Concept

Phosphate

Publications associées (26)

Palladium-based supramolecular assemblies: from complex structures to water-soluble anion-receptors

The combination of palladium salts and bipyridyl ligands can lead to the formation of a large variety of coordination complexes, with different shapes and sizes, displaying a very versatile host-guest chemistry. Increasing their structural complexity remai ...

EPFL2024

Deriving Major Ion Concentrations at High Resolution from Continuous Electrical Conductivity Measurements in Karst Systems

Paolo Benettin

Time series of hydrochemical parameters support the investigation of dominant karst hydrological processes and conceptual model structures. Nevertheless, high costs for sample collection and analyses cause hydrochemical data to be rarely available at a suf ...

SPRINGER INTERNATIONAL PUBLISHING AG2023

High-throughput Microfluidic Platforms for S. cerevisiae Single Cell Studies

Hon Ming Andrew Yip

Cells consume extra-cellular nutrients and resources to maintain cellular fitness. Extra-cellular conditions vary over time. Cellular programs encoded in genes adjust to adapt to the environments. Gene regulatory networks (GRNs) have evolved to be responsi ...

EPFL2022

Iron phosphate mediated magnetite synthesis: a bioinspired approach

Giulia Mirabello

The biomineralization of intracellular magnetite in magnetotactic bacteria (MTB) is an area of active investigation. Previous work has provided evidence that magnetite biomineralization begins with the formation of an amorphous phosphate-rich ferric hydrox ...

ROYAL SOC CHEMISTRY2021

Tailoring the redox-active transition metal content to enhance cycling stability in cation-disordered rock-salt oxides

Corsin Battaglia, Chunyang Zhang, Yong Yang, Yining Li

Lithium-excess cation-disordered rock-salt oxides (DRXs) are investigated intensively as cathode materials for future lithium-ion batteries combining cationic and anionic redox reactions. However, the lattice oxygen redox can cause severe oxygen release re ...

ELSEVIER2021

Inositol pyrophosphates promote the interaction of SPX domains with the coiled-coil motif of PHR transcription factors to regulate plant phosphate homeostasis

Luciano Andres Abriata

Phosphorus is an essential nutrient taken up by organisms in the form of inorganic phosphate (Pi). Eukaryotes have evolved sophisticated Pi sensing and signaling cascades, enabling them to stably maintain cellular Pi concentrations. Pi homeostasis is regul ...

Nature Research2021

Fighting Health Hazards in Lead Halide Perovskite Optoelectronic Devices with Transparent Phosphate Salts

László Forró, Endre Horvath, Márton Kollár, Pavao Roko Andricevic, Xavier François Mettan

Organic-inorganic lead halide perovskite (CH3NH3PbI3) solar cells have surpassed 25% power conversion efficiency, being ready for industrial-scale production of cheap photovoltaic (PV) panels. In this action, the major hurdle is its lead content, which in ...

AMER CHEMICAL SOC2021

Cellulose phosphorylation comparison and analysis of phosphorate position on cellulose fibers

David Lyndon Emsley, Jayasubba Reddy Yarava, Michel Bardet, Julien Bras

Chemical modifications of cellulose fibers as pretreatment for cellulose nanofibrils (CNF) production have been investigated to improve the production process and the quality of obtained cellulosic nanomaterial. In this study, phosphorylation of cellulose ...

ELSEVIER SCI LTD2020

Nano-sized iron oxides supported on polyester textile to remove fluoroquinolones in hospital wastewater

Sami Rtimi

In this study, we examined the removal kinetics of two fluoroquinolones (FQs), flumequine (FLU) and ciprofloxacin (CIP), in synthetic wastewater (SWW) and real hospital wastewater (RHW) using FeOx thin films, peroxymonosulfate (PMS) and visible light. Nano ...

ROYAL SOC CHEMISTRY2020

Ruthenium on phosphorous-modified alumina as an effective and stable catalyst for catalytic transfer hydrogenation of furfural

Oliver Kröcher, Davide Ferri, Gaël Peng, Thibault Xavier Florian Fovanna

Supported ruthenium was used in the liquid phase catalytic transfer hydrogenation of furfural. To improve the stability of Ru against leaching, phosphorous was introduced on a Ru/Al2O3 based catalyst upon impregnation with ammonium hypophosphite followed b ...

2020

Detrimental vs. beneficial influence of ions during solar (SODIS) and photo-Fenton disinfection of E. coli in water: (Bi)carbonate, chloride, nitrate and nitrite effects

César Pulgarin, Stefanos Giannakis

In this work, we studied the effect of inorganic ions occurring in natural waters on E. coli inactivation by solar and photo-Fenton processes, two crucial methods for drinking water treatment in sunny or developing countries. HCO3-, Cl-, SO42-, NO3-, NO2- ...

2020

Source apportionment of atmospheric P using the Positive Matrix Factorization (PMF) model

Athanasios Nenes, Kalliopi Violaki, Christos Panagiotopoulos

The PMF receptor model was applied to a combined dataset using specific markers such as phospholipids and sugars together with other metals (e.g. Al, Pb, V) and ions (e.g. K+, Ca2+, SO42-, NO3-) as tracers of main aerosol sources in order to characterize t ...

2020

Model-based data analysis of the effect of winter mixing on primary production in a lake under reoligotrophication

Alfred Johny Wüest, Hugo Nicolás Ulloa Sánchez, Camille Roland Marie Minaudo, Shubham Krishna

Nutrient loading, in combination with climate change are important drivers of primary productivity in lakes. Understanding and forecasting future changes in primary production (PP) in response to local and global forcing are major challenges for developing ...

ELSEVIER2020

The role of Organophosphate Esters Flame Retardants and plasticizers (OPEs) in Phosphorus Cycle in the atmosphere of the Mediterranean Sea

Athanasios Nenes, Kalliopi Violaki, Christos Panagiotopoulos

The atmosphere is considered as an important external nutrient source for the marine environment, especially in remote ocean waters or the oligotrophic Mediterranean Sea. Phosphorus (P) is a critical nutrient affecting primary productivity in large areas o ...

2020

Specific Ion Effects at the Interface of Nanometer-Sized Droplets in Water: Structure and Stability

Sylvie Roke, Halil Ibrahim Okur, Evangelia Zdrali

The interaction of ions with interfaces influences numerous processes in chemistry, physics, and biology, while different ion species behave differently at hydrophobic or hydrophilic interfaces. Despite its importance, ion specificity and its relation to s ...

2019

Rapid evaluation of bioactive Ti-based surfaces using an in vitro titration method

Paul Bowen, Jacques Lemaître, Weitian Zhao

The prediction of implant behavior in vivo by the use of easy-to-perform in vitro methods is of great interest in biomaterials research. Simulated body fluids (SBFs) have been proposed and widely used to evaluate the bone-bonding ability of implant materia ...

Springer2019

Enhanced transformation of sulfonamide antibiotics by manganese(IV) oxide in the presence of model humic constituents

Urs von Gunten, Jun Ma, Jin Jiang, Yang Song, Yang Zhou

In this study, a manganese(IV) oxide-mediator (MnO2-mediator) system for the abatement of sulfonamide antibiotics was evaluated. Two simple model humic constituents, syringaldehyde (SA) and acetosyringone (AS), could promote the transformation of sulfonami ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Adsorption of HPDX and CaHPOx (x=1, ...,4) molecules on anatase TiO2 (001) surfaces

Alfonso Baldereschi, Michel Posternak

perform DFT calculations within the COSMO framework to study the adsorption properties of the CaHPOx (x = 1,...,4) phosphate family, and of the related HPOx acids, on a paradigmatic anatase (001) surface. Of particular interest is CaHPO4, a precursor of hy ...

ELSEVIER SCIENCE BV2019

Calcium phosphate formation on titanium-based surfaces: bioactivity evaluated by in vitro methods

Weitian Zhao

The prediction of implant behaviors in vivo by the use of easy-to-perform in vitro methods is of great interest in biomaterials research. In the field of bone implants, it is commonly accepted that a spontaneous formation of a hydroxyapatite (HA) layer on ...

EPFL2018

Non-setting, injectable biomaterials containing particulate hydroxyapatite can increase primary stability of bone screws in cancellous bone

Dominique Pioletti, Ulrike Kettenberger, Jorge Solana Munoz

BACKGROUND: Fracture fixation in weak bone is still a clinical challenge. Screw augmentation was shown to successfully increase their primary stability. The currently used calcium phosphate or polymeric bone cements, however, present important drawbacks su ...

2018