible for new particle formation (NPF), potentially leading to CCN, have remained unidentified s ...

Nature Research2020

Sulfuric acid condensation sink calculated for the Arctic Ocean 2018 expedition

Julia Schmale, Andrea Baccarini

The condensation sink is a measure of the sulfuric acid lifetime against condensation on preexisting aerosol particles. Dimensionally it is the inverse of a time (reported in per second) and it is calculated starting from the aerosol size distribution. A l ...

2020

Tribocorrosion of a CoCrMo alloy in sulfuric acid - Glycerol mixtures

Stefano Mischler, Shoufan Cao

This work reports on the tribocorrosion properties of a CoCrMo alloy sliding under imposed passive potential against alumina in sulfuric acid-glycerol mixtures exhibiting different viscosities and thus, in principle, lubrication properties. As expected, we ...

ELSEVIER SCIENCE SA2020

Ultrafine particle concentration measured during the Arctic Ocean 2018 expedition

Julia Schmale, Andrea Baccarini

The ultrafine particle (UFP) concentration is the concentration of particles having a diameter between 2.5 and 15 nm, it is reported in terms of particle number per cubic centimeter at a time resolution of 10 minutes. UFP are the smallest particles within ...

2020

Optimization of Lignin Extraction from Pine Wood for Fast Pyrolysis by Using γ-valerolactone-Based Binary Solvent System

Jeremy Luterbacher, Allen Puente-Urbina

Fast pyrolysis of lignin is a promising method to produce aromatic chemicals and fuels. Lignin structure and pyrolysis conditions determine the liquid yield and product selectivity. Extraction of pine wood using γ-valerolactone (GVL) mixed with water in th ...

2019

Efficiency improvement of an all-vanadium redox flow battery by harvesting low-grade heat

Hubert Girault, Danick Reynard, Alberto Battistel, Christopher Raymond Dennison

Redox flow batteries (RFBs) are rugged systems, which can withstand several thousand cycles and last many years. However, they suffer from low energy density, low power density, and low efficiency. Integrating a Thermally Regenerative Electrochemical Cycle ...

2018

Applicability of a recently proposed tribocorrosion model to CoCr alloys with different carbides content

Stefano Mischler, Marco Cantoni, Shoufan Cao

Existing sliding tribocorrosion models have been developed for homogeneous passive metals such as stainless steel and pure metals. Many technical alloys contains however second phases, usually much harder than the metallic matrix, intended to provide bette ...

Elsevier Science Sa2017

Bubble electrodeposition of gold porous nanocorals for the enzymatic and non-enzymatic detection of glucose

Sandro Carrara, Irene Taurino

Au nanocorals are grown on gold screen-printed electrodes (SPEs) by using a novel and simple one-step electro-deposition process. Scanning electron microscopy was used for the morphological characterization. The devices were assembled on a three-electrode ...

Elsevier2016

Fine structuration of low-temperature co-fired ceramic (LTCC) microreactors

Paul Muralt, Albert Renken, Bo Jiang, Lioubov Kiwi, Thomas Maeder, Julien Haber

The development of microreactors that operate under harsh conditions is always of great interest for many applications. Here we present a microfabrication process based on low-temperature co-fired ceramic (LTCC) technology for producing microreactors which ...

Royal Society of Chemistry2015

Preparation of titania covered multi-walled carbon nanotube thin films

László Forró, Arnaud Magrez, Endre Horvath, Klara Hernadi

The aim of this work was to investigate the effects of relative humidity on the formation of titania layers on the surface of multi-walled carbon nanotubes under regulated conditions in a sealed system. Reactive precursor compounds such as titanium (IV) ox ...

Elsevier Sci Ltd2015

Mechanism of oxygen reduction by metallocenes near liquid|liquid interfaces

Hubert Girault, Pekka Eero Peljo, Thomas James Stockmann, Haiqiang Deng

The mechanism of the oxygen reduction reaction (ORR) at a liquid|liquid interface, employing ferrocene (Fc) derivatives – such as decamethylferrocene (DMFc) – as a lipophilic electron donor along with sulfuric acid as an aqueous proton source, was elucidat ...

Elsevier2014

Screen-printed electrochemical chromium (VI) sensing electrodes for effluent bioremediation monitoring

Thomas Maeder, Caroline Jacq

Simple, low-cost and acid-resistant carbon-based screen-printed electrodes (SPEs) addressed to detection of hexavalent chromium species, Cr(VI), in sulfuric acid at pH about 1, were prepared and characterized. Working and counter electrodes were prepared j ...

Elsevier2014

Acid-Catalyzed Chitin Liquefaction in Ethylene Glycol

Felix Daniel Bobbink, Ning Yan, Xi Chen

This paper describes chitin liquefaction in ethylene glycol (EG) under the catalysis of sulfuric acid for the first time. Up to 75% of chitin was liquefied at 165 degrees C within 90 min by using 8 wt % of acid (refer to the mass of EG). The major products ...

Amer Chemical Soc2014

Impact of Operating Regime on Aviation Engine Emissions: Modeling Study

Pénélope Leyland

This work is focused on the numerical analysis of pollutant formation in an aviation gas turbine engine at different values of power setting. The analysis is conducted on the basis of a comprehensive approach treating the reactor net model for description ...

Amer Inst Aeronautics Astronautics2013