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Publications associées (28)

Active apolar doping determines routes to colloidal clusters and gels

Ignacio Pagonabarraga Mora

Collections of interacting active particles, self-propelling or not, have shown remarkable phenomena including the emergence of dynamic patterns across different length scales, from animal groups to vibrated grains, microtubules, bacteria, and chemicalor f ...

National Academy of Sciences2018

Forced Electrocodeposition of Silica Particles into Nickel Matrix by Horizontal Impinging Jet Cell

Hubert Girault, Véronique Amstutz, Desire Martial Koutouan Abro

The improvement of silica particle codeposition into a nickel electrodeposited composite coating (ECC) by a double face horizontal impinging jet cell (IJC) has been studied. The microstructure of coatings was examined by means of scanning electron microsco ...

2017

Determining the Surface Structure of Silicated Alumina Catalysts via Isotopic Enrichment and Dynamic Nuclear Polarization Surface-Enhanced NMR Spectroscopy

David Lyndon Emsley, Brennan James Walder, Jasmine Viger-Gravel

Isotopic enrichment of Si-29 and DNP-enhanced NMR spectroscopy are combined to determine the detailed surface structure of a silicated alumina catalyst. The significant sensitivity enhancement provided by DNP is vital to the acquisition of multinuclear and ...

American Chemical Society2017

Ketenimines from Isocyanides and Allyl Carbonates: Palladium-Catalyzed Synthesis of β,γ-Unsaturated Amides and Tetrazoles

Qian Wang, Jieping Zhu, Mathias Mamboury, Guanyinsheng Qiu

The reaction of allyl ethyl carbonates with isocyanides in the presence of a catalytic amount of Pd(OAc)2 provided ketenimines through b-hydride elimination of the allyl imidoylpalladium intermediates. The insertion of the isocyanide into the p-allyl Pd co ...

Wiley-Blackwell2016

Gas Sampling Using Convection and Humidity Stabilization to Improve Point Gas Sensor Responses

Emily Ann Hammes

Many diseases including sick building syndrome, respiratory problems and cancers can be caused by exposure to high concentrations of toxins commonly used in modern building materials, paints, glues and furniture. To minimize exposure to these toxins, it is ...

EPFL2016

Controlling Mesopore Size and Processability of Transparent Enzyme-Loaded Silica Films for Biosensing Applications

Heinrich Hofmann, Bernard Wenger, Oswaldo Javier Pérez Anguiano, Raphaël Pugin, Emmanuel Scolan

Silica-based nanoporous thin films including large mesopores are relevant as enzyme supports for applications in biosensing. The diffusion and immobilization of large biomolecules such as enzymes in such porous films require the presence of large mesopores ...

Amer Chemical Soc2015

Silaffins in Silica Biomineralization and Biomimetic Silica Precipitation

Carolin Christine Lechner

Biomineralization processes leading to complex solid structures of inorganic material in biological systems are constantly gaining attention in biotechnology and biomedical research. An outstanding example for biomineral morphogenesis is the formation of h ...

Mdpi Ag2015

Ambient in situ analysis and imaging of both hydrophilic and hydrophobic thin layer chromatography plates by electrostatic spray ionization mass spectrometry

Hubert Girault, Liang Qiao, Xiaoqin Zhong

Electrostatic spray ionization (ESTASI) mass spectrometry imaging (MSI), recently developed to profile spatial distribution of chemical and biochemical molecules on an insulating surface under ambient conditions, has been applied to identify and quantify c ...

RSC Publishing2015

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