Publications associées à Diagramme de Pourbaix

Microstructure - Electrochemical Surface Reactivity Relationship of Electrochemically Grown Manganese Oxides Films

This Thesis provides a comprehensive and correlative investigation of the microstructure, chemical state, and electrochemical reactivity of manganese oxide (MnOx) films, aiming to gain a deeper understanding of the deposition and dissolution mechanism of M ...

EPFL2024

Operando Observation of (Bi)carbonate Precipitation during Electrochemical CO2 Reduction in Strongly Acidic Electrolytes

Corsin Battaglia, Alessandro Senocrate, Nukorn Plainpan

Precipitation of (bi)carbonate salts during the electrochemical CO2 reduction (CO2RR) has been identified as a major cause of degradation and one of the main challenges to be overcome before implementing this technology on the industrial scale. Recently, t ...

Amer Chemical Soc2024

Data-Intensive Exploration of the Photoelectrochemical Responses of Main-Group Metal Sulfides

Nicola Colonna

Materials that efficiently promote the thermodynamically uphill water-splitting reaction under solar illumination are essential for generating carbon-free ("green") hydrogen. Mapping out the combinatorial space of potential photocatalysts for this reaction ...

Amer Chemical Soc2024

Spectroelectrochemical and Chemical Evidence of Surface Passivation at Zinc Ferrite (ZnFe 2 O 4 ) Photoanodes for Solar Water Oxidation

Michael Graetzel, Kevin Sivula, Mounir Driss Mensi, Meng Xia, Liang Yao, Nestor Guijarro Carratala, Dan Ren, Yongpeng Liu

Recent advances in low‐cost manufacturing as well as in bulk/interface engineering have positioned zinc ferrite (ZnFe2O4, ZFO) in the spotlight as a candidate material for solar water oxidation. However, the severe recombination at the reactive interface r ...

2021

Transferable machine-learning models of complex materials: the case of GaAs

Giulio Imbalzano

Molecular simulations allow to investigate the behaviour of materials at the atomistic level, shedding light on phenomena that cannot be directly observed in experiments. Accurate results can be obtained with ab initio methods, while simulations of large-s ...

EPFL2021

The influence of chemical composition, aerosol acidity, and metal dissolution on the oxidative potential of fine particulate matter and redox potential of the lung lining fluid

Athanasios Nenes, Andrea Mario Arangio

Air pollution is a major environmental health risk and it contributes to respiratory and cardiovascular diseases and excess mortality worldwide. The adverse health effects have been associated with the inhalation of fine particulate matter (PM2.5) and indu ...

PERGAMON-ELSEVIER SCIENCE LTD2021

Aqueous-phase reactive species formed by fine particulate matter from remote forests and polluted urban air

Andrea Mario Arangio, Ting Zhang, Jing Li

In the aqueous phase, fine particulate matter can form reactive species (RS) that influence the aging, properties, and health effects of atmospheric aerosols. In this study, we explore the RS yields of aerosol samples from a remote forest (Hyytiala, Finlan ...

Copernicus Publications2021

Regulating the anomalous Hall and Nernst effects in Heusler-based trilayers

Jean-Philippe Ansermet, Haiming Yu, Simon Granville, Sa Tu, Junfeng Hu, Song Liu

Anomalous Hall and anomalous Nernst properties of thin MgO/Co-2Fe0.4Mn0.6Si/Pd stacks with perpendicular magnetic anisotropy (PMA) revealed the presence of the magnetic proximity effect (MPE) in the Pd layer. The MPE is evidenced by nanometer range thickne ...

2020

Atomic Layer Deposition of ZnO on CuO Enables Selective and Efficient Electroreduction of Carbon Dioxide to Liquid Fuels

Michael Graetzel, Shaik Mohammed Zakeeruddin, Ulf Anders Hagfeldt, Jing Gao, Jingshan Luo, Dan Ren, Zaiwei Wang, Linfeng Pan

Electrochemical reduction of carbon dioxide, if powered by renewable electricity, could serve as a sustainable technology for carbon recycling and energy storage. Among all the products, ethanol is an attractive liquid fuel. However, the maximum faradaic e ...

Wiley-VCH Verlag GmbH2019

Passivity-based Voltage and Frequency Stabilization in AC microgrids

Giancarlo Ferrari Trecate, Pulkit Nahata

In this paper, we investigate the stability of an islanded AC microgrid (ImG) composed of Distributed generation units (DGUs), dynamic power lines, and loads. Each DGU is equipped with a local controller to ensure desired voltage and frequency in the ImG. ...

IEEE2019

H2-fuelled microbial metabolism in Opalinus Clay

Rizlan Bernier-Latmani, Luca Loreggian, Niels Burzan, Aislinn Ann Boylan, Carla Perez Mon

In Switzerland, the Opalinus Clay formation is considered the most likely host rock for a deep geological repository for nuclear waste. In deep geological repositories, H2 is expected to be the most abundant gas formed from the degradation of waste and fro ...

2019

Highly Active Nanoperovskite Catalysts for Oxygen Evolution Reaction: Insights into Activity and Stability of Ba0.5Sr0.5Co0.8Fe0.2O2+delta and PrBaCo2O5+delta

Nicola Marzari, Ivano Eligio Castelli, Xi Cheng

It is shown that producing PrBaCo2O5+delta and Ba0.5Sr0.5Co0.8Fe0.2O2+delta nanoparticle by a scalable synthesis method leads to high mass activities for the oxygen evolution reaction (OER) with outstanding improvements by 10x and 50x, respectively, compar ...

WILEY-V C H VERLAG GMBH2018

Emergent transport in a many-body open system driven by interacting quantum baths

Vincenzo Savona, Eduardo Carlo Mascarenhas Moraes, Juris Reisons

We analyze an open many-body system that is strongly coupled at its boundaries to interacting quantum baths. We show that the two-body interactions inside the baths induce emergent phenomena in the spin transport. The system and baths are modeled as indepe ...

Amer Physical Soc2017

Redox Levels through Constant Fermi-Level ab Initio Molecular Dynamics

Alfredo Pasquarello, Assil Bouzid

We develop a method to determine redox levels of half reactions through the use of ab initio molecular dynamics evolving at constant Fermi energy. This scheme models the effect of an electrode by controlling the charge transfer between the single-particle ...

Amer Chemical Soc2017

A universal chemical potential for sulfur vapours

Davide Tiana

The unusual chemistry of sulfur is illustrated by the tendency for catenation. Sulfur forms a range of open and closed S-n species in the gas phase, which has led to speculation on the composition of sulfur vapours as a function of temperature and pressure ...

2016

Self-assembled 2D WSe2 thin films for photoelectrochemical hydrogen production

Kevin Sivula, Xiaoyun Yu, Nestor Guijarro Carratala, Mathieu Steven Prévot

WSe2-a layered semiconductor that can be exfoliated into atomically thin two-dimensional sheets-offers promising characteristics for application in solar energy conversion. However, the lack of controllable, cost-effective methods to scalably fabricate hom ...

Nature Publishing Group2015

Explicit solvent simulations of the aqueous oxidation potential and reorganization energy for neutral molecules: Gas phase, linear solvent response, and non-linear response contributions

Jeremy Samuel Arey, Peter Rudolf Tentscher, Marianne Seijo, Jennifer Guerard

First principles simulations were used to predict aqueous one-electron oxidation potentials (E-ox) and associated half-cell reorganization energies (lambda(aq)) for aniline, phenol, methoxybenzene, imidazole, and dimethylsulfide. We employed quantum mechan ...

Royal Soc Chemistry2015

A selective chemiluminescence detection method for reactive oxygen species involved in oxygen reduction reaction on electrocatalytic materials

Christos Comninellis, Pauline Bornoz

An original selective and quantitative detection method for direct access to reactive oxygen species (ROS) generated in near-neutral aqueous solutions during transient electrochemical experiments is described herein. Several chemiluminescent probes, which ...

Pergamon-Elsevier Science Ltd2013

Dual and multi-stimuli responsive polymeric nanoparticles for programmed site-specific drug delivery

Harm-Anton Klok

In the past decades, polymeric nanoparticles have emerged as a most promising and viable technology platform for targeted and controlled drug delivery. As vehicles, ideal nanoparticles are obliged to possess high drug loading levels, deliver drug to the sp ...

Elsevier Sci Ltd2013

Formation of an electron hole doped film in the alpha-Fe2O3 photoanode upon electrochemical oxidation

Michael Graetzel, Artur Braun, Florent Alexandre Boudoire

Solar hydrogen generation by water splitting in photoelectrochemical cells (PEC) is an appealing technology for a future hydrogen economy. Hematite is a prospective photoanode material in this respect because of its visible light conjugated band gap, its c ...

Royal Society of Chemistry2013